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Sprill Prevention and Maintenance Plan SPILL PREVENTION/MANAGEMENT PLAN TEXACO STATION 63-157-293 706 Ye1m Avenue East Yelm, WA A. FACILITY HAZARDOUS MATERIAL INFORMATION 1. Hazardous Material Stored On Site Underground storage tanks are as follows: (1) 12,000 gallon regular unleaded (1) 10,000 gallon mid-grad unleaded (1) 10,000 gallon premium unleaded (1) 10,000 gallon diesel All tanks are double wall flberglass and were installed ln 1992 The system meets all federal UST requirements for leak detection, cathodic protection and spill/overfill 2 Types of Hazardous Material Generated on Site Gasolines and Diesel (See attached Annual Dangerous Waste Form 4) 3 Hazardous Waste Disposal Hazardous Waste is handled through a central TSDF contracted by Texaco The company lS Phllip Environmental, located in Renton, WA The company conducts a chemical proflle of any hazardous waste generated on site, transports and disposes of the waste in their TSDF B SPILL PREVENTION REQUIREMENTS 1. Inspection a) Daily BaS1S - Statlon Manager and/or employee wlll 1 Inspect monitoring equipment for operation and alarm status. il Inspect supply of sorbent material and restock if needed Ensure proper storage and dlsposal of spent sorbents iii. Inspect dispensers/lslands, durlng cleanlng, for eVldence of spills iv. Inspect tank fill area, during sticking, for any aa Evidence of spills/overfills, and bb. Any damage to fill caps/seals or manhole covers (See attached vapor recovery log) b) Quarterly Basis - Outside Contractor will' 1 Perform fire extingulsher inspection and recharge. ii. Perform first aid kit replenishment 111. Inspect dispenser containment for any leaks/spills c) Annual Basis - Outside Contractor will 1 Peform monitoring equipment callibration and/or working order test 11 Perform test of the Emergency Shut Off System 111 Peform dispenser meter callibration. lV. Perform leak detector test 2. Loadlng, Unloading, and Transfer Areas a) Unloading A~eas - Tanker Truck Fuel Deliverles Spill containment during the delivery of fuel at the service station is handled through 1 An overfill alarm and lightlng system, 11 Spill contalnment around the fill area, 111. Absorbent Boom/Dlklng lS onboard the tanker delivery truck to contaln large spllls b) Transfer Areas - Connection Point Repair 1 Outside contractors performlng this type of repalr are mandated to follow Texaco's Contractor Safety Guidelines which include the appropriate use of drip pans 3 Employee/Resldent Training Training is specificallly outllned ln the Station's HazCom/Emergency Response Manual (See attached). The station manager is trained, and in turn the manager trains each station employee before they are allowed to work Both the manager and station employees receive annual refresher training on the materials included ln the statlon manual. 4 Recordkeeping and Inventory Inventory Control Program a) Daily Basis - Station Manager will 1. Manually stick tanks and compare Gauging Equipment to verify what underground. Perform meter / console comparison sales and any callibration errors iii Verify product delivery receipts. Prepare computer report that calculates loss/growth with the above information. (See Attached Report) wi th Auto Tank is being stored ii. to determine lV. product b) Monthly Basis 1 Store Supervisor completes an inventory reconcillation on slte for Dlvision records (See attached - Report) Log Book The followlng activities are recorded ln the log book. a) Testing - All testing of 1 Dispensers (Callibrations) ii. Tanks (Tightness Testing) 111 Product/Vent Lines (Precision Tests) iv. Monitoring Equipment aa Liquid/Vapor Probe Tests bb Working Order Tests cc Pressure Tests b) Inspections - All Inspections performed ln Section 1 1 Daily ii Weekly iii. Quarterly lV Annually c) Malntenance - All malntenance effectlng. 1 Dispensers - Including hoses, nozzles, breakaways, meters, and impact valves, 11. Tanks Physical tank repair, fill caps, spill containment, iii Product/Vent line/Subpump repair, lV Monltorlng Equlpment RepalrjResettlng/Dlsabllng. d) System Alarms Recording of monitoring equipment alarms 1. Time of alarm ii Type of alarm iii Action taken to respond to alarm lV. Cause of Alarm e) Spills/Overfills/Nozzle Breakaways i. Emergency response procedures documented followed and 5 Notification and Labeling See Labeling section of HazCom/Emergency Response Manual 6. Additional Spill Prevention Requirements For Temporarily Storing HS in bulk Does not apply at this time C. SPILL MANAGEMENT REQUIREMENTS 1. Spill Management Plan a) Faclllty Characterizatlon Information i Sewer/Storm Blueprint 11. G/A of tanks 111 MSDSs on all Cp~micals stored on site lV SARA Title III Form v Internal Emergency Response Notebook (See Attached) 2 Response Equipment a) Automatic Shut Off Button b) Fire Extinguishers c) Sorbent Material d) Emergency Response Spill Kit (See attached list of kit contents) 3 Response Procedures a) HazCom/Emergency Response Manual 1 See HazCom Written Plan ii See Emergency Response Sheet b Internal Emergency Response Notebook (See attached) FACILITY CLOSURE PLAN It is Texaco's position to follow all applicable State and Federal guidelines regarding the temporary and/or permanent closure of any portion of its undergound storage tank system All notices of closure and site assessment checklists/reports required by State and Federal Agencies will also be submitted in copy to the Tacoma- pierce County Health Department, Envlronmental Services Dlvslon, for review and recording .~ ~,,;r'- _c.:. {.;.: ','t/;" . <.'~';{::.';~ ~;VS~/J ,;,,*~,ii"{i';;"<"'i>)if#I"'''~i~<''5;if~'''i~';'j~i~~~, ,.t~~.J.u~. ~~',;'P;;,'>i; .. GENERAL SITE INFORMATION FORM ANSWERS PLEASE ENTER: WAD 988502365 EPAfState 10 number. Site name: TEXACO 4/:63- 157-0293 FOR ECOLOGY USE ONLY: Date received: A-:L What is your EPA/State (0 N~mber? WA 12. _ -.2 8 8i9~3~5_ __ A-2. What Is the name of this site (I.e., the company/agency to which the EPA/State 10 Number is ~(~ed)? If your company has more than one site by the same name in Washin~n, provide a site Identifier here (e.g., ACME-Everett v. ACME-Auburn) TEXACO 4/: 63 -15 T - 0 29 3 A-3. What is your Washington Department of Revenue Tax Registration Account Number (also known as the United Business Identifier-U8I)? 60123 8 698 -r- (Please enter the mne <L.gits only; do not enter any letters precedmg the number. ThIS number IS assigned to your business's Tax Regrstration Account by the Department of Revenue. Contact your fiscal office or the Department of Revenue If you do not know your regIStratIOQ number. Do not use your federal tax number here. If you are a tax-exempt agency, enter "NA" in the first two spaces and leave the other spaces blank; the Department of Revenue will construct a number for you for dangerous waste fee purposes only, and Ecology will mamtam records of that number mternaUy) For the name and address mformatIon requested below, if you need to repeat a partICular name or address for nore than one questIOn, you may Simply speClfy<<Same as questIon XX" (e.g., If the locatIOn address m ques- 'IOn A-5 IS tile same as the matlmg address In questIOn A-4, wnte <<Same as A-4" m the space for questIOn A-5) '>lease read questIOns A-4 through A-II before completmg any of the InformatIOn. TIns WIll help you aVOId laving to correct portIons of the form. Do not leave any of the followmg questIOns bIalik-you must at least \TrIte <<Same as. "on the first lUIe of each questIOn. \-4. What is tIle mailing address for the company/agency? (I.e., where should Ecology send future form Y3ckels and cO[ respondence<) Street Address or PO Box CIl)', State Zip Code P. O. BOX 2969 KIRKLAND, WA 98083 Page 1 of 7 pages GOO 1\ 1 1 9 9 5 FOR 1\1 SAN 0 INS T RUe T ION S 1. 5 ".. t:-r. ...." r.: .~.> ~:',~ ".;<f'<;; .it ".:..;, __. jS, 0'. -:,to ~;.-:.;~ .:~. ~'~~'~ " :~~ .. ;,.. ,..." - i- . . ........... ~...~ ;: ^ , .' DANGEROUS WASTE ANNUAL REPORT . ...:. ~. A-S. What Is the locatlon address of the cORJpany/agency at this site? (ieo. enter the street address or geographic location.lf a street address is not available. please provide nearbyaoss-streets for reference; you may also use Township, Section, and Range information. Do not provide PO Box or rural mail route address.) Street Address City, State, Zip Code County 706 YELM AVENUE EAST YELM, WA 98597 THURSTON A-6. Who Is the legal owner of the company/agency? (Please provide information regarding the person, company, or agency that owns this busrness.) Name TEXACO REFINING AND MARKETING INC Street Address or PO Box P.O. BOX 2969 WA 98083 KIRKLAND, City, State, Zip Code County Phone( 206) 827-0761 KING --.,.. - A-7. Has the owner of the company/agency changed since you last reported? UNo (If no, skip to A-S.) o Yes (If yes, answer A-7..a.) A-7.a. Please provide the qate on which the ownership changed. (mm/ddjyy) __/__/__ 'T If the ownershIp of the busl!)css has changed Since you last reported a NotificatIOn Form (Form 2) or the Annual Report forms, you wIll be reqUired to complete a new NotIficatIon Form. Please call Ecology at 206/407-6737 A-8 Who is the operator of the company/agency responsible for the dangerous waste handling activity? (Please proVIde mformatlon regardmg the company or agency responsible for the overall operatIOn of thts busmess.) Name TEXACO REFINING AND MARKETING INC ,.",( Street Address or PO Box P.O. BOX 2969 City, State, Zip Code KIRKLAND, WA 98083 COUllty KING Phone ( 206 ) 827-0761 Page 2 of 7 J.6 80 0 1\ 1 1 9 9 5 FOR M SAN 0 INS T RUe T 10 N S ., . ';~.'.'~ :-;'VC" :fl' GENERAl. SITE INFORMATION FORM PLEASE ENTER: EPA.fSt,ate 10 number. W~ 9 8 850 2 3 6 5 "Site name: TEXACO 163-157-0293 A-9. Who owns the property (real estate) on which the company/agency Is located? (Please provide information regarding the person, company. or agency that owns this property.) Name and Tide TEXACO REFINING AND MARKETING INC. Street Address or PO Box P. O. BOX 2969 City. State, Zip Code KIRKLAND, WA 98083 CountyK.:I:NG Pho~e( 206 ) 827-0761 ~-:10. Whom should Ecology contact on-slte regarding site visits and Inspections of the company / agency? (If the indiVIdual whom Ecology should contact is not located on-site, enter the correct address and phone number for that indiVidual's location.) ROBIN L. LANE, TEXACO E H & S SPECIALIST Name and Title Street Address or PO Box P. O. BOX 2969 City, State, Zip Code KIRKLAND, WA gROR1 County KINe; Phone( 206 ) 82 7-07 61 ~- - -:li. Whom should Ecology contact if clarification is needed on this form? NameandTitle ROBIN L. LANE, TEXACO E H & S SPECIALIST Street Address or PO Box Clt)', State, Zip Code P. O. BOX 2969 KIRKLAND, WA 98083 Count)' KING Phone ( 206) 827 - 0761 12. Please enter the four-digit Standard Industrial Classification (SIC) code that best describes the principal products or services rendered at this site. (If more than one code applIes, please enter th~ pnmar)' SIC code-the code that best descnbes your buslOess's products or servICes-1O the space ffir the pnmary number below ThiS IS the SIC code under whICh your busmess IS registered WIth the WashlOgton Department of Revenue_ You may lIst up to three other relevant SIC codes 10 the addi- tIOnal spaces below A Itst of SIC codes can be found on pages 27-38 of Book 2. GUIdebook alld Codes. 554 1 L _ _ _ _ (pllIl13r)) 2 3 ____ 4 Page 3 of 7 8001~ 1 1995 FORMS AND INSTRUCTIONS ~7 tt.~~ I ,: :.: ~',~.;~.r:. ,. ,. ,""",,',,. ";,'\C',, '""",'< ,', "A."" ",,"'''''''~''''''''''''''',;~(',J*'~, WASTE ANNUAL REPORT DANGEROUS B-i. Old the company/agency generate dangerous waste in 1.995? !Xl No (If no, answer B-i.b.) 0 Yes (If yes, answer B-ia.) B-:L.a. What Is your generator status? (Check one box. If you are not sure of your generator status, refer to Worksheet #1 beginning on page 7.) 'f o Large Quantity Generator (proceed to B-2) o Medium Quantity Generator (proceed to B-2) o Small Quantity Generator Maximum accumulation or monthly generation quantity: pounds (NOTE: Small Quantity Generators who are not requIred to report for other rensoT15---e-g, bemuse they are a TSDR-now may slap to the Certificatzon on page 21 and return only thIs GSI Form to Ecology SQGs are not reqUIred to prOVIde all)' addltumallllforl7latloll 011 tlllS or allY other Annual Report form.) _- B-1..b. If the company/agency did NOT generate dangerous waste in 1.995, please indicate the reason(s} below. (Check all reasons that apply) o We never generated dangerous waste. Qg We generate dangerous waste only occasionally and did not generate waste in 1.995 o We are a dangerous waste transporter only o We !lave gone out of bUSiness Date closed (mmjdd/yy) - - /- - /_- o Tile waste we generate IS exempt from state and federal dangerous waste regulation o Otller (please speCify) ~ ,(~ Paae 4 of 7 C> :18 BOOK 1 1995 FORMS AND INSTRUCTIONS , I I -) :) ~ ~:l ~;,,~: "<"",.".,, GENERAL SITE INFORMATION FORM PLEASE ENTER: EPA/State 10 number: WAD 9 8 8 5 0 2 3 65 Site name: TEXACO #63- 157-0293 8-2.. Does the company/agency treat. store, recycle, or dispose of dangerous waste? (11Us does not include treatment-by-generator activity and permit- by-rule actIVIty [see the DefinitIOns section of Book 2: Guidebook and Codes]. Information on treatment-by- generator and permIt -by-rule activity will be captured in the GM Form for those generators conducting on-site treatment actlvities. Generators conductrng either permit-by-rule or treatment-by-generator activity but no other treatment, storage, recyclmg, or disposal activity should answer <<No" to this question.) P Yes (If yes, answer 8-2.a.) 1 l&l No (If no, lQGs'should skip to Section C, below. All other sites should skip to Section 0, Comments, on page 20, if appropriate; otherwise, skip to the Certification on page 21.) 8-203. Is the company/agency exempt from reporting Its dangerous waste treatment, storage, recycling, and disposal activities? o Yes (If yes, specify one of the following.) o No (If no, skip to Section C ) o We manage only exempt wastes o We closed prior to 1995, no dangerous waste treatment, storage, recyclir}g. or disposal actiVIties occurred dUring 1995 -- o We did not treat, pre-treat, store, recycle, or dispose of dangerous waste dunng 1995 o Other (please specify). COMPLETE THIS SECTION ONLY FOR ODD (e.g. ~995, 1997) REPORTING YEARS LQGs and TSDRs must completc thiS seCllon Jf you are not an LOG or a TSDR, procced to ScCtlOll D, Comments (page 20), I( approprIate, or to the CertIficatIon (page 21) Ecology IS reqUired by EPA to collect the foUowmg mformalIon every other year (blenIllally, dunng the odd reportmg years---<,.g , 1995, 1997) These questIons replace the EPA \,Vaste MlIllmlL3110n Report that you have rece1\'ed III the past (rom EPA. Ecology recogmzes the llJ11ltalIons of the waste mlIllmlZ3llon quesllons contalIled III thiS form and III the GM Form and IS collectmg tl1lS l/1(ormalIon solely for proVISion to EPA as per EPA reqUirements. As a matter of polICY l/1 the State of\,Vashmgton, Ecology wrll rely on the Pollution Prevention Plan and Progress Reports for tIlfOrmatlOI1 through wI1lch to analyze busmesses' poUul1on prevention and waste mlI1lmlZ3tlon efforts. Please refer to the defiIllllons of source reductloI1and rccycllI1g (see rife DefiIlltlons sectIon of Book 2: Guulehook and Codes) to help you complete tlus sectlOl1. These quesllons refer to site-wide waste mlIllmlz.atlon activities. The questions on the GM Form arc waste stream-spcClfic. c-~_ Did this company/agency begin or expand a source reduction actiVity during 1.994 or 1.995? DYes ~No GOOI" 1 1995 FORMS AND INSTRUCTIONS ,1 i-- ~9 PAGE 5 OF 7 PGS I .l J ~i. ~...",-..'. -'. ,,,:. -.:~. --.-. 1".... ... . - ~.. ~."- .. ~. .. ,,:~ DANGEROUS WASTE ANNUAL REPORT C--2. Did this company/agency begin or c::xpand a recycling activity during :1.994 or :1.9951 DYes IZJ.No C--3. Did this company/agency systematically investigate opportunities for source reduction or recycling during :1.994 or :1995? DYes e9 No Use tillS sectIon to provide any additional comments, informatIon, or explanatIon, if necessary. In your comments, always provide the reference to the specific question number (e.g., A-7). .. /' 20 800 I{ 1 1 99 5 FOR M SAN 0 INS T Rue T I 0 I\! S PAGE 6 OF 7 PAGES I 'l. I .I .. ,:".: GENERAL SITE INFORMATioN FORM PlEASE ENTER: EPA/State 10 number. WAD 9 8 8 5 023 6 5 Site name: TEXACO #63-i57-0293 Upon completIon of all required forms, please provide the following information. First mark which form(s) you are submitting In this package. Then indicate the total number of pages in your subrruttal. XKl General Site Information Form o Generation and Management Form o Off-Site Identification Information Form ~ Total number of pages submitted [Refer to the instructIOns "Page numbering your submittal" (page 4) for rnstructions on how to number the pages of your submisswn. After you compile and manually numbu all of the pages of your submIttal including the "last page" on page 45, enter in the space prOl'ided the total number of pages bemg submitted. Then complete and sign the Certrficatton below} The following must be signed by an authorized representative of the company/agency. ThIs certIfica- tion language is required under EPA's Biennial Report. Ecology is required to implement reporting requirements at least as stringent as those in that report. [certify under penalty oflflw that th~s document and all attachments were prepared under my dIrectIOn or supervlslOll 111 accordance With a system deSIgned to assure that qualified personnel pro[}{J.1'ly gather and evaluate the 1I1formatlOn submItted. Based on my 111qwry of the persall or persons who manage the system, or those persons directly responsible for gatherIng the mformatlOll, the IIlformatlOn submItted IS, to the best of my knowledge and belIef, true, accurate, and complete. I am aware that there are srgmficant penaltres for submit- ting fa'fse information, includin e possibility of fine and Imprisonment for knowmg VlOlattons. _...--- // SIgnature (in I~Y/ Name (pnntft}'P€1 Date Title TEXACO ENVIRONMENTAL, HEALTH, AND SAFETY SPECIALIST " / 23- PAGE 7 OF 7 PAGES GOOh 1 1995 FORMS AND INSTRUCTIONS I ~ \ WEEKLY STAGE 1 INSPECTION LOG Gasoline Storage Tanks Vapor Recovery Equipment DUAL POINT COAXIAL SYSTEMS DATE TANK ADAPTERS FILL TUBE POPPET COAXIAL COAXIAL REPAIR MADE* INITIALS INSPECTED CAPS (tight) GASKETS VALVES GASKETS SPRINGS (tight & (in place & in (scat (in place & in (operate gasket OK) good condition) properly) good condition) properly) " - + = okay T = torn C = cut M = missing L = loose B = broken R = replaced RR = repaired *Follow your approved procedures for making repairs. Form No. Revised 2/14/96 WEEKLY STAGE 2 INSPECTION LOG - VACUUM-ASSIST (No Bellows) Hoses & Nozzles Vapor Recovery Equipment ..... I DATE HOSES & SPOUTS LATCH MINI BOOTS REPAIR MADE. INITIALS INSPECTED SWIVELS (no leaks) RINGS/COILS (Optional) (no cuts or crimps; (present & in good (undamaged) swivels work) repair) - --""_.~ + = okay T = torn C = cut M = missing L = loose B = broken R = replaced RR = repaired *Follow your approved procedures for making repairs. Form No. Revised 2/14/96 r ,;', fY!o0n/LX cI- !f-t0NU/l-tE c::;. It --- ltt^-D '''~_n~ -"""-::> . I ,- .:~-?:257 ~ - I:~;:~i- :0-7g.&7/,' ,..""'...~...; I ~.~ .::m.. ??l /~J ~r~'.: ,\.- ": '.:1.:":.. , ~ ,~ ,,", ._, ti f1 ~' r:I; ::" / /' ------------------------------------------------------------------------------------------------------------------------------------ -------------------------------------------------------------------------------------------------------------------------------- fic N W Region Lation Level - C-St Sup/Mk rep G/A FUEL VARIANCE REPORT For Period 12/95 Ended 12/31/1995 Page Date/Ti me 1 Prog GA6230 04/18/1996 03'35-PM Tank Fuel -------- Period-to-Date ----------- ----------- Prior-Period ------------ ___________ Year-to-Date ____________ Gallons Variance %Var Gallons Variance %Var Gallons Variance %Var C-St Sup/Mk rep 102-GUY MAHAN Acceptable Variance Exception - Y 05 05 Exception - Y 05 05 Exception - Y 05 ,05 Location 9004 - 63157000293/YELM AV E/YELM,WAO 2 360 16,700 30 51 30 o 31 16,085 01 59 99- o 37- 180,197 31 237 31 o 13 3 365 86,682 60 422 40- o 49- 81,401 28 65 72- o 08- 963,123,88 176 88 o 02 4 456 9,116 18 34 18 o 37 8,227 55 5 45- o 07- 112,607 73 323 73 o 29 5 375 16,874 67 36 33- o 22- 13,916 35 36 65- o 26- 138,341.02 280 98- o 20- '-,,:,:~.~.~.., r:o -:~""-""" ~;Z##L. ~~;:if:. .~.:::*.:.. :~;Ei?:.~z? $......~:i~; Z4E0 '~;.C:":.~~.;;,.: 'W"" '::': '.;31. ,;g;.. ~( .~.~'h'.~ , ' . .!: 'f _; ~c >,,-- ~11 ~;.--- JfJON'rtfL Y ~ t1~-; /AcDtT 320-Pacific N W Region G/A INVENTORY REPORT Page: 1 prog GA6080 C-St Sup/Mk rep 102-GUY MAHAN For 12/01/1995 Thru 12/31/1995 Date/Ti me 04/18/1996 03:34-PM ------------------------------------------------------------------------------------------------------------------------------------ ------------------------ Inventory Units ------------------------ -- Inventory Value -- ------ Delivery Information ------ Date Beginning Delvr'd Xfered Adjusted Sold Ending Per/Unit Dollars Vendor Inv Ref No Cost Type ------------------------------------------------------------------------------------------------------------------------------------ Location 9004 63157000293/YELM AV E/YELM,WA022006 Fuel Type 360 Po....er Prem Tank # 2 12/01 730 00 5000 I 022333 1 26350 360 12/01 6984 00 732 00 o 00 6 98 663 98 7789 00 1 27436 9925 99 5000 I 022334 1 26350 360 12/02 7789 00 o 00 12 15- 484 85 7292 00 1 27436 9292 63 12/03 7292 00 o 00 6 75- 385 25 6900 00 1 27436 8793 08 12/04 6900 00 o 00 9 55- 660 45 6230 00 1 27436 7939 26 12/05 6230 00 o 00 5 33- 515 67 5709 00 1 27436 7275 32 12/06 5709 00 o 00 3 38- 569 62 5136 00 1 27436 6545 11 12/07 5136 00 o 00 1 27- 578 73 4556 00 1 27436 5805 98 12/08 4556 00 2015 00 o 00 16 40- 545 60 6009 00 1 28636 7729.74 5000 I 022551 1 31350 360 12/09 6009 00 o 00 1 75- 496 25 5511 00 1 28636 7089 13 12/10 5511 00 o 00 o 63- 335 37 5175 00 1 28636 6656 91 12/11 5175 00 2420 00 o 00 3 11- 46Q 89 7131 00 1 29501 9234 72 5000 I 022610 1 31350 360 12/12 7131 00 o 00 30 70- 109/}, 30 6002 00 1 29501 7772 65 12/13 6002 00 o 00 14 99 474 99 5542 00 1 29501 7176 95 12/14 5542 00 o 00 1 19- 560 81 4980 00 1 29501 6449 15 12/15 4980 00 o 00 1 89 556 89 4425 00 1 29501 5730 42 12/16 4425 00 1515 00 o 00 13 91- 600 09 5326 00 1 29136 6877 78 5000 I 022807 1 28070 360 12/17 5326 00 o 00 o 51- 392 49 4933 00 1 2913 6 6370 28 12/18 4933 00 o 00 2 58 622 58 4313 00 1 29136 5569 64 12/19 4313 00 3828 00 o 00 2 40- 453 60 7685 00 1 27591 9805 37 5000 I 022883 1 25850 360 12/20 7685 00 o 00 203 85 620 85 7268 00 1 27591 9273 31 12/21 7268 00 o 00 o 51 484 51 6784 00 1 27591 8655 77 12/22 6784 00 o 00 o 84 709 84 6075 00 1 27591 7751 15 12/23 6075 00 o 00 o 88 693 88 5382 00 1 27591 6866 95 12/24 5382 00 o 00 o 26- 468 74 4913 00 1 27591 6268 55 12/25 4913 00 o 00 o 95 247 95 4666 00 1 27591 5953 40 12/26 4666 00 o 00 1 38- 532 62 4132 00 1 27591 5272 06 12/27 4132 00 4557 00 o 00 57 00- 452 00 8180 00 1 26678 10362 26 5000 I 023091 1 25850 360 12/28 8180 00 o 00 3 07 401 07 7782 00 1 26678 9858 08 12/29 7782 00 o 00 2 35 553 35 7231 00 1 26678 9160 09 12130 7231 00 2225 00 o 00 22 85- 575 15 8858 00 1 26483 11203 86 5000 I 023171 1 25850 360 12/31 8858 00 o 00 2 93 503 93 8357 00 1 26483 10570 18 Fuel Total 18022 00 o 00 51 30 16700 30 8357 00 10570 18 Fuel Type 365 Unleaded Tank # 3 12/01 2274 00 9204 00 o 00 80 44- 3598 56 7799 00 1 11244 8675 92 5000 I 022334 1 11240 365 12/02 7799 00 o 00 4 01 2880 01 4923 00 1 11244 5476 54 12/03 4923 00 o 00 30 46 2452 46 2501 00 1 11244 2782 21 12/04 2501 00 8664 00 o 00 93 35- 3199 65 7872 00 1 11241 8756 89 5000 I 022385 1 11240 365 12/05 7872 00 o 00 2 19 2743 19 5131 00 1 11241 5707 78 12/06 513 1 00 o 00 46 94 3401 94 1776 00 1 11241 1975 64 12/07 177 6 00 7489 00 o 00 129 38- 2886 62 6249 00 1 11240 6951 39 5000 I 022501 1 11240 365 12/08 6249 00 5443 00 o 00 21 11- 2971 89 8699 00 1 13 568 9879 28 5000 I 022551 1 16240 365 12/09 8699 00 o 00 8 80- 2748 20 5942 00 1 13568 6748 21 12/10 5942 00 o 00 21 27 2442 27 3521 00 1 13568 3998 73 12/11 3521 00 7299 00 o 00 11 59- 2537 41 8271 00 1 15370 9542 25 5000 I 022610 1 16240 365 320-Pacific N W Region G/A INVENTORY REPORT Page 2 Prog: GA6080 C-St Sup/Mk rep 102-GUY MAHAN For 12/01/1995 Thru 12/31/1995 Date/Ti me 04/18/1996 03 34-PM ------------------------------------------------------------------------------------------------------------------------------------ ------------------------ Inventory Units ------------------------ -- Inventory Value __ ------ Del ivery Information ------ Date Beginning Delvr'd Xfered Adjusted Sold Ending Per/Unit Dollars Vendor Inv Ref No Cost Type ------------------------------------------------------------------------------------------------------------------------------------ 12/12 8271 00 o 00 10 63- 4991 37 3269 00 1 15370 3771 45 12/13 3269 00 7653 00 o 00 66 77- 3250 23 7605 00 1 13688 8645 97 5000 I 022680 1 12970 365 12/14 7605 00 o 00 3 76 2884 76 4724 00 1 13688 5370 62 12/15 4724 00 o 00 45 97 3097 97 1672 00 1 13688 1900 86 12/16 1672 00 10177 00 o 00 107 05- 2853 95 8888 00 1 11585 9917 67 5000 I 022807 1 11240 365 12/17 8888 00 o 00 14 24- 2319 76 6554 00 1 11585 7313 28 12/18 6554 00 o 00 21 56 2810 56 3765 00 1 11585 4201 18 12/19 3765 00 4933 00 o 00 35 99- 2593 01 6069 00 1 11106 6743 02 5000 I 022883 1 10740 365 12/20 6069 00 o 00 220 09 2709 09 3580 00 1 11106 3977 59 12/21 3580 00 7957 00 o 00 66 60- 2875 40 8595 00 1 10854 9527 90 5000 I 022943 1 10740 365 12/22 8595 00 o 00 10 29 3302 29 5303 00 1 10854 5878 59 "12/23 5303 00 6973 00 o 00 74 59- 2819 41 9382 00 1 10789 10394 22 5000 I 023008 1 10740 365 12/24 9382 00 o 00 8 83 2263 83 7127 00 1 10789 7895 93 12/25 7127 00 o 00 3 95 645 95 6485 00 1 10789 7184 67 12/26 6485 00 6447 00 o 00 59 85- 2747 15 10125 00 1 10765 11214 96 5000 I 023054 1 10740 365 12/27 10125 00 2517 00 o 00 17 08- 2418 92 10206 00 1 10760 11304 17 5000 I 023091 1 10740 365 12/28 10206 00 o 00 4 43 2859 43 7351 00 1 10760 8141 97 12/29 7351 00 o 00 10 28 2674 28 4687 00 1 10760 5191 32 12/30 4687 00 7451 00 o 00 63 35- 2539 65 9535 00 1 10748 10559 82 5000 I 023171 1 10740 365 12/31 9535 00 o 00 4 39 2163 39 7376 00 1 10748 8168.77 Fuel Total 92207 00 o 00 422 40- 86682 60 7376 00 8168 77 Fuel Type 456 DIESEL Tank # 4 12/01 5250 00 o 00 4 04 494 04 4760 00 1 15641 5504 51 12/02 4760 00 o 00 1 96 229 96 4532 00 1 15641 5240 85 12/03 4532 00 o 00 1 68 243 68 4290 00 1 15641 4961 00 12/04 4290 00 o 00 2 70 336 70 3956 00 1 15641 4574 76 12/05 3956 00 o 00 2 21 313 21 3645 00 1 15641 4215 11 12/06 3645 00 o 00 2 74 261 74 3386 00 1 15641 3915 60 12/07 3386 00 3025 00 o 00 36 31- 503 69 5871 00 1 15239 6765 68 5000 I 022501 1 14790 456 12/08 5871 00 3020 00 o 00 6 34- 335 66 8549 00 1 14574 9794 93 5000 I 022551 1 13280 456 12/09 8549 00 o 00 1 98- 277 02 8270 00 1 14574 9475 27 12/10 8270 00 o 00 1 89 120 89 8151 00 1 14574 9338 93 12/11 8151 00 o 00 1 53- 241 47 7908 00 1 14574 9060 51 12/12 7908 00 o 00 o 34 316 34 7592 00 1 14574 8698 46 12/13 7592 00 o 00 2 10- 334 90 7255 00 1 14574 8312 34 12/14 7255 00 o 00 o 75- 352 25 6902 00 1 14574 7907 90 12/15 6902 00 o 00 o 32- 343 68 6558 00 1 14574 7513 76 12/16 6558 00 o 00 o 98 281 98 6277 00 1 14574 7191 81 12/17 6277 00 o 00 o 14 289 14 5988 00 1 14574 6860 69 12/18 5988 00 o 00 o 90 407 90 5581 00 1 14574 6394 37 12/19 5581 00 o 00 o 52 162 52 5419 00 1 14574 6208 77 12/20 5419 00 o 00 97 42 375' 42 5141 00 1 14574 5890 25 12/21 5 14 1 00 o 00 1 84 28/f 84 4858 00 1 14574 5566 00 12/22 4858 00 o 00 3 90 570 90 4291 00 1 14574 4916 37 12/23 4291 00 o 00 1 71 378 71 3914 00 1 14574 4484 43 12/24 3914 00 o 00 o 29 179 29 3735 00 1 14574 4279 34 12/25 3735 00 o 00 o 00 66 00 3669 00 1 14574 4203 72 12/26 3669 00 o 00 1 89 303 89 3367 00 1 14574 3857 71 12/27 3367 00 4438 00 o 00 53 86- 243 14 7508 00 1 13838 8546 96 5000 I 023091 1 13280 456 320-Pacific N W Region G/A INVENTORY REPORT Page: 3 Prog GA6080 C-St Sup/Mk rep 102-GUY MAHAN For 12/01/1995 Thru 12/31/1995 Date/Time 04/18/1996 03:34-PM ------------------------------------------------------------------------------------------------------------------------------------ ------------------------ Inventory Units ------------------------ -- Inventory Value -- ------ Delivery Information ------ Date Beginning Delvr'd Xfered Adjusted Sold Ending Per/Unit Dollars Vendor Inv Ref No Cost Type ------------------------------------------------------------------------------------------------------------------------------------ 12/28 7508 00 o 00 3 26 228 26 7283 00 1 13838 8290 82 12/29 7283 00 o 00 4 10 327 10 6960 00 1 13838 7923 12 12/30 6960 00 o 00 1 55 176 55 6785 00 1 13838 7723 91 12/31 6785 00 o 00 1 31 135 31 6651 00 1 13 83 8 7571 37 Fuel Total 10483 00 o 00 34 18 9116 18 6651 00 7571 37 Fuel Type 375 POWER PLUS Tank # 5 12/01 7204 00 o 00 4 73- 684 27 6515 00 1 19300 7772 40 12/02 6515 00 o 00 3 18- 593 82 5918 00 1 19300 7060 17 12/03 5918 00 o 00 1 91- 473 09 5443 00 1 19300 6493 50 12/04 5443 00 2018 00 o 00 12 62- 499 38 6949 00 1 19027 8271 19 5000 I 022385 1 18290 375 12/05 6949 00 o 00 1 96- 489 04 6458 00 1 19027 7686 76 12/06 6458 00 o 00 2 38- 5 \.1 62 5944 00 1 19027 7074 96 12/07 5944 00 o 00 o 39- 523 61 5420 00 1 19027 6451 26 12/08 5420 00 o 00 o 34- 635 66 4784 00 1 19027 5694 25 12/09 4784 00 o 00 o 91 397 91 4387 00 1 19027 5221 71 12/10 4387 00 o 00 1 12 471 12 3917 00 1 19027 4662 29 12/11 39 17 00 1912 00 o 00 22 20- 598 80 5208 00 1 20425 6271 73 5000 I 022610 1 23290 375 12/12 5208 00 o 00 22 45- 1184 55 4001 00 1 20425 4818 20 12/13 4001 00 4032 00 o 00 27 55- 555 45 7450 00 1 20222 8956 54 5000 I 022680 1 20020 375 12/14 7450 00 o 00 3 42- 401 58 7045 00 1 20222 8469 64 12/15 7045 00 o 00 2 83- 500 17 6542 00 1 20222 7864.92 12/16 6542 00 o 00 1 15- 434 85 6106 00 1 20222 7340 76 12/17 6106 00 o 00 1 15- 414 85 5690 00 1 20222 6840 63 12/18 5690 00 o 00 o 08- 543 92 5146 00 1 20222 6186 62 12/19 5146 00 2817 00 o 00 16 52- 417 48 7529 00 1 19539 9000 09 5000 I 022883 1 18290 375 12/20 7529 00 o 00 149 13 498 13 7180 00 1 19539 8582 90 12/21 7180 00 o 00 2 57 514 57 6668 00 1 19539 7970 86 12/22 6668 00 o 00 2 66 625 66 6045 00 1 19539 7226 13 12/23 6045 00 o 00 2 22 829 22 5218 00 1 19539 6237 55 12/24 5218 00 o 00 1 90 571 90 4648 00 1 19539 5556 17 12/25 4648 00 o 00 o 15- 319 85 4328 00 1 19539 5173 65 12/26 4328 00 5046 00 o 00 70 40- 502 60 8801 00 1 18598 10437 81 5000 I 023054 1 17790 375 12/27 8801 00 o 00 9 11 517 11 8293 00 1 18598 9835 33 12/28 8293 00 o 00 5 96 533 96 7765 00 1 18598 9209 13 12/29 7765 00 o 00 3 31 503 31 7265 00 1 18598 8616 14 12/30 7265 00 1581 00 o 00 21 99- 745 01 8079 00 1 18454 9569 90 5000 I 023171 1 17790 375 12/31 8079 00 o 00 2 18 382 18 7699 00 1 18454 9119 77 Fuel Total 17406 00 o 00 36 33- 16874 67 7699 00 9119 77 Loc Total 138118 00 o 00 373 25- 129373 75 30083 00 35430 09 CJ6S 50d- 3Co5 ~ Rovised November 1990 WASHINGT(}J CCJ.MJNITY RIGfT - TO-KNJ...J #: Fac;lllly I~UflcaUon k+- ~ S. Name X~D I ~ 511N1 e....\ '<Y"\ e-n e.- O', y _ f;:, ",,",,'1h~n ... JtJ.a r_ q~ 'i'11 Tier Two EMERGENCY AND HAZARDOUS CHEMICAL INVENTORY SICC<xJ. ~ ~"N'~ [Q]Q]-~-~ Sptcific '"/orma/wIt by CM~aJ P"II. .._L__ ol J "''II.' FOIm ~""ed OMO No 20~ 00/2 CMner/:alor ~ ReJ~(), '," ~ Phone ~ )g~ ."'M~. r1a~", 8'?l PI')3I<Mi<f!, W498037, Emefgen~ co'tAct N&tr. K e-J Ed lNtu-ds Phone (~/J) 6 fJq - 8;253 NMne UurreJ I ltV~n Phone (~0) f36Cj - 3;;2..30 .........;. ---,- ,::,: FOR .I~, . I :::9f~lfl.E. Ab.:r::".:::. '.::::'. . . '~L'( :0... ReooIved I . . . ,. . - . . . . . . . . . . . . . . Important Read all Instructions before completing form ........:iiii:I~I.I:... CAS ~ [WIT] Ell ~"': 18] Cham, Name 6Q t)O If ne... P6'Wer + Cl>ed .JI ... Yf'I1: o DO a. EHS ~D SolId [Z] lJqud Pure loIix EHS Name CAS nnEI:IJ [l(IT] l:m ~"': lKl Cham, Name Grit;(') liv-e - (r1'1Jmded Cl>ed .JI ... .".q: o DO a.. EHS [ZlD Mix Solid ro l.Jquid Pure EHS Name CAS ~ ~ r:i':il Tr.o. n:::7I ~ Se<... ~ Cham. Name ... - flA' UA'l) Clwd .JI loW/ Yf'I1: Q ~Q ~ Cd Q EHS Name Reporting Period FromJan..-., 110 o.o..ro., 31 111M Physical ::"and:Halth ':r:"H,a:#~~$". :::?:~iiiifu;. . Sudden RM.. 01 P__ure A.Mct;"1y 1trmedioII. (1O<Mj Dele)'ed (chl'QOc) :::il;:~~I~:~i,R:,' :.:t:):;:::::::::: :::;:;:':::::':";:: li1!'1 ri:-rJnq"'~,,(l.tiy,: ',. .~L~~l~,<'~)"" ~,:^~;'~~j':",..': ~:,!:tm~M:l~}:. ~~Wta;!J ..;.;.;.; .. .. . . . !7;'1"';'n 'M.\tOaJIy' r:.L.l!d:J. ..~. ,. ~) ~'~~~~l ~::~oli:>ay. ~'9~~(c;l.y.) " Tit. 2. HI. Phone ( Tille 2A Hr, Phone ( . [gJ~~~~~~~~ 'llnlll."lljt~~ . 1m ~A'35~;j Sh:a(f 1M!) 0aJ. .i9ned ( id1:J'~~ )~~~ 10M lJ~1Pr%~ ~%(1)~f {{lIlk :2/3/CfS .-;: T.;;;-;-:-: ~.-: "; '-:::' ~.:;-:: ::. 8 I........ Iftecl>ed · .... pkn I ........ anaclled . iii' 01 ... e<>ot<litw. obbt..,;a/Ooo. I t.av. &IIacIled . ~oo 01 di... erd Olher ,oIOQ_d """'u,.. .- -'--' I o D o 042595 " ~, ..... "I '~ I" \ I "It, CONSUMER INFORMA TION: ,,.. ;-1-800-PETROSORB (1-800-738-7676) ." A , .~ ,;(~~;;~~~ \,~i~;;' ,'~ "f,L;&@1995 PETROSORB, INC. ~ . EVERETT, WASHINGTON 98208. "i;l~o ";If;l~tf!j~ "'1" ,,; ','; i~, . ,\. ., ; .~ ~ - PetroSorb Custom Kit 1;, REUSABLE ABSORBENT PRODUCTS \ '> '.:; -<i., i" "':f:'t;'~{ .i" 'y. ,. ". ~ ". ,- ,:~ ,.. .~~: ~. ; , ~,!,'~~i 'r+ -"~". .~' 'i, ,,.. ;;<.:"~r , CONTENTS. , gr,. '~~~;',~,;';,n ;'i'. ' ~~::~':'~~);;Bl1.~' ".r, PETRO-MAT DRAIN COVERS ,i(:#~f~~~:"f:'->'< "~'.\ \.~; ~'J ~,~j'\';1 '? ~;.:t'-rl'~..~..t ~.;,:Wt.~~~~': _~?J}}._~:t PETRO-KWIKSORB.PADS ';~.;~,':~~Ji~i~\ ' " "'t .~~.; ~~~ ;;J. .-~~ ~rrli~)~ ~~~:;t~". PETRO-SOCKS"'" ".,'ii:;;~; 'v ., "'-"'. ;;i~r~~~;:,:~ PETRO-PILLOWS \;.' i, ;~i.~,. ..... .\~;.:~. ;:~'I PETRO PLUG ' k, ~'bJ, -, I' ..'. 7; ":~i;$j,' :~~l;(" .,;i~:~i':}i~;,< ABSORBENT GP NATURAL FIBf;lrPADS ~~~~~~~.:ijr . ~t ..~ .~:~:-~:'~;i::Y\'~'.;;,r,; t..~:~~~~;t~:,*i/(~;F .1; BAGS OF ABSORBENT PARTICULATE '=J1~~; ~~ ..~ c~J;:~:}> DISPOSABLE,GLOVES~2;~i~' ,~ .)r>~~'2:, ;-f~,},~'?~; ',~i.:~\~<~V{~;~~:' TEMPORARY DISeOSAlJ BAGS WITH TIES {., "t,l'~ :.:.. ~ ;~_~'..<\.~ "";f"~.~li,?' . PETRO-LOG SPILL RESPONSE REPORT ,,:, 'i. D.O.T. EMERGENCY RESPONSE MANUAL 't,. INSTRUCTION BOOKLET " 1,;_ '1! ~. ";":,) )i;. ',. .,1I,~~\.,';,;); "'DUE TO cusrOMIZA nON, NOT ALL PRODuprs ARE; INcUJDED IN ALL KITS.!. I, '~~:,~~~: ' '~ ~. ~.. ,i}"t;'i .t;. ,. ,;!~~ ,,' , ~ 'I" 17_".;;:.<"" <I: it ~". INSTRUCTIONS FOR USE.: PETRO-MAT DRAIN COVERS. PETRO-SOCKS. PETRO-PILLOWS: PETRO-KWIKSORB: PETRO-PLUG: BAGS OF LOOSE PARTICULATE. ."/ .;. ABSORBENT GP NATURAL FIBER PADS: TEMPORARY DISPOSAL BAGS DISPOSABLE GLOVES' CAUTION TAPE: PETRO-LOG SPILL RESPONSE REPORT: ~ .~ 1ft~!\; \ .,....... ~~ . ~~~,.._J~ ,';~f;' ~~!~f:;;.' h. lJir J~!~\" ~~ ." .,. PLACE ON TOP OF SEWER GRA TElSTORM DRAIN NE SPILL. ;';Ii, }- PLACE INIAROUND SPILL OR DRAIN IF SPILL IS LARGE j-~l'~.,~.~~ ,-,-.. J ;: FOR USE IN STROM DRAINS AND OIUWATER SEPAAA ABSORB PETROLEUM BASED LIQUIDS BY PLACING I CONTAINMENT PAN OR ON TOP OF SPILL.?;:+ '~~>'T ~. " TO TEMPORARILY SEAL A GASH OR LEAK IN A TANKlD SPREAD TO ABSORB LIQUID OR LET LIQUID DRIP INT OPEN BAG. SWEEP ABSORBENT INTO SPILL. . ,. ....;;.y ~;~ USE FOR FINAL CLEAN-UP. ,ABSORBS PETROLEUM PRODUCTS AND WATER. ~ PLACE SOAKED MATERIAL INTO DISPOSAL BAGS AND:, TOP DISPOSE OF PROPERLY. USE TO PROTECT SKIN DURING SPILL CLEAN-UP. ~' .j SURROUND AREA WITH TAPE TO WARN OUTSIDERS 0 DANGEROUS SPILLS. ;0,'10 '~.',1'&, " '.'~ . d::;~~;~;~~ '~, T RECOR~ SPILL INFORM~TION FOR ~UTH9R~!IES._ ::; i '~, ,:;;';;~"t" :ofi~.",,1 .,::{ ,,(',:1~6t;i,~1:l\\' j ,; . ,~;;;' o ~ -;" J"t. .t'" .j, KIT CLEANING AND MAINTENANCE: < ~1f;"!' ' }~~~ 'l~"" "~ ",~..,,,, .~.. ,.. t ,~,,:~:y~;S; ~,:1~j1r~t;:~ ,,'. DISPOSAL OF PRobuCT:'::WJ:'~)~1~~" ,<~: - ':" ~ \C'~2Y?,}'.!: '~ #~[~~:~ft": EMPTY CONTAINERS, DISPOSABLE ~1j GLOVES AND GARBAGE BAGS MUS BE DISPOSED OF IN ACCORDANCE\:, WITH THE LOCAL, STATE, AND "~ FEDERAL REGULATIONS OF YOUR .. AREA :-... /: .:~. ~. WASHING: t: CLEAN ABSORBENT PRODUCTS WITH A BIODEGRADABLE CLEANERlDEGREASER BY SQUEEZING AND FORCING WATER THROUGH SOCK, PILLOW OR SPONGE. RINSING: ALL OTHER KIT CONTENTS ARE 'i' REUSABLE AND MUST BE CLEANED , AND REPACKED FOR FURTHER USE.;: FOR ADDITIONAL HELP, PLEASE SEE.~ KIT CLEANING AND MAINTENANCE INSTRUCTIONS ON PREVIOUS PAGE;" THOROUGHLY RINSE PRODUCT AND AERATE TO DRY. REPACK KIT FOR FURTHER USE. \.; DISPOSAL: " ':'.' DISPOSE OF ALL SPILL CLEAN-UP WASTE IN ACCORDANCE WITH THE LOCAL, STATE, AND FEDERAL REGULATIONS OF YOUR AREA. " c ;~r: '-J~ .,~ 'J: ; PRODUCT ORDERING: TO RE-ORDER PRODUCTS CONTACT YOUR LOCAL SUPPLIER. \ " \ :..." ,;\ l~ '\. :( ~~~ \. 01; ~; .>'Texac:o '.~.'.. . ..~'~~ , : : """.:'\.' !'~'~"". .,:.~;.: . (206)827.;076 ....' ~:':': .~ EMERGENCY RESPONSE LIST UNCONTROLLED RELEASES mayor may not be contained on the facility property. This kind of spill may occur when a truck has a large over-fill during a delivery to the facility, or when a car hits a dispenser and causes extensive damage. Or it may occur through a catastrophic disaster such as earthquakes, windstonns, floods, or even riots. Immediatelv: 1) Shut down fuel flow to dispensers by activating the Emergency Shut-off switch. 2) Take a TLS 350 Inventory reading. 3) Sh~ down circuit breakers. 4) Evacuate all customers. 5) Stop all traffic through area. 6) Put up barricades if available. 7) Notify everyone listed in the following box. Monday-Friday 7:30am to 4:00 pm 1) Fire Department 911 2) Store Manager's # 3) Maintenance Center 800-825-0761 4) Eric Smith (206)889-3201 5) EH&S Coordinator (206)889-3253 After hours, Week-ends & Holidays 1) Fire Department 911 2) Store Manager's # 3) SME 800-345-8487 4) Maintenance Center 800-825-0761 5) Eric Smith's pgr. 800-263-2158 6) EH&S Coord pgr. 206-340-5563 Do Not attempt to approach the point of release to stop the source or try to contain the release NEVER WASH A SPILL OFF THE PROPERTY INTO A DITCH OR SEWER Notification Information: 1) Date and time of spill 2) Where did spill occur? 3) How much was spilled? 4) Was anyone or anything affected by the spill? 5) Who was notified? 6) Was the spill contained? 7) Was anyone responsible for spill? p:\Excel\Haz\Emrgncy# EMERGENCY REPAIR PHONE PROCEDURES EVENINGS, WEEKENDS AND HOLIDAYS 1. LEAKS INCLUDES PPH 4000, TLS 350 ALARMS AND INTERIOR DISPENSER LEAKS. NOT INCLUDED, LEAKING NOZZLES, S~IVElS, BREAKA~AYS AND HOSES. THEY SHOULD BE PUT IN "OUT OF ORDER" STATUS. CERTIFIED CONTRACTOR ~ NORTH~EST PUMP 2. DAMAGE TO BUILDING AND EQUIPMENT DAMAGE THAT PRESENTS A HAZARD TO EMPLOYEES OR THE PUBLIC. CERTIFIED CONTRACTORS - SERVICE STEEL D S STEEL AND FABRICATION 3. LOSS OF ONE OR MORE PRODUCTS CHECK TO MAKE SURE THEY HAVE NOT RUN OUT OF PRODUCT. (ONE OR T~ HOSES DOYN IS NOT CLASSIFIED AS AN EMERGENCY). CERTIfIED CONTRACTORS - SME (SOUTH LOCATIONS) ACME PUMP (NORTH LOCATIONS) 4. CONSOLE FAILURE MAKE SURE FAILURE IS NOT OPERATOR ERROR MANAGER SHOULD CHECK IT OUT PRIOR TO CALLING THE CONTRACTOR. AMS PRINTERS ARE NOT AN EMERGENCY ~ITH THE EXCEPTION TO MHX 3000 UNITS. CERTIFIED CONTRACTORS - SME (SOUTH LPC~TIONS) ACME PUMP (NORTH LOCATIONS) 5. WALK-IN COOLER AND FREEZER FAILURE CERTIFIED CONTRACTORS - SCOTT POLAR (SOUTH LOCATIONS) CAR ~ASH SERVICES (NORTH LOCATIONS) 6. AIR CONDITIONING OR HEAT FAILURE NOT AN EMERGENCY UNLESS SEVERE/ExrREHE TEMPERATURES EXIST. CERTIfIED CONTRACTOR - SCOTT POLAR (SOUTH LOCATIONS) CAR ~ASH SERVICES (NORTH LOCATIONS) ** OIL FURNACES PLS CALL EITHER SHE (SOUTH LOCATIONS) ACHE PUMP (NORTH LOCATIONS) 7. ELECTRICAL FAILURE CONTACT LOCAL UTILITY TO DETERMINE IF CAUSE IS OUTSIDE THE FACILITY PRIOR TO CALLING A CONTRACTOR. CERTIfIED CONTRACTOR - SME (SOUTH LOCATIONS) ACHE PUMP (NORTH LOCATIONS) 8. MISCELLANEOUS ENVIRONMENTAL INCIDENTS CERTIFIED CONTRACTOR - $ME (SOUTH LOCATIONS) ACHE PUHP (NORTH lOCATIONS) HORTHlJEST PUMP (ANY lOCATlON) PHONE NUMBERS J~r.?~ff~c<~(;:;' ACME PUMP CAR ~ASH SERVICES D S STEEL NORTHWEST PUMP SCQTT. ..POlAR ,i. .'~ .;~~;~_.~+~;t!j~t:~4-;!:;.~)ti':_j~<.;!tP;.:~.~lt~/.:: :,:'...:~~i~J<,;.i.,:, i'Z;' _ -,I) {',:".t;,,,,;""-!';ISERv';I-EI:i'*,'SliEE~;'", . SME 367-0070 774-1207 546-8870 622-8100 833-9300 t;"8"'~ii';;^~':"Ji!tl~'. '8":W6:;':'~;!\c;, ',-0:-:' .' , ~ "''',,:0:',,,, ~ .....I~...". ,.,.. ; -,!,.,,' ,". ',' 572-3822 \iT!< '>;';~''; :t".. EMERGENCY RESPONSE FLOW CHART (;JOIG13Jo~j IN THE EVENT A SPILL IS REPORTED TO YOU, COMPLETE ALL OF THE FOLLOWING ACTIVITIES IN THE ORDER THEY APPEAR BELOW. A. UNCONTROLLED RELEASE - Definition: A release that mayor may not be contained on the facility property. This kind of spill may occur when a truck has a large over-fill during a gasoline delivery to the facility, or when a car hits a gasoline dispenser resulting in extensive damage. 1) Complete DOE 24 hr Spill Report with Caller (Ex. 1,2,4) 2) Review Emergency Response Sheet with Caller including Notification Information Questions (Inside Cover) 3) Dispatch Contractor to Clean up and dispose (Ex. 5) 4) Notify the Department of Ecology (Ex. 6) a) Go through 24 hr Response Sheet b) Get Case Number 5) Notify Environmental Analyst (Ex. 7,8) 6) Notify TES (Ex. 9) 7) Notify Maintenance Analyst/Field Malntenance Supervisor (Ex. 7, 8) 8) Notlfy Marketlng Consultant/Store Supervlsor (Ex. 7,8) 9) Provide copies of the 24 hour Response Sheet to: a) Environmental Analyst b) Maintenance Analyst/Field Maintenance Supervisor c) TES d) Marketing Consultant/Store Supervisor e) Retall Manager/C-Store Coordlnator f) Copy of report Permanent Statlon File 10) In the event a spill has the possibility of causing or has caused significant threat to the environment and/or human health with high media exposure to the company, also notify the following individuals/groups immediately: a) Division Manager (Ex. 7,8) b) Western Region - Public and Government Affairs (Ex. 10) (Have them notify W.Reglon Management) c) Houston EH&S (Ex. 11) (Have them notify Harrison Management) d) Company Insurance Carrler (Ex. 12) e) Receptionist/Switchboard Operator B. Incidental Releases - Definition: Any controllable release which can be absorbed, neutralized or controlled at the time of the release by employees to the immediate release area, and which can be contained on the facility property. This kind of spill can occur when a customer over-fills their car. <(nI~; 1) 4) _CompLat_e-DOE---24---hr-Sp-il-l.-Repo.r.t__:wi.t.h__Caller---(Ex.----1, -3 , 4 ) Ensure proper disposal of contaminated materials (Get with maintenance/enviro analyst for disposal instructions) 3) Notify the Department of Ecology (Ex. 6) a) Go through 24 hr Response Sheet b) Get Case Number ~4) Notify Environmental Analyst/Environmental Supervisor (Ex. 7,8) ? 5') ----- I ~~f 6) / ~~ ..-J - '-- Notify Maintenance Analyst/Field Maintenance supervisor (Ex. 7,8) Notify Marketing Consultant/Store Supervisor (Ex. 7,8) Pr:..Q.Y.ide-e-0pies--of--the-24--hour-"'RespenS'e'- Sheet to: a) Eny ironmental--AI1CiTys"f- b) Mainten-ance-~'AhaTyst/Tield Malntenance Superv isor c) Mar~~~ing Consultant/Store supervisor d) Permanent station File ; .{~~;~: Exhibit Information: 1. Blank 24 hour response sheet (Blanks and Completed Example) 2. Example of Completed 24 hour response sheet for an uncontrolled release. 3. Example of Completed 24 hour response sheet for an incidental release. 4. DOE Numbers for each location on Retail Directory List 5. MJS's Contractor ListjER Packet 6. DOE Spill Response Telephone Numbers 7. New Phone Extension List 8. Home Phone Number List 9. TES telephone numbers 10. Public and Government Affairs Cards 11. Houston EH&S Contact 12. Insurance Carrier l ~ CASE NUMBER CONTACT PERSON: LUST Initzal Response (24 Hour) Report Form UST SIte RegistratIon Number SIte Name Contact Person Contact Phone Site Street SIte City SIte County SIte ZIP SIte Phone Owner (If dIfferent than above) Owner's Address Owner's Phone CONSULT ANT CONSULTANT PHONE COt.fP ANY Other COnJact Phone Affilzorion Date Reported Date Started Date Under Control Date Completed Date Final Report TYPE OF FACILITY 1/ OF TANKS PRODUcr(S) TANK STATUS (IN OR OUT) CLEANUP STATUS LEAD FOR CLEANUP IS TRUST $ USED'] POLLUTED MEDIA Reason for Discovery Closure Monlfonng Spill Tank Tes[ EX. 1 ~AM.l'L1~ FOK UNCONTKOLLEO KELEASF CASE NUMBER' Sq&S CONTACT PERSON:Rp';n~~ Hnvde LUST Initial ReSlJonse (24 Hour) Report Fonn UST Site Registration Number 00/'/121 SIte Name TEXACO STATION Contact Person (Your Name Here) Contact Phone 827-0761 Site Street 2400 140th NE Site City Bellevue Site County King Site ZIP 98005 SIte Phone 747-5025 Owner (If different than above) TEXACO REFINING AND MARKETING INC Owner's Address 10602 NE 38th Place, Kirkland, WA 98033 Owner's Phone (206)-827-0761 CONSULTANT Mark Nichols CONSULTANT PHONE (206)-251-5441 COMPANY GROUNDWATER TECHNOLOGY INC. Other Contact Mark Wells Phone (206)-774-6090 AffilzatlOn TEXACO ENVIRONMENTAL SERVICES Date Reported 10/30/91 Date Started 10/30/91 Date Under Control 10/30/91 Date Completed Date Final Report # OF TANKS 5 TYPE OF FACILITY Service Station PRODUCT(S) (3) Gasoline; (1) Waste Oil; (1) Heating Oil TANK STATUS (IN OR Our) In CLEANUP STATUS In Process TRUST $ USED? N/A LEAD FOR CLEANUP IS: Mark Wells POLLurED MEDIA Pet,,,, Pllm r"nt",min",tpn Sni 1/~r01mri IJ:'l rpr Reason for Discovery Closure Monitonng Spill x Tank Test Dispenser sheared off of Island by Drunk Driver. Approximately 50 gallons released. Ex. 2 SAMPLE OF INCIDENTAL RELEASE CASE NUMBER. 5946 CONTACT PERSON: "ern61 \ LUST Initial Response (24 Hour) Report Fonn \ UST SIte.f.eglstrauon Number 8954 \ SIte Name ~FYAr.() STATTON Contact Person (your name here) Contact Phone 827-0761 Site Street 5115 Olympic Drive Site City Gig Harbor, WA Mason SIte County SIte ZIP 98335 Site Phone (206)-851-2635 TEXACO REFINING AND MARKETING INC Owner (If dIfferent than above) Owner's Address 10602 NE 38th Place, Kirkland, WA 98033 Owner's Phone (206)-827-0761 CONSULTANT N/A CONSULTANT PHONE N/A COMPANY N/ A Other COnlOCl N/A Phone N/A Affilzanon N/A Date Reported 10/30/91 10/30/91 Date Started 10/30/91 Date Completed 10/30/91 Date Under Control Date Final Report TYPE OF FACILITY C-Store # OF TANKS 4 PRODUcr(S) (3) Gasoline; (1) Diesel TANK STATUS (IN OR OUT) In CLEANUP STATUS Complete LEAD FOR CLEANUP IS' SME Corp TRUST $ USED? N/A POLLUTED MEDIA Spill onto ConcrP1P P~n ~nn Tnt Asrh~lt Reason for Discovery Closure MOTllfOnTlg Spill x Tank Test 10 Gallon Spill from Customer overfilling car tank Ex. 3 ( EMERGENCY CONTINGENCY PLAN LEAKS, SPILLS, STATION REPAIR EASTERN & WESTERN WASHINGTON MAJOR CONSTRUCTION CONTRACTORS: TANK AND LINE TESTS, WATER AND SOIL TESTING, WELL DRILLING, HAULING, SERVICE STATION ELECTRICAL AND CONSTRUCTION, MAJOR AND MINOR PETROLEUM CLEAN UP. ESE CORPORATION DAY & NIGHT: 11011 WALLER ROAD EAST (206) 535-3112 TACOMA, WA 98446 WES JOHNSON VENDOR NO. 248303000 r JOE HALL CONSTRUCTION DAY: 1317 - 54TH AVENUE EAST (206) 922-6815 FIFE, WA 98424 NIGHT. VENDOR NO 350460002 (206) 446-2347 DEL LOVELL (206) 848-019 MIKE CURTAIN DAVIS INDUSTRIES DAY' '-- 6425 -212TH STREET S.W. (206) 783-5959 L YNNWOOD, WA 98036 NIGHT: VENDOR NO. 218649002 (206) 794-4504 DEAN RAYMOND (206) 321-1250 MIKE DAVIS r \, Ex. 5 ( I ( (- STATION MAINTENANCE: DISPENSER REPAIR, HOIST, FILLS, MINOR LEAKS, PLUGGED DRAINS, GLASS, SEWERS, ETC. ACME PUMP SERVICE 11518 LAKE CITY WAY N E. SEATTLE, WA 98125 VENDOR NO. 005554001 NIGHT & DAY. (206) 367-0070 (206) 431-0299 DARRELL HARRISON NIGHT: (206) 789-0138 GARY HAGEN (206) 367-5538 DARRELL HARRISON JR. SME CORPORATION 2302 A STREET TACOMA, WA 98402 VENDOR NO. 690167009 (206) 775-7865 JAN O'NIEL DAY & NIGHT. (206) 572-3822 (HOME) (HOME) 833-6765 DON RUTH 874-5368 ~ JERRY WIESE STRUCTURAL STATION REPAIR: CANOPY, BUILDING DAMAGE, ROOF, ALL STEEL AND MASONRY REPAIR. SERVICE STEEL P.O. BOX 1360 -~ KENT, WA 98032 VENDOR NO. 710148016 DAY: NIGHT. (206) 872-7877 (206) 630-5956 JOHN HOLLINGER (206) 630-8770 BRENT HOLLINGER (206) 271-5957 BRIAN HOLLINGER .,. -~~ SIGN REPAIR: MODULE, PRIMARY 10, CANOPY SIGNS AND LIGHTS ( S.S. SIGN 13190 STONE AVENUE NORTH SEATTLE, WA 98133 VENDOR NO. 690397005 DAY & NIGHT. (206) 365-0242 NIGHT (HOME) (206) 488-2378 JAY STARR (HOME) (206) 774-4426 ROGER CORSTED (-\ (HOME) (206) 525-5495 SAM STARR TANK PUMPING: CO-MINGLING, PRODUCT REMOVAL FROM LEAKING TANK FOR RETURN TO TERMINAL AMERICAN TRANSPORT 24 HRS. 1-800-477-1217 ARROW FREIGHT LINES DAY: (206) 767-3605 24 HRS (206) 767-3605 TANK & SEPARATOR PUMPING OR VACUUMING: CONTAMINATED OR SPILLED l PRODUCT FOR DISPOSAL NW ENVIRO SYS (206) 622-1090 1700 AIRPORT WAY SO. HAZARDOUS WASTE SEATTLE, WA 98134 VENDOR NO. 587896002 (206) 762-1190 NON-HAZARDOUS WASTE NIGHT (206) 991-5234 TOM GREMIL: (NIGHT) (206) 833-5423 (MOBILE) (206) 953-5457 24 HRS: 1-800-735-7069 CHEM PRO 20245 76TH AVENUE SOUTH KENT, W A 98031 VENDOR NO 203703004 DAY. (206) 622-3400 L DAY OR NIGHT: (206) 872-8030 '1tiL/o 77 ferry S\eve\\s Pend Ore\\le OK8J\ogan Wha\COm .. Regional Olfice Location Uncoln .. SpoKane S\YJKa\\8 YaKima SKaf1l?<nia Walla Walla \ Klicki\a\ Ex. 6 TRMI, INe. PHONE EXTENSION UST EXT LAST FIRST CAR PHONE # 3245 ARMSTRONG PAT DlRECf DIAL 3211 BARREIT DON 940-3621 '889' TI-IEN EXTENSION 3205 BEARD SCOTI 3238 BECK FRANK 949-6521 MAIN SWITCHBOARD: 3226 BICKEL GEORGE x200 OR 827-0761 DlRECf 3232 CARLILE AL 949-3679 3251 CHUN (GRAVES) LYNN 949-3473 FAX. (206) 822-0022 3266 ClARKE ANGELA 3202 COATS RON MERIDIAN MAIL. x3200 3247 COMPUTER ROOM 3203 CRONIN JEAN 3201 CURRIE NANCY 3264 DORDENBAL HEIDI 3206 DORGAN LYN 3229 FLYNN TOM 948-1223 3212 FRANCIES LEONARD 3236 GERL KEN 947-5254 3235 GUBSCH KEN 348-1703 3213 GRAYBEAL PAT 3260 HAGOOD ROBERT 948-7892 3234 HANSON STEVE 947-1673 3204 HELMHOLZ VICKI 955-0308 BEEPER 3248 HINDMAN JAYNE 3244 HUNTER AL 947-6347 3210 JUDD MARGARET 3219 KLlJfZ TOM 948-1106 3216 LA JAMBE JERRY 999-714Q 3253 LANE ROBIN 948-5879 3231 LAZZERI TONY 948-1149 3265 MAHANNA BARB 955-0309 BEEPER 3207 MAIL ROOM 3262 MEETING ROOM 3208 MERLITTI ROBERTA 3240 MILES BOB 948-1459 3217 PERCY KERRYJO 999-9286 3214 PRICE JOHN 949-3189 3239 RAMOS DONNA 3209 RAMSEY JOHN 3252 RENSLO PEGGY 999-9456 3242 ROBERTS SHARON 3248 ROHR CECILIA 3223 SALMON MIKE 949-3403 3249 SACOMANO JOE 955-0305 BEEPER 3246 SARGENT ANGELA 3227 SPARE OFFICE 3228 STANGER ANNA 948-7915 3241 STEELE ANDREW 3215 TANKERSLEY GENE 948-1338 3237 TUFFEY DAN 3221 VSETECKA PENNY 3222 WAHL BRENDAN 3263 WALKER RITA 940-<i343 3230 WATSON DARRELL 949-1613 3233 WOLFE SUSAN 3224 WORSHAM JOHN 799-2102 3261 ZAHAlKO MIKE 940-3246 Ex 7 FILrNi\!\'lE. 'PIIONr \\'P~' rc\'''CU 10/7/91 "- MINOR SPILLS, CLEAN UP, PAINTING MOBILE CLEANING SYSTEM 1415 SENECA S W RENTON, WA 98055 VENDOR NO. 550864003 DAY: (206) 255-1600 LARRY DAY' (NIGHT) (206) 746-6689 (206) 939-8489 (MOBILE) (206) 954-9065 MAJOR SPILLS OR LEAKS: EXTENDED CLEAN UP, RECOVERY UNDERGROUND, ETC. TEXACO ENVIRONMENTAL SERVICES 3400 188TH ST SUITE 630 LYNNWOOD, WA 98037 DAY' FAX: (206) 77 4-6090 (Z06j 771-7786 (206) 771-5796 ANITA BURKE '-- (206) 481-4866 MIKE CONDON (206) 823-1090 MARK WELLS GROUNDWATER TECHNOLOGY 19226 - 66TH AVE. SO. SUITE L -109 KENT, WA 98032 VENDOR NO, 594670002 NATIONAL CONTRACT #7897 DAY (206) 251-5441 NIGHT. (206) 226-5363 MARK NICHOLS (206) 432-9170 MARK WINTERS (206) 639-0837 CHRISTOPHER NELSON Ex. 9 INSTRUCTIONS fOR OEALING WITH THE NEWS MEDIA IH AN EMERGENCY Immediately notify the nearest Public and Government Affairs (PGA) person below to make arrangements for a press statement regardless of time of day or night The applicable PGA office will send a representative to the scene if the emergency dictates N L. STANLEY Office: (818) 505-2654 Pager. 1-800-759-7243 PINI65398 S H STAKES Office. (818) 505-2679 Pager: 1-800-759-7243 PINI65397 B A KORNYLO Office: (81~) 505-2655 Pager 1-800-759-7243 PIN15~867 o W JOHNSQN Office (818)~505-2650 Pager. 1-800-759-7243 PINI52866 Ho.e' (80S) 497-0693 Mobile. (818) 383-1877 Ho.e. (213) 474-8124 Mobile: (818) 383-2560 Ho.e (818) 954-0004 Ho.e: (818) 597-9665 Mobile. (818) 370-3511 2 If the demand for information Is so urgent that a delay could lead to serious distortion of the situation in the media the local Senior Company Representative (SCR) Is authorized to release a minimum factual statement until the PGA representative can be contacted 1/91 The SCR present s~ould designate a qualified person to handle inquiries from the press pr10r to the availability of the PGA Press Representative shall representetive The A Prepare the minilllum factual statement h' h f 11 101 1C should includ_e, the o owing . a Time, date and location of incident b General factual description of what happened c Number of. injured or dead 00 NOT release names d Company 101111 provide update as more information becomes available B The statement should HOT include a Speculation on ca~ (State cause is not known but . Investigation) IS under b Estimate of dollar amount of damage ,; c Any s:atement which might Infer or admit Company negl' d Assum I~g res pons Ib i I ity for the sp ill Or C leanup unt\glenf~a 1 and executIve management have approved such a position ~hen warranted follow-up statements should be prepared by PGA office the appropriate 5 Procedures outlined will minimize distortions 1- - f n news reports protect th 1nterest 0 the Company and generally result in favorable handlin of the.e emergency by the media 9 3 4 1/91 Ex. 10 Director' Doug Youngblood 752-{j892 EH&S Inquiry Line: (713) 752-{j885 Environment Health and Safety Manager Environment Health & Safety Secretary E-QWllity Model Federal Register Rev,ew Support Litigation Tracking Support Retail Audit Program Environmental Affairs Manager Environmental Affairs Secretary Budget (Environmental RemediatIOn) En\'. Compliance Assurance Programs Information Systems National Environmental Database Third Party Claims - General lnfo. AIR Refining Marketing SOUD/HAZARDOUS WASTE Refining Marketi ng WATER Refining Marketing Marine Vapor Control Thnks Above/Underground Construction Support Closed Facilities Amarillo Bayonne / Changev.ater Casper Lockport Sunburst STAR ENTERPRISE Primary Pamck Tomlinson Missy Thomas Andy Moran Delilah Gauthia Gerri Reynolds John Sexton Primary Mike Meeuwsen Norma Rocha Ted Irvin Sheryl Maruca Delilah Gauthia Don Hitchcock JL^~l\.....V I"CIIIIIII~ ....-'1 ,-_" -, Environment, Health & Safety ext. Secondary ex\.. - 6888 6877 Sandy Tomme 6891 6905 6876 Gerri Reynolds 6885 6885 Hester Hanlon 6879 6887 Carol Papso 6884 ext. Secondary ext. 6939 6970 Missy Thomas 6877 6893 Hester Hanlon 6879 6875 Don Hitchcock 6880 6876 Gerri Reynolds 6885 6880 Gerri Reynolds 6885 Sheryl Maruca 6875 Les Lakie 6881 John Sexton 6887 Sheryl Maruca 6875 Fred Hamilton 6878 Don Hitchcock 6880 Don Hitchcock 6880 Fred Hamilton 6878 Duane Melton 6883 Russ Larson 6882 Russ Larson 6882 Duane Melton 6883 John Sexton 6887 Sheryl Maruca 6875 Greg Bolner 6958 John Sexton 6887 Sheryl Maruca 6875 Ted Irvin 6893 Les Lakie 6881 Ted Irvin 6893 Russ Larson 6882 Ted Irvin 6893 Duane Melton 6883 Ted Irvin 6893 John Sexton 6887 Ted Irvin 6893 Pre-elUsting Envllunmental Liabilities (PEL) RefIning Fred Hamilton Marketing Fred Hamilton Port Arthur Dale Friedrichs Health and Safetv Manager Health and Safety Secretary Compli2....'lce Audits & A.ssurdnce Pro. DOTffransportation Safety Hazard Communication/Product Safety Health Prornotion/Wellness Industrial Hygiene Loss Control/OSHA 200 Safcty Toxic Substances Control Act (TSCA) Fire ProtectionlEmergency Response Chronic Exposure LitJgation Process - Environmental Manager Process Envlfllllmental Secretary Refoml. Gasoline Research Reform. Gasoline EconomICS Alternative MOlnr Fuels Low Sulfur Diesel Low Aromatics 01=1 Oxygenates SupplvlTkmand Future Fuel SpcClfic.3t1ons Fuel Blending of L.....,v. EmiSSIon Prop. CIC2n Fuels Stratcg.\ Devcloplllcnt Primary Dav!d Watts Sandy Tomme D:lVid Noble Jay Wallace Carol I'dpSO Bert Benedick George Andis Jay Wallace DaVid Noble David Watts David Noble Carol Papso Primary Doug Hopkins Rose Williams Huey Zang Doug HopkInS Doug Hopkins Nonn Schultz Huey Zang Nonn Schultz Hucy Zang Nonn Schultz Doug Hopkins 6878 Les Lakie 6881 6878 Russ Larson 6882 6957 Les Lalue 6881 exL Secondary ext. 6890 6891 Norma Rocha 6970 6955 George Andis 6869 6889 David Noble 6955 6884 George Andis 6869 6870 Carol Papso 6884 6869 David 'MItts 6890 6889 6955 Jay Wallace 6889 6890 George Andis 6869 6955 Jay Wallace 6889 6884 David 'MItts 6890 exL Secondary ex\.. 6724 7626 Linda Burnett 6872 6871 Doug Hopkins 6724 6724 Huey Zang 6871 6724 Norm Schultz 6886 6886 Huey Zang 6871 6871 Nann Schultz 6886 6886 Doug HopkInS 6724 6871 Nann Schultz 6886 6886 Huey Zang 6871 6724 Huey Zang 6871 Nonn Schultz 6886 Ex. 11 Secretary' Linda Burnett 752-{j872 Fax: (713) 752-4686 Texaco Workgroups I Conuniuees Primary ex\.. Secondary - Texaco EH&S Council Doug Youngblood 6892 Patrick Tomlinson Mike Meeuwsen 6939 David Watt~ Texaco Environmental & Health Risk Management Comminee David Watts 6890 Texaco Hazard Communication Committee Carol Papso 6884 Texaco TSCA Depanmental Coordinators Comminee David Watts 6890 Texaco Cargo Transfer Task Fo= John Sexton 6887 Texaco Clean Air Act Work Group Sheryl Maruca 6875 Texaco Used Oil Commlllce Don Hitchcock 6880 Texaco Waste Action Comminee Duane Melton 6883 Les Lakie Regulatory Action Comminee On Fuels Norm Schultz 6886 Huey Zang Industrial or Trade Associations Primary ex\.. Secondary - Auto/Oil Air QWllity Improvement Research Program Doug Youngblood 6892 Doug Hopkins Huey Zang Amen= Petroleum Institute Mkt Operations and Engineering Subcomminee Patrick Tomlinson 6888 Mkt Environmental Subcommittee Don Hitchcock 6880 Air Toxics Task Fo= Sheryl Maruca 6875 Soil/GroundwaterTa.~k Fo= Russ La=n 6882 Mkt Terminal Effiuent Work Group Don Hitchcock 6880 Class V Injection Well Work Group Russ Larson 6882 Waste Task Force Don Hitchcock 6880 Oversight Work Group - Soil TrmL Tech. Russ La=n 6882 M\.:l. Facilities Suocommlttec (NFPA L"Hson) Don Hitchcock 6880 Health and EnvlronnlCnlal Affairs Dept. Dav Id 'MItts 6890 Committee on Safety and Fire Protection David 'MItts 6890 Committee on Rfg, Env. Control Les Lakie 6881 Manne Vessel EmiSSions Work Group John Sexton 6887 Storage Tank Ta.~k Force Greg Bolner 6958 John Sexton Aboveground Storage Tank Leak DetectIOn Work Group GfL'g Bainer 6958 John Sexton Soil/Groundw.ner lech Task f-orce Waste Min Task Force (Liaison Mkt) Don Hitchcock 6880 Used Oil Task Fo= (Liaison Mkt) Don Hitchcock 6880 Markeling Wa.'te Work Group Don Hitchcock 6880 Reg/Ncg Process - TItle IT of CAA Huey Zang 6871 National Fire ProtectIOn Association Dave Noble 6955 NFPA m"-API Representative Don Hitchcock 6880 National Plotroleum Refmers Assc. Fire and Accident Prevention DaVid Watts 6890 INSURANCE CARRIER INFORMATION Insurance Carrier: CIGNA - INA (206)-881-3700 Texaco Contact: Rick stuart vince Trulaje Ex. 12 \,~,~,.,,:-,~ \~~,: \ \ ~\\\;\~\i\;';~\\ \\\\\\,\\li\W', ~~~~~~~~~~,;:~1' ~' \ a -. If' '!.)( ci~ .,.. ~_. :r- (ltf'l'l ~u ~ ~ Exhibit E-5 TRAINING CHECKLIST _ 1 Established a thorough traming program. _ 2. Identified employees who need training. _ 3. Training program ensures that new employees are trained before their frrst assignment. 4 Infonned employees of the specific infonnation and training requirements of the Hazard Communication Standard. 5 Infonned employees of the requirements of the standard and their rights under the law _ 6. Infonned employees of the different chemicals at the workslte and the hazards associated With them. 7 Informed employees of the specific hazards of the chemicals and processes they work With and therr proper use and handhng. _ 8. Informed employees of the chemical hazards associated with performing any non-rout1Oe tasks. 9 Employees know how to detect the presence or release of hazardous chemicals 10 the statIon. _10 Tra.Ined employees in the use of proper work practIces, personal protectIve eqUlpment and cloth1Og, and other controls to reduce or eliminate theu exposure to the hazardous chemicals .In their work areas. 11 Tratned employees 10 emergency and fust-aId procedures and signs of overexposure _12. Employees know where the hazardous chemIcals are located .In the statIon, about the eXIstence of the Hazardous ChemIcals Inventory LISt, where It IS located and how It IS updated. 13 Obta1Oed Matenal Safety Data Sheets (MSDS) for each hazardous chemIcal (Texaco or other) 10 the statIon. _14 Explatned how to use and 10terpret a MSDS and 1Oformed employees where MSDS are located 10 the statIon. 15 Explatned labels and theu warn10gs to employees. Exhibit E-5, Page 2 16 Developed a system to ensure that all 1Ocom1Og hazardous chemicals are checked for proper labels and MSDS 17 Employees know the procedures to ensure proper labelhng or warnmg signs for con tamers that hold hazardous chemicals. 18 Developed a way to identIfy and inform employees of new hazardous chemicals before they are introduced mto the workplace. 19 Estabhshed a way to inform employees of new hazards associated with the chemicals they already use. _20 Developed a way to evaluate the effectIveness of the tram10g program and keep track of who has received trammg tJ · \t1fefPtF / r }A-zt1JYY'1 I\.J r--- ... ~ ~ ~ s ~ ~ ... .,. ~1+~Wrtj,\ t:~~~. \ ,) TABLE OF CONTENTS A. INTRODUCTION B OUR WRITTEN HAZARD COMMUNICATION PLAN EXHIBIT B-1 HAZARDOUS CHEMICALS INVENTORY EXHIBIT B-2 MSDS REQUEST LOG EXHIBIT B-3 EMPLOYEE TRAINING RECORD LOG C. MATERlAL SAFETY DATA SHEETS (MSDS) D-l GENERAL OVERVIEW OF OSHA HAZARD COMMUNICATION STANDARD D-2. GENERAL OVERVIEW OF HAZARDOUS WASTE OPERATIONS AND EMERGENCY RESPONSE" E. STEP-BY-STEP COMPLIANCE/CHECKLISTS EXHIBIT E-l HAZARD COMMUNICATION COMPLIANCE CHECKLIST EXHIBIT E-2 MSDS CHECKLIST EXHIBIT E-3 SAMPLE LEITER REQUESTING MSDS EXHIBIT E-4 SAMPLE LEITER REQUESTING ADDITIONAL MSDS INFORMATION EXHIBIT E-5 TRAINING CHECKLIST EXHIBIT E-6 TRAINING LESSON PLAN APPENDIX I OSHA HAZARD COMMUNICATION STANDARD APPENDIX II MSDS GLOSSARY APPEND IX III EXPLANATION GUIDE TO TEXACO MSDS APPENDIX IV EMERGENCY RESPONSE PROCEDURES (HAZWOPER) INTRODUCTION The OccupatIonal Safety and Health AdministratIon (OSHA) Issued a rule 10 1983 called the Hazard CommunIcatIon Standard (29 CFR 1910 1200). ThIS law covers all employees (includmg retaIl store personnel) who may be exposed to hazardous chemicals 10 the workplace. ThIS law IS based on the concept that employees have both a need and a nght to know the hazards of the chemIcals to WhICh they are exposed while worlong. The Hazard CommunIcatIon Standard was desIgned to reduce the incidence of chemical related illnesses and mJunes by malong both employees and employers aware of the potential hazards of the chemIcals 10 the workplace. In short, the purpose of this law and our Hazard CommunIcatIon Program IS to protect the health of our employees. The Hazardous Waste OperatIons and Emergency Response (HAZWOPER) Standard Final Rule went mto effect ill 1990 ThIS law was designed to protect employees dunng emergmg resPQn~es to hazardous substance releases. OUR WRITTEN HAZARD COMMUNICATION PROGRAM 1. PURPOSE AND SCOPE Our facihty has implemented a comprehensIve hazard communicatlon program to 1Oform our employees of the hazards of the chemicals in the workplace. This program will ensure comphance with the OSHA Hazard Communication Standard, (HCS) Title 29 of CFR 1910 1200 Under thIS program, you WIll be mformed of the contents of the HCS, the hazards of the chemIcals to WhICh you are exposed to at work, safe handhng procedures, and measures to take to protect yourselves from these hazardous chemicals. You will also be 1Oformed of the hazards of non-routine tasks. To accomphsh thIS, thIS hazard commumcatlon program 1Ocludes. A. A Hazardous Chemicals Inventory hst B Material Safety Data Sheets C Con tamer labels D Employee training ThIS program apphes to all work operatlons 10 our statlon where you as employees !llay be exposed to hazardous substances under normal working condltlOnS or dunng an emergency sItuation. This wntten program will be in tlns Hazard Communication Manual which WIll be kept 10 the statlon and made available to employees at all times. Caples of thIS program Will be provided by 7: 12-. m . r. upon request II. RESPONSIBILITY iJ?./?1/!.JA i3J";' .4N/lLVSr has overall responsIbility for the program unless otherwIse noted. HI will review and update the program as necessary Section B, Page I III. LIST OF HAZARDOUS CHEMICALS/CHEMICAL INVENTORY 5, A7J 0,.) /)14, J2.. . will maintaIn the list of all hazardous chemIcals present 10 the station. This 1Oventory wIll lIst the chemIcal, manufacturer's name and phone number and where 10 the station thIS chemIcal is used. ThIS lIst (ExhIbit B-l) IS part of our Written Hazard Communication Program and WIll be kept wIth10 thIS Hazard Communication Manual. This list will also serve as an index of our MSDS The lIst in ExhibIt B-1 is 10itially provIded generically and STlFTJDtJ /rlGt:tf!.. , IS responsible for review10g and updatIng this list to reflect all the hazardous matenals present at the facility. IV MATERlAL SAFETY DATA SHEETS Matenal Safety Data Sheets (MSDS) provide specific informatIon on the chemIcals we use Copies of MSDS for each chemIcal on our Hazardous Chemicals Inventory lIst will be kept in thIs Hazard CommunIcatl.on Manual under SectIon C, Matenal Safety Data Sheets. These MSDS will be available to all employees, 1Oclud1Og contract employees at all tImes. SrAllotJ m~2-. WIll ensure that there IS an MSDS for every chemical on the Hazardous ChemIcal Inventory He/she wIll be responsIble for obtam1Og an MSDS for any new hazardous chemIcal used 10 the station by contactIng the vendor or manufacturer If the MSDS has not been supplIed With the InItIal shipment. He/she will keep a MSDS Request Log (ExhIbit B-2) as part of thIS Wntten Program to document MSDS requests. He/she will also be responsible for ma1Ota1Omg and updatl.ng the MSDS file to 10sure it contaIns only the most current MSDS aVallable for each product. V LABELS All contaIners receIved or 10 use 10 the statIon must be labeled with the appropnate hazard communicatIon informatIon. .sTAT1~ rl1_1L-will ensure that all hazardous chemIcals 10 the statIon are properly labeled to 10clude the product IdentIty, manufacturer's name and address and appropnate hazard warn10g All contaIners of non- hazardous matenals will be labelled WIth the identIty of the matenal. If there IS any question on the proper labelIng of hazardous products, refer to the product MSDS to verify label 1Oformation. If there are hazardous chemIcals contained 10 statIOnary containers, the Station Manager WIll ensure that the statIonary container IS properly labelled. When a hazardous product IS transferred from a labelled contaIner to another conta1Oer (l.e., from large or bulk storage to a smaller portable contaIner), the person do1Og the transfemng is responsIble for ensuring the second contamer is properly labelled. If you transfer chemIcals from a labelled contalner to a portable contaIner that is mtended only for your ImmedIate use, no labels are reqUIred on the portable contaIner SectIon B, Page 2 VI. TRAINING ;- All employees will receive traIning in the Hazard Communication Standard and the safe handling and use of the hazardous chemicals used in our statIon prior to th~ assIgnment. This traming will be done by ':::'(JlTION vn.4ot~ , or 71<A-1 ~U7 S~lZ.r if\~12.- usmg written materials provIded 10 SectlOn E and ExhIbits -5 and E-6 of thIS manual and audIovISuals when avaIlable. Whenever a new hazard IS mtroduced into our station, additIonal trammg will be provIded to all employees. ..5-rATlolJ rnG.t~ , will ensure that all new employees are traIned at the tIme of thelI mitial assignment and whenever a new hazard IS mtroduced mto the station. A trainmg record (Exhibit B-3) will be kept to document employees traInmg. This record will be kept within this Written Hazard CommunIcatIon Program Manual. 5-rA nON MC:.tfl-. will also hold hazard commUnIcatIon reVIew meetIngs penodlcally to revIew the information presented in the 10itIal traInmg. The traill10g program wIll emphasize * ReView of the reqUlrements of the Hazard CommunIcatIon Standard. * ReView of the elements of our Written Hazard CommUnICatlOn Program which descnbes how the hazard communicatIon program IS Implemented ill our statIon. * Where the Wntten Hazard CommunIcatIon Program, Hazardous Chemical Inventory and MSDS's are kept. * How to read and 10terpret the mformatIon on labels and MSDS, and how employees may obtam addItional mformation. * The chemIcal and physical propertIes (flash pomt, bOlhng pomt, reactIvIty, etc ) of hazardous chemIcals 10 our statIon and methods and observatIons (VISUal appearance, smell, etc.) whIch can be used to detect the presence or release of chemIcals. * PhYSICal hazards (potentIal for [lIe, explosion, etc.) of products in the work area. * Health hazards, 1Oclud1Og SIgns and symptoms of exposure, assocIated WIth exposure to chemIcals and any medical condition that may occur or be aggravated by exposure to the chemIcal. * Measures employees can take to protect themselves from the hazards (personal protectIve eqmpment, proper work practIces, emergency response procedures, etc.) Section B, Page 3 VII. NON-ROUTINE TASKS When you are requIred to perfonn non-routme tasks involving exposure to hazardous chemicals, a special trammg sesslOn will be conducted to infonn you about the hazardous chemicals to WhICh you mIght be exposed and the proper precautIOns to take to reduce or avoid exposure. ::S11t7iON m"e.. will Identify those special projects that are consIdered hazardous and will provIde the appropriate trammg. Vill. CONIRACTORS :SiA77CJN rrJte,l!.. will advISe outsIde contractors, who are worlang on the premises, of the hazards of the chemicals they may become exposed to dunng their work. He will also infonn the contractors of the location and availabilIty of the MSDS' s, protective measures to be taken and the safe handlIng procedures to be used when working WIth the hazardous chemIcals. If a contractor bnngs a hazardous chemIcal onto our statIon premIses, he must provIde the MSDS and any addItIonal hazard 1OfonnatIon on thIS chemIcal (includmg the precautIonary measures to be'taken) to the facIlIty manager Srl'f77tJN ntd.,l!.... will msure that all employees potentIally exposed to thIS chemIcal are mformed of Its hazards and handling IX. EMERGENCY RESPONSE TO HAZARDOUS MATERIAL RELEASES Employees of thIS faCIlIty are classified as "First Responders Awareness Level" when dealmg WIth uncontrolled releases of hazard~ous matenals WhICh present a safety or health hazard per the OSHA regulatIon 29 CFR 1910 120 (q) (ie. HAZWOPER) Uncontrolled releases are releases WhICh cannot be absorbed, neutralIzed or controlled at the tIme of the release by employees 10 the ImmedIate release area. Uncontrolled releases typIcally requIre response efforts by outside personnel such as fIre departments or hazardous matenal response teams. Examples of possible uncontrolled releases are. - Hit dispenser - Delivery truck spIlls SectIon B, Page 4 " ~): In the event of an uncontrolled release employees are expected to notify the proper authorities (ie. fIre department. station manager, marketing representative, mamtenance center, etc.) and actIvate the remote emergency dispenser shut-off devIce. They are not expected to attempt to approach the point of release to stop the source or to try to contain the release. See ExhibIt E-6 (Hazard CommunicationlEmergency Response Training Program, SectIon 9 0) and Appendix IV (Emergency Response Procedures) of thIS manual. Section B, Page 5 . \ .,."C .', ~~~?~~??~~ \. \ ~';i'\\\';~;\\\;".' ~\.\, ~"'~\'l" ,l 'l;ll' !~\ ~~ \ \ ~~"" ~',~, ~,\~1~ , \ \ ; -~'\% Page 1 EXHIBIT B-1 HAZARDOUS CHEMICALS INVENTORY LIST AND INDEX OF MSDS'S MSDS MANUFACTURER AREA ON HAZARDOUS CHEMICAL NAM ElPH ONE USED FILE Motor Gasolines Texaco Regular Texaco (914) 831-3400 Texaco Unleaded Texaco (914) 831-3400 Texaco Unleaded Plus Texaco (914) 831-3400 Texaco Super Unleaded Texaco (914) 831-3400 ~ . - Diesel Fuels Texaco DIesel 2 Texaco (914) 831-3400 Antifreeze Texaco Anufreeze/Coolant Texaco (914) 831-3400 Page 2 EXHIBIT B-1 HAZARDOUS CHEMICALS INVENTORY LIST AND INDEX OF MSDS'S MSDS MANUFACTURER AREA ON HAZARDOUS CHEMICAL NAM EJPH ONE USED FILE Motor Oils Havol..me Supenor Grade Texaco (914) 831-3400 Motor 011 SAE 30 Havo1me Supenor Grade Texaco (914) 831-3400 Motor OIl SAE 40 Havo1me Supenor Grade Texaco (914) 831-3400 Motor 011 SAE 5W - 30 - , Havolme Supenor Grade Texaco (914) 831-3400 Motor OU SAE 10W-30 Havohne Supenor Grade Texaco (914) 831-3400 Motor 011 SAE lOW -40 Havolme Supenor Grade Texaco (914) 831-3400 Motor Ou SAE 20W-50 ~ Others - - ~~ .;';" E~h1b1t B-2 MSDS REQUEST RECORD \~~~i~;~~ \'-j PRODUCT MANUFACTURER DATE MSOS DATE MSDS NAME NAME REQUESTED RECEIVED ~ I ~ I . l'~~~~~ " ' l' ,'. \' fmmtllllli f. ~".i~;5' ~;~: i ,<<'~!~ EXHIBIT B-3-A OFFICIAL TRAINING RECORD Employees lIsted below acknowledge hav10g receIved the traInIng outlIned In the Hazard CommunIcations Lesson Plan 10 ExhibIt E-5 of this manual. DATE TRAINED EMPLOYEE NAME EMPLOYEE SIGNATURE TRAINED BY , " EXHIBIT B-3-B OffiCIAL TRAINlNG RECORD Employees hsted below acknolwedge hav10g receIved addltlonal Hazard CommunIcatIon tra1010g reqmred when a new hazard is 1Otroduced 1Oto the work area. ThIS tralnIng included revIewmg the MSDS of the specific chemical involved. NEW EMPLOYEE DATE HAZARD TRAINED EMPLOYEE NAME SIGNA TURE TRAINED MSDS BY ~ " ~~ , \:i:''i;}''~' : ;.~~\\~' ' , ,\\\\~'\~\\\' ,\~,\'A'\" ~;\~~\\;\lY , Date Issued Supersedes' 01-03-96 12-08-95 NOTE Read and TEXACO MATERIAL SAFETY DATA SHEET understand Material Safety Data Sheet before handling or disposing of product 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL IDENTITY Product Code and Name 26000 UNLEADED REGULAR GASOLINE Chemical Name and!or Family or Description Automotive Lead-Free Gasoline Manufacturer's Name and Address TEXACO REFINING AND MARKETING, INC POBox 7812 Universal City, CA 91608 Telephone Numbers Transportation Emergency-Company CHEMTREC -Company Health Emergency General MSDS Assistance Technical Information -Fuels -Chemical -Lubricant! Antifreezes -Additives -Solvents (914) 831-3400 (800) 424-9300 (914) 831-3400 (914) 838-7204 (914) 838-7336 (512) 459-6543 (800) 782-7852 (713) 235-6278 (800) 876-3738 This Material Safety Data Sheet may be used for the following products for Hazard Communications purposes only, not intended to imply identical performance/technical specifications 00315 UNLEADED REGULAR GASOLINE (7 8#) 00323 TEXACO REGULAR UNLEADED BLENDSTOCK w/ETHANOL 00326 TEXACO UNLEADED GAS (RVP 7 8#) 00330 CALIFORNIA UNBRANDED UNLEADED REGULAR 00334 REGULAR UNLEADED BLENDSTOCK w/ETHANOL 00351 UNLEADED REGULAR GASOLINE 00353 TEXACO UNLEADED GAS W/ OXY 00354 UNLEADED REGULAR GASOLINE W/ETHER OXY 00356 UNLEADED WITH ETHANOL 00358 TEXACO REGULAR W/ ETHER OXY 00362 TEXACO REGVL~R WITH ETHANOL 00365 TEXACO UNLEADED GASOLINE 00371 UNLEADED REGULAR GASOLINE 00376 TEXACO UNLEADED GASOLINE w/ETHANOL 00384 MARYLAND GRADE UNLEADED REGULAR GASOLINE 00458 TEXACO UNLEADED REGULAR GASOLINE w/5 7% ETOH 00469 UNLEADED REGULAR GASOLINE w/5 7% ETHANOL 00476 UNLEADED REGULAR OXYGENATED 00478 ADDITIZED UNLEADED REGULAR OXYGENATED 00485 TEXACO UNLEADED REGULAR GASOLINE w/7 7% ETOH 00496 UNLEADED REGULAR GASOLINE w/7 7% ETHANOL 01108 CITGO RFG REGULAR UNLEADED 87 01112 TEXACO UNLEADED GASOLINE (RFG 2 0) 01116 TEXACO UNLEADED GASOLINE (RFG 2 7) OXY 01125 TEXACO UNLEADED GASOLINE (RFG 2 0) 7 2 RVP 01132 TEXACO UNLEADED GASOLINE (RFG 2 0) 8 1 RVP 01136 UNLEADED GASOLINE (RFG 2 0) 01141 UNLEADED GASOLINE (RFG 2 7) OXY 01145 UNLEADED GASOLINE (RFG 2 0) 7 2 RVP 01149 UNLEADED GASOLINE (RFG 2 0) 8 1 RVP 01166 TEXACO UNLEADED REGULAR GASOLINE (7 2 RVP) 01182 UNLEADED REGULAR GASOLINE 01193 TEXACO UNLEADED REGULAR (MIN 1 8 OXY) 01199 UNLEADED REGULAR GASOLINE (MIN 1 8 OXY) 01243 UNLEADED REGULAR RFG 2 0 OPRG NOT-VOC 02632 FORD UNLEADED GASOLINE (RFG) 02635 FORD UNLEADED GASOLINE (RFG) 7 2 RVP 02752 UNLEADED REGULAR - CARB PHASE 2 RFG 02753 TEXACO UNLEADED REGULAR - CARB PHASE 2 RFG 02754 UNLEADED REGULAR - CARB PHASE 2 RFG - ADDITIZED PAGE 1 N D - NOT DETERMINED N A - NOT APPLICABLE N T - NOT TESTED < - LESS THAN > - GREATER THAN Lf t-: ^ iiiill ~ (~~ Date Issued 01-03-96 Supersedes. 12-08-95 PRODUCT CODE: 26000 ,-<. NAME UNLEADED REGULAR GASOLINE 2 COMPOSITION/INFORMATION ON INGREDIENTS THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS FOLLOWS CARCINOGENS ARE LISTED WHEN PRESENT AT 0 1 % OR GREATER, COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN PRESENT AT 1 0 % OR GREATER, NON-HAZARDOUS COMPONENTS ARE LISTED AT 3 0 % OR GREATER THIS IS NOT INTENDED TO BE A COMPLETE COMPOSITIONAL DISCLOSURE REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND OTHER REGULATORY INFORMATION Product and/or Component(s) Carcinogenic According to OSHA IARC NTP OTHER NONE X X ~ r Composition (Sequence Number and Chemical Name) ~ Chemical Name CAS Number Range in % Gasoline consists of straight/branched paraffinic hydrocarbons olefins, cycloparaffins and aromatics Mayor may not contain any combination of these oxygenates MTBE, ETBE, TAME and/or EtOH in the range of 0-20% Typ- ical constituents (not intended as manufacturing specifications) include 01 * Gasoline 95 00-99 99 02 * Methyl-t-butyl ether 1634-04-4 10 00-19 99 03 * Ethyl-t-butyl ether 637-92-3 10 00-19 99 04 * Tertiary amyl methyl ether 994-05-8 10 00-19 99 05 * Ethyl alcohol 64-17-5 3 00-9 99 06 * Xylenes 1330-20-7 3 00-9 99 07 * Toluene 108-88-3 3 00-9 99 08 * Benzene (if RFG, 0 99% max ) 71-43-2 1 00-2 99 09 * 1 2 4-trimethylbenzene 95-63-6 1 00-2 99 10 * N-hexane 110-54-3 1 00-2 99 11 * Ethylbenzene 100-41-4 1 00-2 99 PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910 1200) * COMPONENT IS HAZARDOUS ACCORDING TO OSHA Exposure Limits referenced by Sequence Number in the Composition Section ~ Limit 01 01 01 01 02 02 05 05 06 06 06 06 07 07 07 08 08 08 09 09 10 10 11 11 1 1 11 300 500 300 100 40 40 1000 1000 100 150 100 150 100 150 50 1 5 10 25 25 50 50 100 125 100 125 ppm TWA-OSHA ppm STEL-OSHA ppm TWA-ACGIH ppm TWA-TEXACO ppm TWA-ACGIH (A3) ppm TWA-TEXACO ppm TWA-OSHA ppm TWA-ACGIH ppm TI;'A-OSHA ppm STEL-OSHA ppm TWA-ACGIH ppm STEL-ACGIH ppm TWA-OSHA ppm STEL-OSHA ppm TWA-ACGIH (SKIN) ppm TWA-OSHA (SUBJECT TO 29 CFR 1910 1028) ppm STEL-OSHA ppm TWA-ACGIH-(A2) ppm TWA-OSHA ppm TWA-ACGIH ppm TWA-OSHA ppm TWA-ACGIH ppm TWA-OSHA ppm STEL-OSHA ppm TWA-ACGIH ppm STEL-ACGIH 3 HAZARD IDENTIFICATION EMERGENCY OVERVIEW Appearance Light red to light straw liquid Odor PetrOleum odor PAGE 2 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED N D - NOT DETERMINED < - LESS THAN hi. 'L ~~~ !{f;;; ~: PRODUCT CODE 26000 NAME UNLEADED REGULAR GASOLINE 3. HAZARD IDENTIFICATION (CONT) Date Issued supersedes. 01-03-96 12-08-95 DANGER WARNING STATEMENT EXTREMELY FLAMMABLE LIQUID AND VAPOR VAPOR MAY CAUSE FLASH FIRE MAY CAUSE DIZZINESS AND DROWSINESS MAY CAUSE IRRITATION TO EYES AND RESPIRATORY TRACT ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE POSSIBLE CANCER HAZARD - MAY CAUSE CANCER BASED ON ANIMAL DATA ATTENTION HMIS NFPA Health 1 Reactivity 0 Health 1 Reactivity 0 Flammabil ity 3 Special Flammability 3 Special POTENTIAL HEALTH EFFECTS EYE SKIN INHALATION INGESTION Primary Route of Exposure ~ ~ ~ EFFECTS OF OVEREXPOSURE Acute Eyes May cause irritation, experienced as mild discomfort and seen as slight excess redness of the eye Skin Brief contact may cause slight irritation Prolonged contact as with clothing wetted with material, may cause more severe irritation and dis- comfort, seen as local redness and swelling Other than the potential skin irritation effects noted above acute (short term) adverse effects are not expected from brief skin contact see other effects below and Section 11 for information regarding potential long term effects Prolonged widespread, or repeated skin contact may result in the absorption of potentially harmful amounts of material Inhalation Vapors or mist may cause irritation of the nose and throat Inhalation may cause dizziness drowsiness euphoria loss of coordination disorientation headache nausea and ~oTiting In poo~ly ventilated areas or confined spaces unconsciousness and asphyxiation may result Prolonged or repeated overexposure may result in the absorption of potentially harmful amounts of material Ingestion If more than several mouthfuls are swallowed abdominal discomfort nausea and diarrhea may occur Aspiration may occur during swallowing or vomiting resulting in lung damage Sensitization Properties Unknown Chronic Prolonged and repeated exposure to ethanol vapor may cause headache lack of coordination sleepiness fatigue, and difficulty concentrating Chronic ingestion of alcoholic beverages has resulted in liver, stomach, heart and nervous system damage as well as cancers of the mouth pharynx, larynx esophagus and liver in humans Repeated ingestion of ethanol by pregnant women has caused miscarriage, premature birth and low birth weight and birth defects (Fetal Alcohol Syndrome) Medical Conditions Aggravated by Exposure Because of its irritating properties, repeated skin contact may aggravate an existing dermatitis (skin condition) .~~~~~;~\~ \,' PAGE 3 - NOT APPLICABLE - GREATER THAN - NOT TESTED N T N D < - NOT DETERMINED - LESS THAN N A > .&(~ --~~ -, PRODUCT CODE 26000 NAME UNLEADED REGULAR GASOLINE 3 HAZARD IDENTIFICATION (CONT) Date Issued Supersedes 01-03-96 12-08-95 Other Remarks This product contains benzene Prolonged and repeated exposure to benzene may cause headaches, loss of appetite rapid pulse. fatigue, liver and kidney damage decreased bone-marrow activity with increased bleeding tendencies and possible irreversible injury to blood forming organs Prolonged and repeated overexposure to benzene has been associated with aplastic anemia and acute myelogenous leukemia in humans 4 FIRST AID MEASURES Eyes Immediately flush eyes with plenty of water for at least 15 minutes Hold eyelids apart while flushing to rinse entire surface of eye and lids with water Get medical attention Skin Wash skin with plenty of soap and water for several minutes attention if skin irritation develops or persists Get medical Ingestion If person is conscious and can swallow. give two glasses of water (16 oz but do not induce vomiting If vomiting occurs give fluids again Have medical personnel determine if evacuation of stomach or induction of vomiting is necessary Do not give anything by mouth to an unconscious or convulsing person Inhalation If inhaled remove to fresh air If not breathing or in respiratory distress clear person's airway and start artificial respiration With a physician's advice give supplemental oxygen using a bag-valve mask or manually triggered oxygen supply Other Instructions Aspiration of this product during induced emesis may result in severe lung injury If evacuation of stomach is necessary use method least likely to cause aspiration such as gastric lavage after endotracheal intubation Contact a Poison Center for additional treatment information Remove and dry-clean or launder clothing soaked or soiled with this material before reuse Dry cleaning of contaminated clothing may be more effective than normal laundering Inform individuals responsible for cleaning of potential hazards associated with handling contaminated clothing 5 FIRE-FIGHTING MEASURES Ignition Temperature - AIT (degrees F) 850 Flash Point (degrees F) -40 (PMCC) Flammable Limits (%) Lower 1 4 Upper 7 6 Recommended Fire Extinguishing Agents And SpeCial Procedures Water may be ineffective on flames but should be used to cool fire-exposed containers and provide protection for persons atempting to stop the leak Use water spray dry chemical alcohol resistant foam or carbon dioxide to extinguish fire Unusual or Explosive Hazards Gasol ine vapors are heavier than air and may travel a considerable distance to a source of ignition and flash back Flowing gasoline can generate static electricity and cause a fire explosion if a spark occurs in a flammable vapor-air atmosphere When handling use non-sparking tools, ground and bond all containers Extremely flammable can be ignited by heat. spark, or flame N 0 - NOT DETERMINED < - LESS THAN PAGE 4 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED Jf,~ ~L~ /~, ! PRODUCT CODE 26000 NAME UNLEADED REGULAR GASOLINE 5 FIRE-FIGHTING MEASURES (CONT) Date Issued supersedes 01-03-96 12-08-95 Special Protective Equipment for Firefighters Wear full protective clothing and positive pressure breathing apparatus 6 ACCIDENTAL RELEASE MEASURES (Transportation Spills CHEMTREC (800)424-9300) Procedures in Case of Accidental Release, Breakage or Leakage Eliminate all ignition sources including internal combustion engines and power tools Ventilate area Barricade the immediate hazard area Stay upwind and warn of possible downwind explosion hazard Avoid breathing vapor Avoid contact with skin, eyes, or clothing Pressure demand air supplied respirators should always be worn when the airborne concentration of the contaminant or oxygen is unknown Otherwise, wear respiratory protection and other personal protective equipment as appropriate for the potential exposure hazard Contain spill if possible Remove with inert absorbent Prevent entry into sewers and waterways If more than 714 pounds of product is spilled. then report spill according to SARA 304 and/or CERCLA 102(a) requirements, unless product qualifies for the petroleum exemption (CERCLA Section 101(14)) 7 HANDLING AND STORAGE Precautions to be Taken in Handling Use spark-proof tools Material may be at elevated temperatures and/or pressures Exercise care when opening bleeders and sampling ports Storage Ground and bond shipping container Keep away from heat sparks, flame transfer line and receiving container and other sources of ignition 8 EXPOSURE CONTROLS/PERSONAL PROTECTIO~ Protective Equipment (Type) Eye/Face Protection Safety glasses chemical type goggles, or face shield recommended to prevent eye contact Sk i n Protect i on Gloves resistant to petroleum distillates are recommended to minimize skin contact The most effective glove materials are Nitrile rubber Teflon or ~iton for prolonged contact with gasoline Protective clothing such as coveralls or boots should be also be worn where contact with product is 1 ikely Launder or dry clean soiled clothes Respiratory Protection Airborne concentrations should be kept to lowest levels possible If vapor mist or dust is generated and the occupational exposure limit of the product or any component of the product is exceeded use appropriate NIOSH or MSHA approved air purifying or air supplied respirator after determining the airborne concentration of the contaminant Air supplied respirators should always be worn when airborne concentration of the contaminant or oxygen content is unknown Ventilation Use explosion-proof equipment to maintain adequate ventilation to meet occupational exposure limits if applicable (see below) prevent accumulation of explosive air-gas mixtures, and avoid significant oxygen displacement Oxygen levels should be at least 19 5% in confined spaces or other work areas (OSHA value) Exposure Limit for Total Product Gasol ine OSHA PEL-TWA 300 ppm, ACGIH TLV-TWA 300 ppm TEXACO TLV-TWA 100 ppm STEL 500 ppm STEL 500 ppm .;<' '\: PAGE 5 - NOT APPLICABLE - GREATER THAN - NOT TESTED N T N 0 < - NOT DETERMINED - LESS THAN N A > L~ ,~~ PRODUCT CODE 26000 NAME UNLEADED REGULAR GASOLINE Date Issued 01-03-96 Supersedes:, .12-08-95 ,j 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Light red to light straw liquid Odor Petroleum odor Boiling Point (degrees F) > 90 Melting/Freezing point (degrees F) Not appl icable Specific Gravity (water=1) 7 - 77 pH of undiluted product Not applicable Vapor Pressure 300 - 700 mmHg at 100 0 Viscosity ~ 1 4 cSt at 37 7 C VOC Content Not determined Vapor Density (air=1) 3 - 4 SolUbility in Water (%) 1 - 1 Other None 10 STABILITY AND REACTIVITY This Material Reacts Violently With (If Others is checked below see comments for details) Air Water Heat Strong Oxidizers Others None of These X X - - Comments None Products Evolved When Subjected to Heat or Combustion Toxic levels of carbon monoxide carbon dioxide irritating aldehydes and ketones Hazardous Polymerizations DO NOT OCCUR 11 TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA) Median Lethal Dose Oral LD50 Believed to be > 5 00 g/kg (rat) practically non-toxic Inhalation Not determined Dermal LD50 Believed to be > 2 00 g/kg (rabbit) practically non-toxic Irritation Index, Estimation of Irritation (Species) Skin (Draize) Believed to be > Eyes (Draize) Believed to be > 15 00 - 25 00 /110 (rabbit) slightly irritating Sensitization Not determined Other Studies in laboratory rats and mice exposed to constant levels of wholly vaporized unleaded gasoline for six hours per day. five days per week for two years caused kidney damage and kidney cancer in male rats and liver tumors in female mice Many scientists do not believe that the male rat is an appropriate predictor of human kidney disease and are not in agreement PAGE 6 N A - NOT APPLICABLE - GREATER THAN 50 - 3 00 /8 0 (rabbit) slightly irritating N D < - NOT DETERMINED - LESS THAN N T - NOT TESTED > Ar': \:;". ~~ .2\t~~ u .,..:- it,__ . ',-'- i>~ <.' ~ I i..: PRODUCT CODE 26000 NAME UNLEADED REGULAR GASOLINE 11 TOXICOLOGICAL INFORMATION (CONT) Date Issued Supersedes 01-03-96 12-08-95 on the relationship between liver tumors in laboratory animals and humans Prolonged and repeated exposure to benzene has caused anemia lymphoma, and other cancers, in laboratory animals Benzene has been shown to cause embryo/fetal toxicity and birth defects in laboratory animals, but only at doses which cause maternal toxicity (i e illness in the mother) Chronic ingestion of ethanol, a possible component of this product, has caused birth defects as well as developmental effects in laboratory animals Prolonged and repeated exposure of rats to high levels of TAME vapor resulted in 25% mortality at the highest dose level and produced transient CNS depression (sedation, incoordination, reduced activity) Body and organ weight changes were observed without underlying tissue pathology (i e changes to the tissue) A repeated oral study with TAME in rats resulted in two deaths in the high dose group There were no treatment related tissue changes in any of the organ systems evaluated although there were body and organ weight changes TAME was judged to produce an overall low order of toxicity In male mice prolonged and repeated exposure to high levels of MTBE vapor produced a higher than expected mortality due to urinary tract obstruction believed caused by physical non-neoplastic blockage of the urethral canal In female mice data indicate increased incidence of hepatocellular adenomas (benign liver tumors) Prolonged and repeated exposure to high levels of MTBE (up to 8000 ppm for over 15 months) resulted in excess mortality (82 %) in male rats Preliminary evaluation showed a chronic progressive nephrosis (kidney damage) as the possible cause of death Associated with the increased severity of nephropathy was an increase in the number of renal tubular cell adenomas (benign kidney tumors) and carcinomas (malignant kidney tumors) There was also a difference in the number of testicular interstitial cell adenomas (benign testicular tumors) MTBE has been shown to cause embryo/fetal toxicity and birth defects in mice but only at maternally toxic doses No developmental effects were seen in rabbits at the same exposure levels Although the significance of these findings to humans is unclear workers should minimize exposure to MTBE vapor Additional or repeat studies are planned or underway to better define the toxic potential of this product or to verify the results obtai~ed from previous animal studies 12 DISPOSAL CONSIDERATIONS Waste Disposal Methods This product (as presently constituted) has the RCRA classification of benzene toxicity and ignitability If discarded in its present form it would have the hazardous waste numbers 0018 and 0001 respectively Under RCRA it is the responsibility of the user of the product to determine at the time of disposal whether the product meets RCRA criteria for hazardous waste This is because product uses transformations mixtures processes etc may change the classification to non-hazardous, or hazardous for reasons other than or in addition to benzene toxicity and igni tabi 1 ty Remarks Do not allow to enter drains or sewers Can cause explosion PAGE 7 - NOT APPLICABLE - GREATER THAN - NOT TESTED N T N 0 < - NOT DETERMINED - LESS THAN N A > A:\U. ~~~ PRODUCT CODE: 26000 NAME UNLEADED REGULAR GASOLINE 13 TRANSPORT INFORMATION Date Issued Supersedes 01-03-96 12-08-95 Transportation DOT Proper Shipping Name Gasol ine Hazard Class 3 Identification Number UN1203 Packing Group II Label Required Flammable liquid Marine pollutant Not applicable This product contains a DOT Hazardous SUbstance or Substances. listed in Section 14 of the MSDS If the product's shipping container holds at least 714 lbs, then the DOT information must be accompanied with RQ notation. or an otherwise 'Not Regulated' product will be classified as Environmentally Hazardous (solid/liquid) NOS. Class 9, unless the product qualifies for the petroleum exemption (49 CFR 171 8) IMDG Proper Shipping Name Not evaluated ICAo Proper Shipping Name Not evaluated TOG Proper Shipping Name Not evaluated 14 REGULATORY INFORMATION Federal Regulations SARA Ti t 1 e II I Section 302/304 Extremely Hazardous Substances ~ Chemical Name CAS Number None Section 302/304 Extremely Hazardous Substances (CONT) ~ TPQ RQ None Section 311 Hazardous Categorization Acute Chronic Fire Pressure X X X React i ve N/A Section 313 Toxic Chemical Chemical Name Methyl-t-butyl ether Xylenes Toluene Benzene (if RFG 0 99% max ) 1 2 4-trimethylbenzene N-hexane Ethylbenzene CAS Number 1634-04-4 1330-20-7 108-88-3 71-43-2 95-63-6 110-54-3 100-41-4 CERCLA 102(a)/DOT Hazardous Substances ~ Chemical Name 01+ Methyl-t-butyl ether 02+ Xylenes 03+ Toluene 04+ Benzene (if RFG 0 99% max ) 05+ Ethylbenzene 06+ N-hexane 07+ Benzene, (1-methylethyl) - Ran<:Je in % Concentration 10 00- 19 99 3 00-9 99 3 00-9 99 1 00-2 99 1 00-2 99 1 00-2 99 1 00-2 99 (+ indicates DOT Hazardous Substance) CAS Number 1634-04-4 1330-20-7 108-88-3 71-43-2 100-41-4 110-54-3 98-82-8 N 0 - NOT DETERMINED < - LESS THAN PAGE 8 N A - NOT APPLICABLE > - GREATER THAN Ran<:Je in % 10 00- 19 99 3 00-9 99 3 00-9 99 1 00-2 99 1 00-2 99 1 00-2 99 o 01-0 09 N T - NOT TESTED ,..:f-';"'~, A'..F ~...,. W;". ~lti... tqJ.~ ,.;r-:,i; .~: ,;.. PRODUCT ,CODE 26000 NAME UNLEADED REGULAR GASOLINE 14 REGULATORY INFORMATION (CONT) Date Issued supersedes 01-03-96 12-08-95 CERCLA/OOT ~RQ 01+ 02+ 03+ 04+ 05+ 06+ 07+ Hazardous Substances (Sequence Numbers and RQ's) 1000 100 1000 10 1000 5000 5000 TSCA Inventory Status This product, or its components, are listed on or are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance Inventory Other None State Regulat;ons Cal;forn;a Propos;t;on 65 The following detectable components or belong to classes of substances, to cause cancer and/or reproductive Chemical Name Gasoline Toluene Benzene (if RFG 0 99% max ) of this product are substances known to the State of California toxicity CAS Number 108-88-3 71-43-2 States Right-to-know Regulat;ons Chemical Name Toluene Benzene, (1-methylethyl) - Benzene (if RFG 0 99% max Gasol ine Ethylbenzene N-hexane Xylenes Methyl-t-butyl ether Ethyl alcohol 1 2 4-trimethylbenzene State Right-to-know CT FL IL MA NJ PA RI MI CT,FL,IL MA NJ,PA RI MI CT FL,IL MA NJ PA RI MI CT FL IL,LA MA NJ RI CT FL,IL MA NJ PA RI CT,FL,IL MA NJ PA RI CT FL,IL MA NJ PA RI MI MA,NJ,PA CT FL,IL,MA NJ,PA RI MA NJ PA State list CT (Connecticut) FL (Florida) IL (Illinois) MI (Michigan) LA (Louisiana) MA (Massachusetts) NJ (New Jersey) PA (Pennsy10a~ia) RI (Rhode Island) International Regulations Export Notification (TSCA-12b) This product may be subject to export notification under TSCA section 12(b) contains Methyl-t-butyl ether Tertiary amyl methyl ether WHMIS Classif;cation Not determined Canada Inventory Status Not determined EINECS Inventory Status Not determined Australia Inventory Status Not determined uapan Inventory Status Not determined 15 ENVIRONMENTAL INFORMATION Aquatic Toxicity Not determined N D - NOT DETERMINED < - LESS THAN PAGE 9 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4. .~~~ PRODUCT CODE: 26000;, NAME UNLEADED REGULAR GASOLINE 15 ENVIRONMENTAL INFORMATION (CONT) --- Date Issued supersedes 01-03-96 12-08-95 Mobility Not determined Persistence and Biodegradability Not determined Potential to Bioaccumulate Not determined Remarks None 16 OTHER INFORMATION THIS PROOUCT IS INTENDED FOR USE AS A MOTOR FUEL ONLY Texaco recommends that all exposures to tHis product be minimized by strictly adhering to recommended occupational controls procedures to avoid any potential adverse health effects Texaco has notified EPA of a TSCA 8(e) Notice of Substantial Risk to Health on the basis of results from a range finding developmental toxicity study for this product or a component of this product A definitive developmental toxicity study is underway THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT FOR PURPOSE OF HAZARD COMMUNICATION AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM IT IS NOT INTENOED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT NO EXPRESS WARRANTY OR IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION CONTAINED HEREIN DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY PROCESS USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN TO DETERMINE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY TEXACO DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS Since the last mailing;f~r this customer code, the following sections have been revised 1 2 6 11 14 16 17 Date 01-03-96 Date printed 02-05-96 New .0. Revised Supersedes 12-08-95 Inquiries regarding MSDS should be directed to Texaco Inc Manager Product Safety POBox 509 Beacon N Y 12508 PLEASE SEE NEXT PAGE FOR PRODUCT LABEL N D - NOT DETERMINED < - LESS THAN PAGE 10 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED ~'- ..,,~~ " '-'I'-'..~' ~ . '.1';..... ,,", ~, . -....,'.. "." ~~~: PRODUCT CODE 26000 NAME UNLEADED REGULAR GASOLINE 01-03-96 12-08-95 17 PRODUCT LABEL Date Issued Supersedes Label Date 12-08-95 READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING DR DISPOSING OF PRODUCT THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910 1200) FOR USE IN THE WORKPLACE THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS 26000 UNLEADED REGULAR GASOLINE WARNING STATEMENT DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR VAPOR MAY CAUSE FLASH FIRE MAY CAUSE DIZZINESS AND DROWSINESS MAY CAUSE IRRITATION TO EYES AND RESPIRATORY TRACT ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE ATTENTION POSSIBLE CANCER HAZARD - MAY CAUSE CANCER BASED ON ANIMAL DATA PRECAUTIONARY MEASURES -Keep away from heat, sparks or flame -Use only with adequate ventilation -Avoid breathing vapor, mist or gas -Avoid contact with eyes skin, and clothing -keep container closed -Never siphon by mouth -Wash thoroughly after handling FIRST AID Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes Hold eyel ids apart while flushing to rinse entire surface of eye and lids with water Get medical attention Skin Contact Wash skin with plenty or soap and water for several minutes attention if skin irritation develops or persists Ingestion If person is conscious and can swallow give two glasses of water (16 OZ but do not induce vomiting If vomiting occurs give fluids again Have medical personnel determine if evacuation of stomach or induction of vomiting is necessary Do not give anything by mouth to an unconscious or convulsing person Inhalation If inhaled remove to fresh air If not breathing or in respiratory distress clear person's air~ay and start artificial respiration With a physician's advice give supplemental oxygen using a bag-valve mask or manually triggered oxygen supply Note to Physician Aspiration of this product during induced emesis may result in severe lung injury If evacuation of stomach is necessary use method least likely to cause aspiration such as gastric lavage after endotracheal intubation Contact a Poison Center for additional treatment information FIRE use water spray dry chemical alcohol resistant foam or Water may be ineffective on flames Use water spray to keep and protect personnel attempting to stop the leak Get medical In case of fire carbon dioxide containers cool If more than 714 pounds of product is spilled then report spill according to SARA 304 and/or CERCLA 102(a) requirements, unless product qualifies for the petroleum exemption (CERCLA Section 101(14)) Chemical Name CAS Number RanQe in % Gasoline consists of straight/branched paraffinic hydrocarbons olefins cycloparaffins and aromatics Mayor may not contain any combination of these oxygenates MTSE, ETBE, TAME and/or EtOH in the range of 0-20% Typ- ical constituents (not intended as manufacturing specifications) include PAGE 11 - NOT APPLICABLE - GREATER THAN - NOT TESTED N 0 < - NOT DETERMINED - LESS THAN N A > N T ~~ ,,~~ PRODUCT CODE 26000 NAME UNLEADED REGULAR GASOLINE 17 PRODUCT LABEL (CaNT) 01-03-96 12-08-95 Date Issued Supersedes Label Date 12-08-95 * ., ., ., ., ., ., ., ., ., ., Gasol i ne Methyl-t-butyl ether Ethyl-t-butyl ether Tertiary amyl methyl ether Ethyl alcohol Xylenes Toluene Benzene (if RFG 0 99% max ) 1,24-trimethylbenzene N-hexane Ethylbenzene 1634-04-4 637-92-3 994-05-8 64-17-5 1330-20-7 108-88-3 71-43-2 95-63-6 110-54-3 100-41-4 PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910 1200) ., COMPONENT IS HAZARDOUS ACCORDING TO OSHA Pennsylvania Soecial Hazardous Substance(s) Benzene (if RFG, 0 99% max ) CAS Number 71-43-2 Health F I ammab i I i ty HMIS 1 Reactivity 0 3 Special Health F I ammab i lit Y NFPA 1 Reactivity 0 3 Spec i a I Transportation DOT Proper Shipping Name Gasoline Hazard Class 3 Identification Number UN1203 Packing Group II Label Required Flammable liquid Marine pollutant Not appl icable 95 00-99 99 10 00-19 99 10 00-19 99 10 00-19 99 3 00-9 99 3 00-9 99 3 00-9 99 1 00-2 99 1 00-2 99 1 00-2 99 1 00-2 99 Ranae in % 1 00-2 99 This product contains a DOT Hazardous Substance or Substances 1 isted in Section 14 of the MSDS If the product's Shipping container holds at least 714 lbs then the DOT information must be accompanied with RQ notation or an otherwise 'Not Regulated' product will be classified as Environmentally Hazardous (solid/liquid) NOS Class 9 unless the product qual ifies for the petroleum exemption (49 CFR 171 8) CAUTION Misuse of empty containers can be hazardous Empty containers can be hazardous if used to store toxic flammable or reactive materials Cutting or welding of empty containers might cause fire explosion or toxic fumes from residues 00 not pressurize or expose to open flame or heat Keep container closed and drum bungs ln place Manufacturer s Name and Address TEXACO REFINING AND MARKETING INC POBox 7812 Universal City CA 91608 TRANSPORTATION EMERGENCY Company CHEMTREC (914) 831-3400 (800) 424-9300 HEALTH EMERGENCY Company (914) 831-3400 &~ ~~~ -,., Date Issued 01-03-96 supersedes 12-08-95 TEXACO MATERIAL SAFETY DATA SHEET NOTE Read and understand Material Safety Data Sheet before handling or disposing of product CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL IDENTITY Product Code and Name 26010 UNLEADED MID-GRADE GASOLINE Chemical Name and/or Family or Description Automotive Lead-Free Gasoline Manufacturer's Name and Address TEXACO REFINING AND MARKETING, INC POBox 7812 Universal City, CA 91608 Telephone Numbers Transportation Emergency-Company CHEMTREC -Company (914) 831-3400 (800) 424-9300 (914) 831-3400 (914) 838-7204 (914) 838-7336 (512) 459-6543 (800) 782-7852 Health Emergency General MSDS Assistance Technical Information -Fuels -Chemical -Lubricant! Antifreezes -Additives -Solvents (713) 235-6278 (800) 876-3738 This Material Safety Data Sheet may be used for the following products for Hazard Communications purposes only, not intended to imply identical performance/technical specifications 00317 UNLEADED MEDIUM GASOLINE (7 8#) 00327 TEXACO POWER PLUS (RVP 7 8#) 00331 CALIFORNIA UNBRANDED UNLEADED PLUS 00357 UNLEADED INTERMEDIATE GASOLINE w/ETHER OXYGENATE 00366 TEXACO POWER PLUS W/ OXY 00367 UNLEADED INTERMEDIATE GASOLINE 00375 TEXACO POWER PLUS GASOLINE 00385 MARYLAND GRADE UNLEADED INTERMEDIATE GASOLINE 00479 TEXACO UNLEADED PLUS w!5 7% ETHANOL 00483 ADDITIZED MID-GRADE UNLEADED OXYGENATED 00487 UNLEADED INTERMEDIATE GASOLINE w/7 7% ETHANOL 00495 TEXACO UNLEADED PLUS GASOLINE w!7 7% ETHANOL 00531 UNLEADED INTERMEOIATE GASOLINE w/5 7% ETHANOL 01107 POWER PLUS (RFG 2 0) 01109 CITGO RFG MIOGRAOE UNLEADED 89 01115 POWER PLUS (RFG 2 7) OXY 01124 POWER PLUS (RFG 2 0) 7 2 RVP 01131 POWER PLUS (RFG 2 0) 8 1 RVP 01135 UNLEADED PLUS GASOLINE (RFG 2 01139 UNLEADED PLUS GASOLINE (RfG 2 01144 UNLEADED PLUS GASOLINE (RFG 2 01148 UNLEADED PLUS GASOLINE (RFG 2 01151 TEXACO POWER PLUS (7 2 RVP) 01178 UNLEADED PLUS GASOLINE (MIN 1 8 OXY) 01181 UNLEADED PLUS GASOLINE (7 2 RVP) 01191 TEXACO POWER PLUS (MIN 1 8 OXY) 01198 UNLEADED PLUS GASOLINE (MIN 1 8 OXY) 01244 UNLEADED MIDGRADE RFG 2 0 OPRG NOT-VOC 02755 UNLEADED INTERMEDIATE - CARB PHASE 2 RFG 02756 TEXACO POWER PLUS -CARB PHASE 2 RFG 02757 UNLEADED INTERMEDIATE - CARB PHASE 2 RFG ADDITIZED 0) 7)OXY 0) 7 2 0) 8 1 RVP RVP N D - NOT DETERMINED < - LESS THAN PAGE N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED ....r~ --~~ ... Dat~ Issued Supersedes 01-03-96 12-08-95 PRODUCT CODE 26010 NAME UNLEADED MID-GRADE GASOLINE 2 COMPOSITION/INFORMATION ON INGREDIENTS THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS FOLLOWS CARCINOGENS ARE LISTED WHEN PRESENT AT 0 1 % OR GREATER COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN PRESENT AT 1 0 % OR GREATER NON-HAZARDOUS COMPONENTS ARE LISTED AT 3 0 % OR GREATER THIS IS NOT INTENDED TO BE A COMPLETE COMPOSITIONAL DISCLOSURE REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND OTHER REGULATORY INFORMATION Product and/or Component(s) Carcinogenic According to OSHA IARC NTP OTHER NONE ~ X ~ ~ Composition (Sequence Number and Chemical Name) ~ Chemical Name CAS Number Ranqe in % Gasoline consists of straight/branched paraffinic hydrocarbons olefins cycloparaffins and aromatics Mayor may not contain any combination of these oxygenates MTBE ETBE. TAME and/or EtOH in the range of 0-20% Typ- ical constituents (not intended as manufacturing specifications) include 01 * Gasoline 95 00-99 99 02 ~ Methyl-t-butyl ether 1634-04-4 10 00-19 99 03 * Ethyl-t-butyl ether 637-92-3 10 00-19 99 04 * Tertiary amyl methyl ether 994-05-8 10 00-19 99 05 * Ethyl alcohol 64-17-5 3 00-9 99 06 ~ Xylenes 1330-20-7 3 00-9 99 07 * Toluene 108-88-3 3 00-9 99 08 * Benzene (i f RFG 0 99% max ) 71-43-2 1 00-2 99 09 * 1 2 4-trimethylbenzene 95-63-6 1 00-2 99 10 * Ethylbenzene 100-41-4 1 00-2 99 11 * N-hexane 110-54-3 1 00-2 99 PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910 1200) * COMPONENT IS HAZARDOUS ACCORDING TO OSHA by Sequence Number in the Composition Section Exposure Limits referenced ~ Limit 01 300 01 500 01 300 01 100 02 40 02 40 05 1000 05 1000 06 100 06 150 06 100 06 150 07 100 07 150 07 50 08 1 08 5 08 10 09 25 09 25 10 100 10 125 10 100 10 125 11 50 11 50 ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm TWA-OSHA STEL-OSHA TWA-ACGIH TWA-TEXACD TWA-ACGIH (A3) TWA-TEXACO TWA-OSHA TlfA-ACGIH TWA-OSHA STEL-OSHA TWA-ACGIH STEL-ACGIH TWA-OSHA STEL-OSHA T\~A-ACGIH (SKIN) TWA-OSHA (SUBJECT STEL-OSHA TWA-ACGIH-(A2) TWA-OSHA TWA-ACGIH TWA-OSHA STEL-OSHA TWA-ACGIH STEL-ACGIH TWA-OSHA TWA-ACGIH TO 29 CFR 1910 1028) 3 HAZARD IDENTIFICATION EMERGENCY OVERVIEW Appearance Light red to light straw 1 iquid Odor Petroleum odor PAGE 2 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED N 0 - NOT DETERMINED < - LESS THAN 4~ ~1,.~ , PRODUCT CODE 26010 NAME UNLEADED MID-GRADE GASOLINE Date Issued Supersedes 01-03-96 12-08-95 3 HAZARD IDENTIFICATION (CONT) DANGER WARNING STATEMENT EXTREMELY FLAMMABLE LIQUID AND VAPOR VAPOR MAY CAUSE FLASH FIRE MAY CAUSE DIZZINESS AND DROWSINESS MAY CAUSE IRRITATION TO EYES AND RESPIRATORY TRACT ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE POSSIBLE CANCER HAZARD - MAY CAUSE CANCER BASED ON ANIMAL DATA ATTENTION HMIS NFPA Health 1 Reactivity 0 Hea 1 th 1 Reactivity 0 Flammability 3 SpeCial F 1 ammab i 1 i t Y 3 Special POTENTIAL HEALTH EFFECTS EYE SKIN INHALATION INGESTION Primary Route of Exposure ~ ~ X EFFECTS OF OVEREXPOSURE Acute Eyes May cause irritation experienced as mild discomfort and seen as sl ight excess redness of the eye Skin Brief contact may cause sl ight irritation Prolonged contact as with clothing wetted with material may cause more severe irritation and dis- comfort seen as local redness and swelling Other than the potential skin irritation effects noted above acute (short term) adverse effects are not expected from brief skin contact see other effects below and Section 11 for information regarding potential long term effects Prolonged widespread or repeated skin contact may result in the absorption of potentially harmful amounts of material Inhalation Vapors or mist may cause irritation of the nose and throat Inhalation may cause dizziness drowsiness euphoria loss of coordination disorientation headache nausea and vomiting In poorly ve~trlated areas or confined spaces unconsciousness and asphyxiation may result Prolonged or repeated overexposure may result in the absol'ption of potentially harmful amounts of material Ingestion If more than several mouthfuls are swallowed and diarrhea may occur Aspiration may occur resulting in lung damage abdominal discomfort during swallowing or nausea vomiting Sensitization Properties Unknown Chronic Prolonged and repeated exposure to ethanol vapor may cause headache lack of coordination sleepiness fatigue and difficulty concentrating Chronic ingestion of alcoholic beverages has resulted in 1 iver stomach heart and nervous system damage as well as cancers of the mouth pharynx larynx esophagus and liver in humans Repeated ingestion of ethanol by pregnant women has caused miscarriage premature birth and low birth weight and birth defects (Fetal Alcohol Syndrome) Medical Conditions AggraVated by Exposure Because of its irritating properties repeated skin contact may aggravate an existing dermatitis (skin condition) N 0 - NOT DETERMINED < - LESS THAN PAGE 3 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4,., ~~~ , PRODUCT CODE 26010 NAME UNLEADED MID-GRADE GASOLINE Date Issuetl Supersedes 01-03-96 12-08-95 3 HAZARD IDENTIFICATION (CaNT) Other Remarks This product contains benzene Prolonged and repeated exposure to benzene may cause headaches, loss of appetite, rapid pulse, fatigue liver and kidney damage decreased bone-marrow activity with increased bleeding tendencies and possible irreversible injury to blood forming organs Prolonged and repeated overexposure to benzene has been associated with , aplastic anemia and acute myelogenous leukemia in humans 4 FIRST AID MEASURES Eyes Immediately flush eyes with plenty of water for at least 15 minutes Hold eyelids apart while flushing to rinse entire surface of eye and 1 ids with water Get medical attention Skin Wash skin with plenty of soap and water for several minutes attention if skin irritation develops or persists Get medical Ingestion If person is conscious and can swallow give two glasses of water (16 oz but do not induce vomiting If vomiting occurs give fluids again Have medical personnel determine if evacuation of stomach or induction of vomiting is necessary Do not give anything by mouth to an unconscious or convulsing person Inhalation If inhaled remove to fresh air If not breathing or in respiratory distress clear person's airway and start artificial respiration With a physician's advice give supplemental oxygen using a bag-valve mask or manually triggered oxygen supply Other Instructions Aspiration of this product during induced emesis may result in severe lung injury If evacuation of stomach is necessary use method least likely to cause aspiration such as gastric lavage after endotracheal intubation Contact a Poison Center for additional treatment information Remove and dry-clean or launder clothing soaked or soiled with this material before reuse Dry cleaning of contaminated clothing may be more effective than normal laundering Inform individuals responsible for cleaning of potential hazards associated with handl ing contaminated clothing 5 FIRE-FIGHTING MEASURES Ignition Temperature - AIT (degrees F) 850 Flash Point (degrees F) -40 (PMCC) Flammable Limits (%) Lower 1 4 Upper 7 6 Recommended Fire Extinguishing Agents And Special Procedures Water may be ineffective on flames but should be used to cool fire-exposed containers and provide protection for persons atempting to stop the leak Use water spray dry chemical alcohol resistant foam or carbon dioxide to extinguish fjre Unusual or Explosive Hazards Gasol ine vapors are heavier than air and may travel a considerable distance to a source of ignition and flash back Flowing gaso1 ine can generate static electricity and cause a fire explosion jf a spark occurs in a flammable vapor-air atmosphere When handl ing use non-sparking tools ground and bond all containers Extremely flammable can be ignited by heat spark or flame N 0 - NOT DETERMINED < - LESS THAN PAGE 4 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4~ ~L- PRODUCT CODE 26010 NAME UNLEADED MID-GRADE GASOLINE Date Issued Supersedes 01-03-96 12-08-95 5 FIRE-FIGHTING MEASURES (CONT) Special Protective Equipment for Firefighters Wear full protective clothing and positive pressure breathing apparatus 6 ACCIDENTAL RELEASE MEASURES (Transportation Spills CHEMTREC (800)424-9300) Procedures in Case of Accidental Release, Breakage or Leakage ~ Eliminate all ignition sources including internal combustion engines and power tools Ventilate area Barricade the immediate hazard area Stay upwind and warn of possible downwind explosion hazard Avoid breathing vapor Avoid contact with skin, eyes or clothing Pressure demand air supplied respirators should always be worn when the airborne concentration of the contaminant or oxygen is unknown Otherwise wear respiratory protection and other personal protective equipment as appropriate for the potential exposure hazard Contain spill if possible Remove with inert absorbent Prevent entry into sewers and waterways If more than 714 pounds of product is spilled, then report spill according to SARA 304 and/or CERCLA 102(a) requirements unless product qual ifies for the petroleum exemption (CERCLA Section 101(14)) 7 HANDLING AND STORAGE Precautions to be Taken in Handl i ng Use spark-proof tools Material may be at elevated temperatures and/or pressures Exercise care when opening bleeders and samp1 ing ports Storage Ground and bond shipping container Keep away from heat sparks flame transfer 1 ine and receiving container and other sources of ignition 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Protective Equipment (Type) Eye/Face Protection Safety glasses chemical type goggles or face shield recommended to prevent eye contact Skin Protection Gloves resistant to petroleum distillates are recommended to minimize skin contact The most effective glove materials are Nitrile rubber Teflon or Viton for prolonged contact with 9aso1 ine Protective clothing such as coveralls or boots should be also be worn where contact with product is 1 ike1y Launder or dry clean soiled clothes Respiratory Protection Airborne concentrations should be kept to lowest levels possible If vapor mist or dust is generated and the occupational exposure 1 imlt of the product or any component of the product is exceeded use appropriate NIOSH or MSHA approved air purifying or air suppl ied respirator after determining the airborne concentration of the contaminant Air supp1 ied respirators should always be worn when airborne concentration of the contaminant or oxygen content is unknown Ventilation Use explosion-proof equipment to maintain adequate ventilation to meet occupational exposure limits if applicable (see below) prevent accumulation of explosive air-gas mixtures and avoid significant oxygen displacement Oxygen levels should be at least 19 5% in confined spaces or other work areas (OSHA value) Exposure Limit for Total Product Gasoline OSHA PEL-TWA 300 ppm ACGIH TLV-TWA 300 ppm TEXACO TLV-TWA 100 ppm STEL 500 ppm STEL 500 ppm PAGE 5 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED N D - NOT DETERMINED < - LESS THAN 41il.. ~1.~ PRODUCT CODE 26010 NAME UNLEADED MID-GRADE GASOLINE 9 PHYSICAL AND CHEMICAL PROPERTIES 01-03-96 12-08-95 Date I"ssued Supersedes Appearance Light red to light straw liquid Odor Petroleum odor Boiling Point (degrees F) > 90 Melting/Freezing point (degrees F) Not appl icable Specific Gravity (water=l) 7 - 77 pH of undiluted product Not applicable Vapor Pressure 300 - 700 mmHg at 100 0 Viscosity < 1 4 cSt at 37 7 C VOC Content Not determined Vapor Density (air=1) 3 - 4 Solubility in Water (%) 1 - 1 Other None 10 STABILITY AND REACTIVITY This Material Reacts Violently With (If Others is checked below, see comments for details) Air Water Heat Strong Oxidizers Others None of These X X Comments None Products Evolved When Subjected to Heat or Combustion Toxic levels of carbon monoxide carbon dioxide irritating aldehydes and ketones Hazardous Polymerizations DO NOT OCCUR 11 TOXICOLOGICAL INFORMATION < TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA) Median Lethal Dose Oral LD50 Believed to be > 5 00 g/kg (rat) practically non-toxic Inhalation Not determined Dermal L050 Believed to be > 2 00 glkg (rabbit) practically non-toxic Irritation Index, Estimation of Irritation (Species) Skin (Draize) Believed to be > Eyes (Draize) Believed to be > 15 00 - 25 00 1110 (rabbit) slightly irritating Sensitization Not determined Other Studies in laboratory rats and mice exposed to constant levels of Wholly vaporized unleaded gasol ine for six hours per day five days per week for two years caused kidney damage and kidney cancer in male rats and liver tumors in female mice Many scientists do not bel ieve that the male rat is an appropriate predictor of human kidney disease and are not in agreement PAGE 6 N A - NOT APPLICABLE - GREATER THAN 50 - 3 00 18 0 (rabbit) sl ightly irritating N 0 - NOT DETERMINED - LESS THAN > N T - NOT TESTED &flit.. ~L~ , PROOUCT CODE 26010 NAME UNLEADED MID-GRADE GASOLINE Date Issued Supersedes 01-03-96 12-08-95 11 TOXICOLOGICAL INFORMATION (CONT) on the relationship between liver tumors in laboratory animals and humans Prolonged and repeated exposure to benzene has caused anemia lymphoma and other cancers, in laboratory animals Benzene has been shown to cause embryo/fetal toxicity and birth defects in laboratory animals but only at doses which cause maternal toxicity (i e illness in the mother) Chronic ingestion of ethanol, a possible component of this product has caused birth defects as well as developmental effects in laboratory animals Prolonged and repeated exposure of rats to high levels of TAME vapor resulted in 25% mortality at the highest dose level and produced transient CNS depression (sedation, incoordination reduced activity) Body and organ weight changes were observed without underlying tissue pathology (i e changes to the tissue) A repeated oral study with TAME in rats resulted in two deaths in the high dose group There were no treatment r~lated tissue changes in any of the organ systems evaluated although there were body and organ weight changes TAME was judged to produce an overall low order of toxicity In male mice prolonged and repeated exposure to high levels of MTBE vapor produced a higher than expected mortality due to urinary tract obstruction believed caused by physical non-neoplastic blockage of the urethral canal In female mice data indicate increased incidence of hepatocellular adenomas (benign liver tumors) Prolonged and repeated exposure to high levels of MTBE (up to 8000 ppm for over 15 months) resulted in excess mortal ity (82 %) in male rats Preliminary evaluation showed a chronic progressive nephrosis (kidney damage) as the possible cause of death Associated with the increased sevRrity of nephropathy was an increase in the number of renal tubular cell adenomas (benign kidney tumors) and carcinomas (malignant kidney tumors) There was also a difference in the number of testicular interstitial cell adenomas (benign testicular tumors) MTBE has been shown to cause embryo/fetal toxicity and birth defects in mice but only at maternally toxic doses No developmental effects were seen in rabbits at the same exposure levels Although the significance of these findings to humans is unclear workers should minimize exposure to MTBE vapor Additional or repeat studies are planned or underway to better define the toxic potential of this product or to verify the results obtained from previous animal studies 12 DISPOSAL CONSIDERATIONS Waste Disposal Methods This product (as presently constituted) has the RCRA classification of benzene toxicity and ignitability If discarded in its present form it would have the hazardous waste numbers 0018 and 0001 respectively Under RCRA it is the responsibility of the user of the product to determine at the time of disposal whether the product meets RCRA criteria for hazardous waste This is because product uses transformations mixtures processes etc may change the classification to non-hazardous or hazardous for reasons other than or in addition to benzene toxicity and ignitabilty Remarks Do not allow to enter drains or sewers Can cause explosion N 0 - NOT DETERMINED < - LESS THAN PAGE 7 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4~ ,,~~ , PRODUCT CODE 26010 NAME UNLEADED MID-GRADE GASOLINE 01-03-96 12-08-95 Date Issued Supersedes 13 TRANSPORT INFORMATION Transportation DOT Proper Shipping Name Gasoline Hazard Class 3 Identification Number UN1203 Packing Group II Label Required Flammable liquid Marine pollutant Not appl icable This product contains a DOT Hazardous Substance or Substances, listed in Section 14 of the MSOS If the product's shipping container holds at least 714 lbs, then the DOT information must be accompanied with RQ notation or an otherwise 'Not Regulated' product will be classified as Environmentally Hazardous (solid/liquid) NOS, Class 9, unless the product qualifies for the petroleum exemption (49 CFR 171 8) lMDG Proper Shipping Name Not evaluated lCAO Proper Shipping Name Not evaluated TOG Proper Shipping Name Not evaluated 14 REGULATORY INFORMATION Federal Regulations SARA Tit 1 e I II Section 302/304 Extremely Hazardous Substances ~ Chemical Name CAS Number None Section 302/304 Extremely Hazardous Substances (CONT) ~ TPQ RQ None Section 311 Hazardous Categorization Acute Chronic Fire Pressure 0: X 0. Reactive N/A Section 313 Toxic Chemical Chemical Name Methyl-t-butyl ether Xylenes Toluene Benzene (if RFG 0 99% max ) 1 2 4-trimethylbenzene N-hexane Ethylbenzene CAS Number 1634-04-4 1330-20-7 108-88-3 71-43-2 95-63-6 110-54-3 100-41-4 CERCLA 102(a)/DOT Hazardous Substances ~ Chemical Name 01+ Methyl-t-butyl ether 02+ Xylenes 03+ Toluene 04+ Benzene (if RFG 099% max ) 05+ Ethylbenzene 06+ N-hexane 07+ Benzene (1-methylethyl)- Ranqe in % Concentration 10 00-19 99 3 00-9 99 3 00-9 99 1 00-2 99 1 00-2 99 1 00-2 99 1 00-2 99 CAS (+ indicates DOT Hazardous SUbstance) Number 1634-04-4 1330-20-7 108-88-3 71-43-2 100-41-4 110-54-3 98-82-8 N D - NOT DETERMINED < - LESS THAN PAGE 8 N A - NOT APPLICABLE > - GREATER THAN Ranqe in % 10 00-19 99 3 00-9 99 3 00-9 99 1 00-2 99 1 00-2 99 1 00-2 99 o 01-0 09 N T - NOT TESTED 4~ ~~~., ;, .; PRODUCT CODE 26010 NAME UNLEADED MID-GRADE GASOLINE Date Issued Supersedes 01-03-96 12-08-95 14 REGULATORY INFORMATION (CONT) CERCLA/DOT ~RQ 01+ 02+ 03+ 04+ 05+ 06+ 07+ Hazardous Substances (Sequence Numbers and RQ's) 1000 100 1000 10 1000 5000 5000 TSCA Inventory Status This product, or its components, are listed on or are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance Inventory Other None State Regulations California Proposition 65 The following detectable components or belong to classes of substances, to cause cancer and/or reproductive Chemical Name Gasoline Toluene Benzene (if RFG 0 99% max ) of this product are substances known to the State of California toxicity CAS Number 108-88-3 71-43-2 States Right-to-know Regulations Chemical Name Toluene Benzene (1-methylethyl)- Benzene (if RFG, 0 99% max Gasoline Ethylbenzene N-hexane Xylenes Methyl-t-butyl ether Ethyl alcohol 1 2 4-trimethylbenzene State Right-to-know CT FL IL MA,NJ,PA RI MI CT FL IL MA NJ PA RI MI CT FL IL MA NJ PA RI,MI CT,FL,IL,LA MA NJ,RI CT FL,IL MA NJ,PA,RI CT,FL,IL,MA NJ,PA,RI CT FL IL MA NJ PA RI MI MA, NJ, 'PA CT FL IL MA NJ PA RI MA NJ,PA State list CT (Connecticut) FL (Florida) IL (Illinois) MI (Michigan) LA (Louisiana) MA (Massachusetts) NJ (New Jersey) PA (Pennsylvania) RI (Rhode Island) International Regulations Export Notification (TSCA-12b) This product may be subject to export notification under TSCA section 12(b) contains Methyl-t-butyl ether Tertiary amyl methyl ether WHMIS Classification Not determined Canada Inventory Status Not determined EINECS Inventory Status Not determined Australia Inventory Status Not determined Japan Inventory Status Not determined 15 ENVIRONMENTAL INFORMATION Aquatic Toxicity Not determined PAGE 9 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED N D - NOT DETERMINED < - LESS THAN 4~ \t~ , PRODUCT CODE 26010 NAME UNLEADED MID-GRADE GASOLINE Date IssueCl Supersedes 01-03-96 12-08-95 15 ENVIRONMENTAL INFORMATION (CONT) Mobility Not determined Persistence and Biodegradability Not determined Potential to Bioaccumulate Not determined Remarks None 16 OTHER INFORMATION THIS PRODUCT IS INTENDED FOR USE AS A MOTOR FUEL ONLY Texaco recommends that all exposures to thi~ product be minimiz~d by strictly adhering to recommended occupational controls procedures to avoid any potential adverse health effects Texaco has notified EPA of a TSCA 8(e) Notice of Substantial Risk to Health on the basis of results from a range finding developmental toxicity study for this product or a component of this product A definitive developmental toxicity study is underway THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT FOR PURPOSE OF HAZARD COMMUNICATION AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM IT IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT NO EXPRESS WARRANTY OR IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION CONTAINED HEREIN DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY, PROCESS USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN TO DETERMINE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY TEXACO DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS Since the last mailing for this customer code, the following sections have been revised 12,6 11 14 16 17 Date 01-03-96 Date printed 02-05-96 New ~ Revised Supersedes 12-08-95 Inquiries regarding MSOS should be directed to Texaco Inc Manager Product Safety POBox 509 Beacon N Y 12508 PLEASE SEE NEXT PAGE FOR PRODUCT LABEL PAGE 10 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED N D - NOT DETERMINED < - LESS THAN 4,., \t~~ ". , . Date Issued Supersedes 01-03-96 12-08-95 PRODUCT CODE 26010 NAME UNLEADED MID-GRADE GASOLINE 17 PRODUCT LABEL label Date 12-08-95 READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910 1200) FOR USE IN THE WORKPLACE THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS 26010 UNLEADED MID-GRADE GASOLINE WARNING STATEMENT DANGER ! EXTREMELY FLAMMABLE LIQUID AND VAPOR VAPOR MAY CAUSE FLASH FIRE MAY CAUSE DIZZINESS AND DROWSINESS MAY CAUSE IRRITATION TO EYES AND RESPIRATORY TRACT ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE ATTENTION POSSIBLE CANCER HAZARD - MAY CAUSE CANCER BASED ON ANIMAL DATA PRECAUTIONARY MEASURES -Keep away from heat sparks or flame -Use only with adequate ventilation -Avoid breathing vapor mist, or gas -Avoid contact with eyes skin and clothing -Keep container closed -Never siphon by mouth -Wash thoroughly after handling FIRST AID Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes Hold eyel ids apart while flushing to rinse entire surface of eye and 1 ids with water Get medical attention Skin Contact Wash skin with plenty of soap and water for several minutes Get medical attention if skin irritation develops or persists Ingestion If person is conscious and can swallow, give two glasses of water (16 oz but do not induce vomiting If vomiting occurs, give fluids again Have medical personnel determine if evacuation of stomach or induction of vomiting is necessary Do not give anything by mouth to an unconscious or convulsing person Inhalation If inhaled remove to fresh air If not breathing or in respiratory distress clear person's airway and start artificial respiration With a physician's advice give supplemental oxygen using a bag-valve mask or manually triggered oxygen supply Note to Physician Aspiration of this product during induced emesis may result in severe lung injury If evacuation of stomach is necessary use method least 1 ikely to cause aspiration such as gastric lavage after endotracheal intubation Contact a Poison Center for additional treatment information FIRE In case of fire carbon dioxide containers cool use water spray dry chemical alcohol resistant foam or Water may be ineffective on flames Use water spray to keep and protect personnel attempting to stop the leak If more than 714 pounds of product is spilled then report spill according to SARA 304 and/or CERCLA 102(a) requirements unless product qual ifies for the petroleum exemption (CERCLA Section 101(14)) Chemical Name CAS Number Range in % Gasoline consists of straight/branched paraffinic hydrocarbons olefins, cycloparaffins and aromatics Mayor may not contain any combination of these oxygenates MTBE ETBE, TAME and/or EtOH in the range of 0-20% Typ- ical constituents (not intended as manufacturing specifications) include N D - NOT DETERMINED < - LESS THAN PAGE 11 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4~ ~~~ , PRODUCT CODE 26010 NAME UNLEADED MID-GRADE GASOLINE Date )ssu~d' 01-03-96 Supersedes 12-08-95 Label Date 12-08-95 17 PRODUCT LABEL (CONT) Art. ~L~ * Gasol ine 95 00-99 99 1 * Methyl-t-butyl ether 1634-04-4 10 00-19 99 * Ethyl-t-butyl ether 637-92-3 10 00-19 99 * Tertiary amyl methyl ether 994-05-8 10 00-19 99 * Ethyl alcohol 64-17-5 3 00-9 99 * Xylenes 1330-20-7 3 00-9 99 * Toluene 108-88-3 3 00-9 99 .,. * Benzene (if RFG, o 99% max ) 71-43-2 1 00-2 99 * 1,2,4-trimethylbenzene 95-63-6 1 00-2 99 * N-hexane 110-54-3 1 00-2 99 * Ethylbenzene 100-41-4 1 00-2 99 PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910 1200) * COMPONENT IS HAZARDOUS ACCORDING TO OSHA Pennsylvania Special Hazardous Substance(s) Benzene (if RFG, 0 99% max ) Ranqe in % 1 00-2 99 CAS Number 71-43-2 Health Flammability HMIS 1 Reactivity 0 3 Special NFPA 1 Reactivity 0 3 Special Health Flammability Transportation DOT Proper Shipping Name Gasol ine Hazard Class 3 Identification Number UN1203 Packing Group II Label Required Flammable 1 iquid Marine pollutant Not appl icable This product contains a DOT Hazardous Substance or Substances listed in Section 14 of the MSoS If the product's shipping container holds at least 714 lbs then the DOT information must be accompanied with RQ notation or, an otherwise 'Not Regulated' product will be classified as Environmentally Hazardous (solid/liquid) NOS Class 9 unless the product qual ifies for the petroleum exemption ~4p CFR 171 8) CAUTION Misuse of empty containers can be hazardous Empty containers can be hazardous if used to store toxic flammable or reactive materials Cutting or welding of empty containers might cause fire explosion or toxic fumes from residues Do not pressurize or expose to open flame or heat Keep container closed and drum bungs in place Manufacturer's Name and Address TEXACO REFINING AND MARKETING INC POBox 7812 Universal City CA 91608 TRANSPORTATION EMERGENCY Company CHEMTREC (914) 831-3400 (800) 424-9300 (914) 831-3400 HEALTH EMERGENCY Company Date Issued 01-03-96 Supersedes 12-08-95 TEXACO MATERIAL SAFETY DATA SHEET NOTE Read and understand Material Safety Data Sheet before handling or disposing of product CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL IDENTITY Product Code and Name 26020 UNLEADED PREMIUM GASOLINE Chemical Name and/or Family or Description Automotive Lead-Free Gasoline Manufacturer's Name and Address TEXACO REFINING AND MARKETING. INC POBox 7812 Universal City, CA 91608 Telephone Numbers Transportation Emergency-Company CHEMTREC -Company (914) 831-3400 (800) 424-9300 (914) 831-3400 (914) 838-7204 (914) 838-7336 (512) 459-6543 (800) 782-7852 (713) 235-6278 (800) 876-3738 Health Emergency General MSDS Assistance Technical Information -Fuels -Chemical -Lubricant/ Antifreezes -Additives -Solvents This Material Safety Data Sheet may be used for the following products for Hazard Communications purposes only, not intended to imply identical performance/technical specifications 00313 TEXACO POWER PREMIUM W/ OXY 93 00314 UNLEADED PREMIUM (w/OXYGENATES) 00318 UNLEADED PREMIUM GASOLINE 92 OCTANE (7 8#) 00319 UNLEADED PREMIUM GASOLINE 93 OCTANE (7 8#) 00328 TEXACO POWER PREMIUM (RVP 7 8#)92 00332 TEXACO POWER PREMIUM (RVP 7 8#)93 00335 CALIFORNIA UNBRANDED UNLEADED PREMIUM 00346 TEXACO SUPER REGULAR W/ETHANOL 00347 TEXACO POWER PREMIUM 93 00348 ~REMIUM UNLEADED GASOLINE 91 00350 PREMIUM UNLEADED QASOLINE BG 00355 UNLEADED PREMIUM WITH ETHANOL 00360 TEXACO POWER PREMIUM 92 00361 PREMIUM UNLEADED GASOLINE 93 OCTANE 00363 TEXACO SUPER UNLEADED WITH ETHANOL 00364 PREMIUM UNLEADED GASOLINE 00368 TEXACO POWER PREMIUM W/ OXY 92 00370 PREMIUM UNLEADED GASOLINE W/ETHER OXY 00378 TEXACO PREMIUM UNLEADED WITH ETHANOL 00379 TEXACO SUPER UNLEADED WITH ETHANOL 00386 MARYLAND GRADE PREMIUM UNLEADED GASOLINE 00451 ADDITIZED PREMIUM UNLEADED OXYGENATED 00498 UNLEADED PREMIUM GASOLINE w/7 7% ETHANOL 00501 UNLEADED PREMIUM GASOLINE w/7 7% ETHANOL 00545 TEXACO UNLEADED PREMIUM GASOLINE w/5 7% ETOH 00553 UNLEADED PREMIUM GASOLINE w/5 7% ETHANOL o 1 1 02 POWER PREMIUM 93 (RFG 2 0) 01105 POWER PREMIUM (RFG 2 0) 01110 CITGO RFG PREMIUM UNLEADED 93 01113 POWER PREMIUM 93 (RFG 2 7) OXY 01114 POWER PREMIUM (RFG 2 7) OXY 01117 POWER PREMIUM 93 (RFG 2 0) OXY 7 2 RVP 01118 POWER PREMIUM (RFG 2 0) 7 2 RVP 01126 POWER PREMIUM 93 (RFG 2 0) 8 1 RVP 01127 POWER PREMIUM (RFG 2 0) 8 1 RVP 01133 UNLEADED PREMIUM GASOLINE 93 (RFG 2 0) 01134 UNLEADED PREMIUM GASOLINE (RFG 2 0) " 01137 UNLEADED PREMIUM 93 GASOLINE (RFG 2 7)OXY 01138 UNLEADED PREMIUM GASOLINE (RFG 2 7) OXY 01142 UNLEADED PREMIUM GASOLINE 93 (RFG 2 0) 7 2 RVP PAGE 1 N D - NOT DETERMINED N A - NOT APPLICABLE N T - NOT TESTED < - LESS THAN > - GREATER THAN &f'- r~' ~~ ~~~ Date Issued 01-03-96 supersedes 12-08-95 PRODUCT CODE 26020 NAME UNLEADED PREMIUM GASOLINE CHEMICAL PRODUCT AND COMPANY IDENTIFICATION (CONT) 01143 UNLEADED PREMIUM GASOLINE (RFG 2 0) 7 2 RVP 01146 UNLEADED PREMIUM GASDLINE 93 (RFG 2 0) 8 1 RVP 01147 UNLEADED PREMIUM GASOLINE (RFG 2 0) 8 1 RVP 01150 TEXACO POWER PREMIUM (7 2 RVP) 01167 UNLEADED PREMIUM GASOLINE (7 2 RVP) 01190 TEXACO POWER PREMIUM (MIN 1 8 OXY) 01197 UNLEADED PREMIUM GASOLINE (MIN 1 8 OXY) 01249 UNLEADED PREMIUM RFG 2 0 OPRG NOT-VOC 02758 UNLEADED PREMIUM - CARB PHASE 2 RFG 02759 TEXACO POWER PREMIUM - CARB PHASE 2 RFG 02760 UNLEADED PREMIUM - CARB PHASE 2 RFG - ADDITIZED 2 COMPOSITION/INFORMATION ON INGREDIENTS THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS FOLLOWS CARCINOGENS ARE LISTED WHEN PRESENT AT 0 1 % OR GREATER COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN PRESENT AT 1 0 % OR GREATER, NON-HAZARDOUS COMPONENTS ARE LISTED AT 3 0 % OR GREATER THIS IS NOT INTENDED TO BE A COMPLETE COMPOSITIONAL DISCLOSURE REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND OTHER REGULATORY INFORMATION Product and/or Component(s) Carcinogenic According to OSHA IARC NTP OTHER NONE X X X X - - Composition (Sequence Number and Chemical Name) ~ Chemical Name CAS Number Ranqe in % Gasoline consists of straight/branched paraffinic hydrocarbons olefins, cycloparaffins and aromatics Mayor may not contain any combination of these oxygenates MTBE ETBE TAME and/or EtOH in the range of 0-20% Typ- ical constituents (not intended as manufacturing specifications) include 01 " Gasoline 95 00-99 99 02 " Methyl-t-butyl ether 1634-04-4 10 00-19 99 03 " Ethyl-t-butyl ether 637-92-3 10 00-19 99 04 " Tertiary amyl methyl ether 994-05-8 10 00-19 99 05 " Ethyl alcohol 64-17-5 3 00-9 99 06 " Xylenes 1330-20-7 3 00-9 99 07 " Toluene 108-88-3 3 00-9 99 08 " Benzene (if RFG 0 99% max ) 71-43-2 1 00-2 99 09 " 1 2 4-trimethylbenzene 95-63-6 1 00-2 99 10 " Ethylbenzene 100-41-4 1 00-2 99 11 ' N-hexane 110-54-3 1 00-2 99 PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910 1200) . COMPONENT IS HAZARDOUS ACCORDING TO OSHA by Sequence Number in the Composition Section Exposure Limits referenced ~ Limit 01 300 01 500 01 300 01 100 02 40 02 40 05 1000 05 1000 06 100 06 150 06 100 06 150 07 100 07 150 07 50 08 1 08 5 08 10 09 25 09 25 10 100 10 125 10 100 10 125 ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm TWA-OSHA STEL-OSHA TWA-ACGIH TWA-TEXACO TWA-ACGIH (A3) TWA-TEXACO TWA-OSHA TWA-ACGIH TWA-OSHA STEL-OSHA TWA-ACGIH STEL-ACGIH TWA-OSHA STEL-OSHA TWA-ACGIH (SKIN) TWA-OSHA (SUBJECT STEL-OSHA TWA-ACGIH-(A2) TWA-OSHA TWA-ACGIH TWA-OSHA STEL-OSHA TWA-ACGIH STEL-ACGIH TO 29 CFR 1910 1028) PAGE 2 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED N D - NOT DETERMINED < - LESS THAN Af.'k.. ~~~ PRODUCT CODE 26020 NAME UNLEADED PREMIUM GASOLINE 01-03-96 12-08-95 Date Issued Supersedes 2 COMPOSITION/INFORMATION ON INGREDIENTS (CONT) 1 1 11 ppm TWA-OSHA ppm TWA-ACGIH 50 50 3 HAZARD IDENTIFICATION EMERGENCY OVERVIEW Appearance Light red to light straw liquid Odor Petroleum odor DANGER WARNING STATEMENT EXTREMELY FLAMMABLE LIQUID AND VAPOR VAPOR MAY CAUSE FLASH FIRE MAY CAUSE DIZZINESS AND DROWSINESS MAY CAUSE IRRITATION TO EYES AND RESPIRATORY TRACT ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE POSSIBLE CANCER HAZARD - MAY CAUSE CANCER BASED ON ANIMAL DATA ATTENTION HMIS NFPA Hea 1 th 1 Reactivity 0 Health 1 Reactivity 0 F 1 ammab i 1 i ty 3 Special Flammability 3 Special POTENTIAL HEALTH EFFECTS EYE SKIN INHALATION INGESTION Primary Route of Exposure ~ ~ ~ EFFECTS OF OVEREXPOSURE Acute Eyes May cause irritation experienced as mild discomfort and seen as slight excess redness of the eye Skin Brief contact may cause slight clothing wetted with material comfort, seen as local redness irritation Prolonged contact, as with may cause more severe irritation and dis- and swelling Other than the potential skin irritation effects noted above acute (short term) adverse effects are not expected from brief skin contact see other effects below and Section 11 for information regarding potential long term effects Prolonged widespread or repeated skin contact may result in the absorption of potentially harmful amounts of material Inhalation Vapors or mist may cause irritation of the nose and throat Inhalation may cause dizziness drowsiness euphoria loss of coordination, disorientation headache nausea and vomiting In poorly ventilated areas or confined spaces unconsciousness and asphyxiation may result Prolonged or repeated overexposure may result in the absorption of potentially harmful amounts of material Ingestion If more than several mouthfuls are swallowed abdominal discomfort nausea and diarrhea may occur Aspiration may occur during swallowing or vomiting resulting in lung damage Sensitization Properties Unknown N D - NOT DETERMINED < - LESS THAN PAGE 3 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED A___.'y,:,< ~. \r~~ PRODUCT CODE 26020 NAME UNLEADED PREMIUM GASOLINE 3 HAZARD IDENTIFICATION (CONT) Date Issued Supersedes 01-03-96 -,"12-08-95 Chronic Prolonged and repeated exposure to ethanol vapor may cause headache, lack of coordination sleepiness fatigue, and difficulty concentrating Chronic ingestion of alcoholic beverages has resulted in liver, stomach, heart and nervous system damage as well as cancers of the mouth, pharynx, larynx, esophagus and liver in humans Repeated ingestion of ethanol by pregnant women has caused miscarriage, premature birth and low birth weight, and birth defects (Fetal Alcohol Syndrome) Medical Conditions Aggravated by Exposure Because of its irritating properties, repeated skin contact may aggravate an existing dermatitis (skin condition) Other Remarks This product contains benzene Prolonged and repeated exposure to benzene may cause headaches loss of appetite, rapid pulse, fatigue, liver and kidney damage, decreased bone-marrow activity with increased bleeding tendencies, and possible irreversible injury to blood forming organs Prolonged and repeated overexposure to benzene has been associated with aplastic anemia and acute myelogenous leukemia in humans 4 fIRST AID MEASURES Eyes Immediately flush eyes with plenty of water for at least 15 minutes Hold eyel ids apart while flushing to rinse entire surface of eye and lids with water Get medical attention Skin Wash skin with plenty of soap and water for several minutes attention if skin irritation develops or persists Get medical Ingestion If person is conscious and can swallow give two glasses of water (16 oz but do not induce vomiting If vomiting occurs give fluids again Have medical personnel determine if evacuation of stomach or induction of vomiting is necessary Do not give anything by mouth to an unconscious or convulSing person Inhalation If inhaled remove to fresh air If not breathing or in respiratory distress clear person's airway and start artificial respiration With a physician's advice give supplemental oxygen using a bag-valve mask or manually triggered oxygen supply Other Instructions Aspiration of this product during induced emesis may result in severe lung injury If evacuation of stomach is necessary use method least likely to cause aspiration such as gastric lavage after endotracheal intubation Contact a Poison Center for additional treatment information Remove and dry-clean or launder clothing soaked or soiled with this material before reuse Dry cleaning of contaminated clothing may be more effective than normal laundering Inform individuals responsible for cleaning of potential hazards associated with handling contaminated clothing 5 FIRE-FIGHTING MEASURES Ignition Temperature - AIT (degrees F) 850 Flash Point (degrees F) -40 (PMCC) Flammable Limits (%) Lower 1 4 Upper 7 6 N 0 - NOT DETERMINED < - LESS THAN PAGE 4 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4' \\"'.. ~~ ~~~ ,r-',,\ PRODUCT CODE 26020 NAME UNLEADED PREMIUM GASOLINE Date Issued Supersedes 01-03-96 12-08-95 5 FIRE-FIGHTING MEASURES (CONT) Recommended Fire Extinguishing Agents And Special Procedures Water may be ineffective on flames but should be used to cool fire-exposed containers and provide protection for persons atempting to stop the leak Use water spray dry chemical alcohol resistant foam or carbon dioxide to extinguish fire Unusual or Explosive Hazards Gasoline vapors are heavier than air and may travel a considerable distance to a source of ignition and flash back Flowing gasoline can generate static electricity and cause a fire explosion if a spark occurs in a flammable vapor-air atmosphere When handling, use non-sparking tools ground and bond all containers Extremely flammable can be ignited by heat, spark or flame Special Protective Equipment for Firefighters Wear full protective clothing and positive pressure breathing apparatus 6 ACCIDENTAL RELEASE MEASURES (Transportation Spills CHEMTREC (800)424-9300) Procedures in Case of Accidental Release, Breakage or Leakage El iminate all ignition sources including internal combustion engines and power tools Ventilate area Barricade the immediate hazard area Stay upwind and warn of possible downwind explosion hazard Avoid breathing vapor Avoid contact with skin eyes or clothing Pressure demand air supplied respirators should always be worn when the airborne concentration of the contaminant or oxygen is unknown Otherwise wear respiratory protection and other personal protective equipment as appropriate for the potential exposure hazard Contain spill if possible Remove with inert absorbent Prevent entry into sewers and waterways If more than 714 pounds of product is spilled then report spill according to SARA 304 and/or CERCLA 102(a) requirements unless product qualifies for the petroleum exemption (CERCLA Section 101(14)) 7 HANDLING AND STORAGE Precautions to be Taken in Handling Use spark-proof tools Material may be at elevated temperatures and/or pressures Exercise care when opening bleeders and ~ampl ing ports Storage Ground and bond shipping container Keep away from heat sparks flame transfer line and receiving container and other sources of ignition 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Protective Equipment (Type) Eye/Face Protection Safety glasses chemical type goggles or face shield recommended to prevent eye contact Skin Protection Gloves resistant to petroleum distillates are recommended to minimize skin contact The most effective glove materials are Nitrile rubber Teflon or Viton for prolonged contact with gasol ine Protective clothing such as coveralls or boots should be also be worn where contact with product is likely Launder or dry clean soiled clothes Respiratory Protection Airborne concentrations should be kept to lowest levels possible If vapor, mist or dust is generated and the occupational exposure limit of the product or any component of the product is exceeded, use appropriate NIOSH or MSHA approved air purifying or air suppl ied respirator after determining the airborne concentration of the contaminant Air suppl ied respirators should always be worn when airborne concentration of the contaminant or oxygen content is unknown PAGE 5 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED N D - NOT DETERMINED < - LESS THAN &~ ~~~ PRODUCT CODE 26020 NAME UNLEADED PREMIUM GASOLINE 8 EXPOSURE CONTROLS/PERSONAL PROTECTION (CaNT) 01-03-96 12-08-95 Date Issued Supersedes Ventilation Use explosion-proof equipment to maintain adequate ventilation to meet occupational exposure limits, if applicable (see below), prevent accumulation of explosive air-gas mixtures and avoid significant oxygen displacement Oxygen levels should be at least 19 5% in confined spaces or other work areas (OSHA value) Exposure limit for Total Product Gasoline OSHA PEL-TWA 300 ppm, STEL 500 ppm ACGIH TlV-TWA 300 ppm, STEl 500 ppm TEXACO TLV-TWA 100 ppm 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance light red to light straw liquid Odor Petroleum odor Boiling Point (degrees F) > 90 Melting/Freezing point (degrees F) Not applicable Specific Gravity (water=1) 7 - 77 pH of undiluted product Not appl icable Vapor Pressure 300 - 700 mmHg at 100 0 Viscosity < 1 4 cSt at 37 7 C VOC Content Not determined Vapor Density (air=1) 3 - 4 Solubility in Water (%) 1 - 1 Other None 10 STABILITY AND REACTIVITY This Material Reacts Violently With (If Others is checked below see comments for details) Air Water Heat Strong Oxidizers Others None of These z;. z;. Comments None Products Evolved When Subjected to Heat or Combustion Toxic levels of carbon monoxide carbon dioxide irritating aldehydes and ketones Hazardous Polymerizations DO NOT OCCUR 11 TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA) Median Lethal Dose Oral LD50 Believed to be > 5 00 g/kg (rat) practically non-toxic Inhalation Not determined N D - NOT DETERMINED < - lESS THAN PAGE 6 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED k... \:.4.:.. ~~~ ,.,..,..,....., . '\ PRODUCT CODE 26020 NAME UNLEADED PREMIUM GASOLINE 11 TOXICOLOGICAL INFORMATION (CaNT): Date Issued Supersedes 01-03-96 12-08-95 Dermal LD50 Believed to be > 2 00 g/kg (rabbit) practically non-toxic Irritation Index, Estimation of Irritation (Species) Skin (Draize) Believed to be > 50 - 3 00 /8 0 (rabbit) slightly irritating Eyes (Draize) Believed to be > 15 00 - 25 00 /110 (rabbit) slightly irritating Sensitization Not determined Other Studies in laboratory rats and mice exposed to constant levels of wholly vaporized unleaded gasoline for six hours per day, five days per week for two years caused kidney damage and kidney cancer in male rats and liver tumors in female mice Many scientists do not believe that the male rat is an appropriate predictor of human kidney disease and are not in agreement on the relationship between liver tumors in laboratory animals and humans Prolonged and repeated exposure to benzene has caused anemia, lymphoma, and other cancers, in laboratory animals Benzene has been shown to cause embryo/fetal toxicity and birth defects in laboratory animals, but only at doses which cause maternal toxicity (i e illness in the mother) Chronic ingestion of ethanol a possible component of this product has caused birth defects as well as developmental effects in laboratory animals Prolonged and repeated exposure of rats to high levels of TAME vapor resulted in 25% mortality at the highest dose level and produced transient CNS depression (sedation incoordination, reduced activity) Body and organ weight changes were observed without underlying tissue pathology (i e changes to the tissue) A repeated oral study with TAME in rats resulted in two deaths in the high dose group There were no treatment related tissue changes in any of the organ systems evaluated although there were body and organ weight changes TAME was judged to produce an overall low order of toxicity In male mice prolonged and repeated exposure to high levels of MTBE vapor produced a higher than expected mortality due to urinary tract obstruction believed caused by physical non-neoplastic blockage of the urethral canal In female mice data indicate increased incidence of hepatocellular adenomas (benign liver tumors) Prolonged and repeated exposure to high levels of MTBE (up to 8000 ppm for over 15 months) resulted in excess mortality (82 %) in male rats Preliminary evaluation showed a chronic progressive nephrosis (kidney damage) as the possible cause of death Associated with the increased severity of nephropathy was an increase in the number of renal tubular cell adenomas (benign kidney tumors) and carcinomas (malignant kidney tumors) There was also a difference in the number of testicular interstitial cell adenomas (benign testicular tumors) MTBE has been shown to cause embryo/fetal toxicity and birth defects in mice but only at maternally toxic doses No developmental effects were seen in rabbits at the same exposure levels Although the significance of these findings to humans is unclear workers should minimize exposure to MTBE vapor Additional or repeat studies are planned or underway to better define the toxic potential of this product or to verify the results obtained from previous animal studies 12 DISPOSAL CONSIDERATIONS ~~. ,~, ~: ': ~~ Waste Disposal Methods This product (as presently constituted) has the RCRA classification of benzene toxicity and ignitability If discarded in its present form, it would have the hazardous waste numbers 0018 and 0001 respectively Under RCRA, it is the responsibility of the user of the product to determine at the time of disposal whether the product meets RCRA criteria for hazardous waste This is because product uses, transformations, mixtures, processes, etc may change the classification to non-hazardous, or hazardous for reasons other than or in addition to benzene toxicity and ignitabilty PAGE 7 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED N 0 - NOT DETERMINED < - LESS THAN Af['"1t:;,. &: &. ~~~ 01-03-96 12-08:-.95 'Z'" PRODUCT CODE 26020 NAME UNLEADED PREMIUM GASOLINE 12 DISPOSAL CONSIDERATIONS (CONT) Date Issued Supersedes Remarks Do not allow to enter drains or sewers Can cause explosion 13 TRANSPORT INFORMATION Transportation DOT Proper Shipping Name Gasol ine Hazard Class 3 Identification Number UN1203 Packing Group II Label Required Flammable liquid Marine pollutant Not applicable This product contains a DOT Hazardous Substance or Substances listed in Section 14 of the MSDS If the product'S shipping container holds at least 714 lbs then the DOT information must be accompanied with RQ notation or, an otherwise 'Not Regulated' product will be classified as Environmentally Hazardous (solid/liquid) NOS Class 9 unless the product qualifies for the petroleum exemption (49 CFR 171 8) IMDG Proper Shipping Name Not evaluated ICAO Proper Shipping Name Not evaluated TOG Proper Shipping Name Not evaluated 14 REGULATORY INFORMATION Federal Regulations SARA Title III Section 302/304 Extremely Hazardous Substances ~ Chemical Name CAS Number None Section 302/304 Extremely Hazardous Substances (CONT) ~ TPQ RQ None Section 311 Hazardous Categorization Acute Chronic Fire Pressure ~ ~ ~ Reactive N/A Section 313 Toxic Chemical Chemical Name Methyl-t-butyl ether Xylenes Toluene Benzene (if RFG 0 99% max ) 1,24-trimethylbenzene N-hexane Ethylbenzene CAS Number 1634-04-4 1330-20-7 108-88-3 71-43-2 95-63-6 110-54-3 100-41-4 N 0 - NOT DETERMINED < - LESS THAN PAGE 8 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED Ranqe in % Concentration 10 00-19 99 3 00-9 99 3 00-9 99 1 00-2 99 1 00-2 99 1 00-2 99 1 00-2 99 Iii. ~ ~~~. 1tt,' ~:':.'. ,J,>' ,-:>,:,,,. ...;~':~> PRODUCT CODE. 26020 NAME UNLEADED PREMIUM GASOLINE 14 REGULATORY INFORMATION (CONT) Date Issued Supersedes: . 01-03-96\ 12-08-95 (+ indicates DOT Hazardous Substance) CERCLA 102(a)/DOT Hazardous Substances ~ Chemical Name 01+ Methyl-t-butyl ether 02+ Xylenes 03+ Toluene 04+ Benzene (if RFG, 0 99% max ) 05+ Ethylbenzene 06+ N-hexane 07+ Benzene, (1-methylethyl) - CERCLA/DOT Hazardous Substances (Sequence ~RQ 01+ 02+ 03+ 04+ 05+ 06+ 07+ CAS Number 1634-04-4 1330-20-7 108-88-3 71-43-2 100-41-4 110-54-3 98-82-8 Numbers and RQ's) Ranqe in % 10 00-19 99 3 00-9 99 3 00-9 99 1 00-2 99 1 00-2 99 1 00-2 99 o 01-0 09 1000 100 1000 10 1000 5000 5000 TSCA Inventory Status This product or its components are listed on or are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance Inventory Other None State Regulations California Proposition 65 The following detectable components or belong to classes of substances to cause cancer and/or reproductive Chemical Name Gasol i ne Toluene Benzene (if RFG, 0 99% max ) of this product are substances known to the State of California toxicity CAS Number 108-88-3 71-43-2 states Right-to-know Regulations Chemical Name State Riqht-to-know Toluene CT FL IL MA,NJ PA RI MI Benzene (1-methylethyl) - CT FL IL MA NJ PA RI MI Benzene (i f RFG o 99% max CT FL IL MA NJ PA RI MI Gasoline CT FL IL LA MA NJ RI Ethylbenzene CT FL IL,MA,NJ PA RI N-hexane CT FL IL MA NJ PA RI Xylenes CT FL IL MA NJ PA RI MI Methyl-t-butyl ether MA NJ PA Ethyl alcohol CT FL IL MA NJ PA RI 1 2 4-trimethylbenzene MA NJ PA State list CT (Connecticut) FL (Florida) IL (Illinois) MI (Michigan) LA (Louisiana) MA (Massachusetts) NJ (New Jersey) PA (Pennsylvania) RI (Rhode Island) International Regulations Export Notification (TSCA-12b) This product may be subject to export notification under TSCA section 12(b) contains Methyl-t-butyl ether Tertiary amyl methyl ether WHMIS Classification Not determined Canada Inventory Status Not determined EINECS Inventory Status Not determined N 0 - NOT DETERMINED < - LESS THAN PAGE 9 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED [. '"'.".. ~~ ";~L~ '...~ :t PRODUCT CODE 26020 NAME UNLEADED PREMIUM GASOLINE Date Issued Supersedes 01-03-96 12-08-95 14 REGULATORY INFORMATION (CONT) Australia Inventory Status Not determined Japan Inventory Status Not determined 15 ENVIRONMENTAL INFORMATION Aquatic Toxicity Not determined Mobility Not determined Persistence and Biodegradability Not determined Potential to Bioaccumulate Not determined Remarks None 16 OTHER INFORMATION THIS PRODUCT IS INTENDED FOR USE AS A MOTOR FUEL ONLY Texaco recommends that all exposures to this product be minimized by strictly adhering to recommended occupational controls procedures to avoid any potential adverse health effects Texaco has nGtifiec EPA of a TSCA 8(e) Notice of Substantial Risk to Health on the basis of results from a range finding developmental toxicity study for this product or a component of this product A definitive developmental toxicity study is underway THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT FOR PURPOSE OF HAZARD COMMUNICATION AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM IT IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT NO EXPRESS WARRANTY OR IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION CONTAINED HEREIN DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY PROCESS USE DR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN TO DETERMINE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY TEXACO DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS Since the last mailing for this customer code, the following sections have been revised 126111416,17 Date 01-03-96 Date printed 02-05-96 New X Revised Supersedes 12-08-95 Inquiries regarding MSDS should be directed to Texaco Inc Manager Product Safety POBox 509 Beacon N Y 12508 PLEASE SEE NEXT PAGE FOR PRODUCT LABEL N 0 - NOT DETERMINED < - LESS THAN PAGE 10 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED ~~ ~~~ PRODUCT CODE 26020 NAME UNLEADED PREMIUM GASOLINE Date Issued supersedes 01-03-96 12-08-95 17 PRODUCT LABEL Label Date 12-08-95 READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910 1200) FOR USE IN THE WORKPLACE THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS 26020 UNLEADED PREMIUM GASOLINE WARNING STATEMENT DANGER ! EXTREMELY FLAMMABLE LIQUID AND VAPOR VAPOR MAY CAUSE FLASH FIRE MAY CAUSE DIZZINESS AND DROWSINESS MAY CAUSE IRRITATION TO EYES AND RESPIRATORY TRACT ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE ATTENTION POSSIBLE CANCER HAZARD - MAY CAUSE CANCER BASED ON ANIMAL DATA PRECAUTIONARY MEASURES -Keep away from heat sparks or flame -Use only with adequate ventilation -Avoid breathing vapor, mist or gas -Avoid contact with eyes skin and clothing -Keep container closed -Never siphon by mouth -Wash thoroughly after handling FIRST AID Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes Hold eyelids apart while flushing to rinse entire surface of eye and lids with water Get medical attention Skin Contact Wash skin with plenty of soap and water for several minutes attention if skin irritation develops or persists Ingestion If person is conscious and can swallow give two glasses of water (16 oz but do not induce vomiting If vomiting occurs give fluids again Have medical personnel determine if evacuation of stomach or induction of vomiting is necessary Do not give anything by mouth to an unconscious or convulsing person Inhalation If inhaled remove to fresh air If not breathing or in respiratory dist8ess clear person s airway and start artificial respiration With a physician's advice give supplemental oxygen using a bag-valve mask or manually triggered oxygen supply Note to Physician Aspiration of this product during induced emesis may result in severe lung injury If evacuation of stomach is necessary use method least likely to cause aspiration such as gastric lavage after endotracheal intubation Contact a Poison Center for additional treatment information FIRE use water spray dry chemical, alcohol resistant foam or Water may be ineffective on flames Use water spray to keep and protect personnel attempting to stop the leak Get medical In case of fire carbon dioxide containers cool If more than 714 pounds of product is spilled then report spill according to SARA 304 and/or CERCLA 102(a) requirements unless product qualifies for the petroleum exemption (CERCLA Section 101(14)) Chemical Name CAS Number Range in % Gasoline consists of straight/branched paraffinic hydrocarbons olefins, cycloparaffins and aromatics Mayor may not contain any combination of these oxygenates MTBE ETBE TAME and/or EtOH in the range of 0-20% Typ- ical constituents (not intended as manufacturing specifications) include N 0 - NOT DETERMINED < - LESS THAN PAGE 11 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED L. \;~ --~~ PRODUCT CODE- 26020 NAME UNLEADED PREMIUM GASOLINE 17 PRODUCT LABEL (CONT) 01-03-96 12-08-95 Date Issued Supersedes Label Date 12-08-95 * Gasoline * Methyl-t-butyl ether * Ethyl-t-butyl ether * Tertiary amyl methyl ether * Ethyl alcohol * Xylenes * Toluene * Benzene (if RFG o 99% max ) * 1 2.4-trimethylbenzene * N-hexane * Ethylbenzene 1634-04-4 637-92-3 994-05-8 64-17-5 1330-20-7 108-88-3 71-43-2 95-63-6 110-54-3 100-41-4 PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910 1200) * COMPONENT IS HAZARDOUS ACCORDING TO OSHA Pennsvlvania Special Hazardous Substance(s) Benzene (if RFG, 0 99% max ) CAS Number 71-43-2 Health Flammability HMIS 1 Reactivity 0 3 Special Hea 1 th F 1 ammab i 1 i ty NFPA 1 Reactivity 0 3 Special Transportation DOT Proper Shipping Name Gasol ine Hazard Class 3 Identification Number UN1203 Packing Group II Label Required Flammable liquid Marine pollutant Not appl icable 95 00-99 99 10 00-19 99 10 00-19 99 10 00-19 99 3 00-9 99 3 00-9 99 3 00-9 99 1 00-2 99 1 00-2 99 1 00-2 99 1 00-2 99 Ranqe in % 1 00-2 99 This product contains a DOT Hazardous Substance or Substances listed in Section 14 of the MSDS If the product's shipping container holds at least 714 lbs then the DOT information must be accompanied with RQ notation or an otherwise 'Not Regulated' product will be classified as Environmentally Hazardous (solid/liquid) NOS Class 9 unless the product qualifies for the petroleum exemption (49 CFR 1718) CAUTI ON Misuse of empty containers can be hazardous Empty containers can be hazardous if used to store toxic flammable or reactive materials Cutting or welding of empty containers might cause fire explosion or toxic fumes from residues Do not pressurize or expose to open flame or heat Keep container closed and drum bungs in place Manufacturer's Name and Address TEXACO REFINING AND MARKETING INC POBox 7812 Universal City CA 91608 TRANSPORTATION EMERGENCY Company CHEMTREC (914) 831-3400 (800) 424-9300 HEALTH EMERGENCY Company (914) 831-3400 A~ ~~~ -<~,,;~;,., Date Issued. 03-20-96 Supersedes 12-08-95 TEXACO MATERIAL SAFETY DATA SHEET NOTE Read and understand Material Safety Data Sheet before handling or disposing of product CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL IDENTITY Product Code and Name 26120 DIESEL 2 Chemical Name and/or Family or Description Diesel Fuel Manufacturer's Name and Address TEXACO REFINING AND MARKETING, INC POBox 7812 Universal City, CA 91608 Telephone Numbers Transportation Emergency-Company CHEMTREC -Company Health Emergency General MSDS Assistance Technical Information -Fuels -Chemical -Lubricant/ Antifreezes -Additives -Solvents (914) 831-3400 (800) 424-9300 (914) 831-3400 (914) 838-7204 (914) 838-7336 (512) 459-6543 (800) 782-7852 (713) 235-6278 (800) 876-3738 This Material Safety Data Sheet may be used for the following products for Hazard Communications purposes only, not intended to imply identical performance/technical specifications 00408 LOW POUR DIESEL 2 00417 HIGH SULFUR LOW POUR RR DIESEL 2 00421 HIGH SULFUR SPECIAL RAILROAD DIESEL 2 00424 TEXACO DIESEL 2 00428 TEXACO LOW SULFUR DIESEL 2 00429 LOW SULFUR DIESEL 2 00430 TEXACO LOW SULFUR CARS DIESEL 2 00435 HIGH SULFUR DIESEL 2 00439 TEXACO PREMIUM DIESEL FUEL 00449 TEXACO HIGH SULFUR DIESEL 2 00450 DIESEL 2 LGLP 00454 RAILROAD DIESEL 00456 TEXACO HIGH SULFUR DIESEL 2 00460 HIGH SULFUR DIESEL 2 00461 ASTF LOW POUR DIESEL 00493 TEXACO HIGH SULFUR WINTERIZED PREMIUM DIESEL 2 00559 LOW SULFUR CARB DIESEL 2 00560 TEXACO LOW SULFUR PREMIUM DIESEL NO 2 00571 LOW SULFUR PREMIUM DIESEL NO 2 00578 HIGH SULFUR PREMIUM DIESEL 2 00634 TEXACO HIGH SULFUR (0 3%) DIESEL 2 00639 TEXACO LOW SULFUR WINTERIZED PREMIUM DIESEL 2 00643 LOW SULFUR LOW POUR DIESEL 2 00651 HIGH SULFUR (3 0%) DIESEL 2 00652 LOW SULFUR PREMIUM DIESEL 2 00665 TEXACO LOW SULFUR WINTERIZED PREMIUM DIESEL 2 00667 TEXACO LOW SULFUR PREMIUM DIESEL 2 00686 TEXACO LOW SULFUR WINTERIZED PREMIUM DIESEL 2 01467 TAX EXEMPT TEXACO LOW SULFUR DIESEL 2 01468 TAX EXEMPT LOW SULFUR DIESEL 2 01469 TAX EXEMPT TEXACO LOW SULFUR PREMIUM DIESEL 2 01470 TAX EXEMPT LOW SULFUR PREMIUM DIESEL 2 01471 TAX EXEMPT TEXACO LS WNTRZ'D 30/70 DIESEL 2 01472 TAX EXEMPT LOW SULFUR WINTERIZED 30/70 DIESEL 2 01473 TAX EXEMPT TEXACO LS WTZ'D 30/70 PREM DIESEL2 01474 TAX EXEMPT TEXACO LS WNTRZ'D 50/50 DIESEL 2 01475 TAX EXEMPT LOW SULFUR SINTERIZED 50/50 DIESEL 2 01476 TAX EXEMPT TEXACO LS W 50/50 PREM DIESEL 2 01477 TAX EXEMPT TEXACO LS WNTRZ'D 70/30 DIESEL 2 01479 TAX EXEMPT TEXACO LOW SULFUR CARB DIESEL 2 PAGE 1 N 0 - NOT DETERMINED N A - NOT APPLICABLE N T - NOT TESTED < - LESS THAN > - GREATER THAN ..,~ ~~~ , PRODUCT CODE 26120 NAME DIESEL 2 Date Issued 03-20-96 Supersedes 12-08-95 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION (CONn 01480 TAX EXEMPT LOW SULFUR CARB DIESEL 2 01483 TEXACO ALASKA TAXABLE HIGH SULFUR DIESEL 2 01484 ALASKA TAXABLE HIGH SULFUR DIESEL 2 01485 TAX EXEMPT LOW POUR LOW SULFUR DIESEL 2 02602 2602 DIESEL CHIEF 02624 2624 TEXACO DIESEL FUEL 02643 TEXACO LOW SULFUR WINTERIZED 70/30 DIESEL 2 02673 TEXACO LOW SULFUR WINTERIZED 50/50 DIESEL 2 02675 LOW SULFUR WINTERIZED 70/30 DIESEL 2 02677 LOW SULFUR WINTERIZED 30/70 DIESEL 2 02679 LOW SULFUR WINTERIZED 50/50 DIESEL 2 02685 TEXACO LOW SULFUR WINTERIZED DIESEL 2 2 COMPOSITION/INFORMATION ON INGREDIENTS THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS FOLLOWS CARCINOGENS ARE LISTED WHEN PRESENT AT 0 1 % OR GREATER COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN PRESENT AT 1 0 % OR GREATER, NON-HAZARDOUS COMPONENTS ARE LISTED AT 3 0 % OR GREATER THIS IS NOT INTENDED TO BE A COMPLETE COMPOSITIONAL DISCLOSURE REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND OTHER REGULATORY INFORMATION Product and/or Component(s) Carcinogenic According to OSHA IARC NTP OTHER NONE X Composition (Sequence Number and Chemical Name) ~ Chemical Name CAS Number Ranqe in % 01 * A complex mixture of hydrocarbons produced by crude oil distillation Consists pre- dominantly of hydrocarbons ranging from C-9 to C-20 and boil ing in the range of 325- 675F The hydrotreated or hydrosulfurized product also contains some hydrocarbons produced by the distillation of the catalytic cracking The latter materials contain bicycl ic and tricyclic aromatic hydrocarbons 100 00 PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910 1200) * COMPONENT IS HAZARDOUS ACCORDING TO OSHA Exposure Limits referenced by Sequence Number in the Composition Section ~ Limit None 3 HAZARD IDENTIFICATION EMERGENCY OVERVIEW Appearance Bright and clear 1 iquid (Tax Exempt Diesels - pale red liquid) Odor Petroleum odor WARNING WARNING STATEMENT MAY CAUSE DIZZINESS AND DROWSINESS CAUSES SKIN IRRITATION MAY CAUSE EYE IRRITATION ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE COMBUSTIBLE LIQUID AND VAPOR USE ONL\ AS A FUEL MAY CAUSE DELAYED SKIN DAMAGE BASED ON ANIMAL DATA CONTAINS MIDOLE OISTILLATES WHICH MAY CAUSE CANCER BASED ON ANIMAL DATA ATTENTION! Hea 1 th Flammabil ity HMIS 1 Reactivity 0 2 Special NFPA 1 Reactivity 0 2 Special Health F 1 ammab i 1 i ty N 0 - NOT DETERMINED < - LESS THAN PAGE 2 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4~ ~.~ .,. PRODUCT CODE 26120 NAME DIESEL 2 Date Issued supersedes 03-20-96 12-08-95 3 HAZARD IDENTIFICATION (CONT) POTENTIAL HEALTH EFFECTS EYE Primary Route of Exposure X SKIN ~ INHALATION ~ INGESTION EFFECTS OF OVEREXPOSURE Acute ~ Eyes May cause irritation, experienced as mild discomfort and seen as slight excess redness of the eye Skin Causes irritation with discomfort or pain, and seen as marked local redness and swelling, with possible bl ister formation Other than the potential skin irritation effects noted above, acute (short term) adverse effects are not expected from brief skin contact see other effects below, and Section 11 for information regarding potential long term effects Prolonged widespread or repeated skin contact may result in the absorption of potentially harmful amounts of material Inhalation Vapors or mist may cause irritation of the nose and throat Inhalation may cause dizziness drowsiness euphoria loss of coordination disorientation headache nausea and vomiting In poorly ventilated areas or confined spaces, unconsciousness and asphyxiation may result Prolonged or repeated overexposure may result in the absorption of potentially harmful amounts of material Ingestion If more than several mouthfuls are swallowed abdominal discomfort nausea and diarrhea may occur Aspiration may occur during swallowing or vomiting resulting in lung damage Sensitization Properties Unknown Chronic NIOSH has recommended that whole diesel exhaust be regarded as a potential occupational carcinogen based on' ~indings of carcinogenlc responses in laboratory animals exposed to whole diesel eyhaust The excess cancer risk for workers exposed to diesel exhaust has not been calculated the proba- bility of developing cancer should be decreased by minimizing exposure to the lowest feasible limits Repeated skin contact may cause a persistent irritation or dermatitis Medical Conditions Aggravated by Exposure Skin contact may aggravate an existing dermatitis (skin condition) Other Remarks None 4 FIRST AID MEASURES Eyes Immediately flush eyes with plenty of water for at least 15 minutes Hold evel ids apart while flushing to rinse entire surface of eve and lids with water Get medica' attention Skin Immediately remove contaminated clothing and shoes Under a safety shower flush skin thoroughl, with large amounts of running water for at least 15 minutes Do not attempt to neutral ize with chemical agents Get medical attention immediately Discard or decontaminate clothing and shoes before reuse N 0 - NOT DETERMINED < - LESS THAN PAGE 3 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4'~ ,,~~ PRODUCT CODE 26120 NAME DIESEL 2 Date Issued supersedes 03-20-96 12-08-95 4 FIRST AID MEASURES (CaNT) Ingestlon If person is conscious and can swallow, give two glasses of water (16 oz but do not induce vomiting If vomiting occurs give fluids again Have medical personnel determine it evacuation of stomach or induction of vomiting is necessary Do not give anything by mouth to an unconscious or convulsing person ~ Inhalatlon If inhaled, remove to fresh air and give artificial respiration medical personnel may administer If not breathing, clear person's airway If breathing is difficult qualified oxygen Get medical attention immediately Other Instructlons Remove and dry-clean or launder clothing soaked or soiled with this material before reuse Dry cleaning of contaminated clothing may be more effective than normal laundering Inform individuals responsible for cleaning of potential hazards associated with handling contaminated clothing Aspiration of this product during induced emesis may result in severe lung injury If evacuation of stomach is necessary, use method least likely to cause aspiration such as gastric lavage after endotracheal intubation Contact a Poison Center for additional treatment information 5 FIRE-FIGHTING MEASURES Ignltlon Temperature - AIT (degrees F) 500 Flash Point (degrees F) 125 (CC) Flammable Limits (%) Lower 5 Upper 4 1 Recommended Fire Extlnguishing Agents And Special Procedures Use water spray dry chemical foam or carbon dioxide to extinguish flames Use water spray to cool fire-exposed containers Unusual or Exploslve Hazards None SpeCial Protective Equipment for Firefighters Wear full protective clothing and positive pressure breathing apparatus 6 ACCIDENTAL RELEASE MEASURES (Transportation Spills CHEMTREC (800)424-9300) Procedures in Case of Accidental Release, Breakage or Leakage Ventilate area Avoid breathing vapor Wear appropriate personal protective equipment including appropriate respiratory protection Contain spill if possible Wipe up or absorb on suitable material and shovel up Prevent entry into sewers and waterways Avoid contact with skin eyes or clothing If more than 100 000 pounds of product is spilled then report spill according to SARA 304 and/or CERCLA 102(a) requirements unless product qualifies for the petroleum exemption (CERCLA Section 101(14)) 7 HANDLING AND STORAGE Precautions to be Taken ln Handling Eye wash and safety shower should be available nearby when this product is handled or used Storage Store away from heat and open flame Periods of exposure to high temperatures should be minimized Water contamination should be avoided PAGE 4 - NOT APPLICABLE - GREATER THAN N T - NOT TESTED N 0 < - NOT DETERMINED - LESS THAN N A > 4~. ~~tf - PRODUCT CODE 26120 NAME DIESEL 2 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Date Issued Supersedes 03-20-96 12-08-95 Protective Equipment (Type) Eye/Face Protection Safety glasses chemical type goggles or face shield recommended to prevent eye contact Skin Protection Protective clothing such as coveralls or lab coats should be worn Launder ~ or dry-clean when soiled Gloves resistant to chemicals and petroleum distillates required When handling large quantities impervious suits gloves and rubber boots must be worn Respiratory Protection Airborne concentrations should be kept to lowest levels possible If vapor, mist or dust is generated and the occupational exposure limit of the product or any component of the product is exceeded. use appropriate NIOSH or MSHA approved air purifying or air supplied respirator after determining the airborne concentration of the contaminant Air supplied respirators should always be worn when airborne concentration of the contaminant or oxygen content is unknown Ventilation Local exhaust ventilation recommended if generating vapor If exhaust ventilation is not available or inadequate use approved respirator as appropriate dust or mist MSHA or NIOSH Exposure Limit for Total Product None establ 1shed for product refer to Section 2 for component exposure 1 imits 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Bright and clear 1 iquid (Tax Exempt Diesels - pale red 1 iquid) Odor Petroleum odor Boiling Point (degrees F) 650 Melting/Freezing point (degrees F) Not appl icable Specific Gravity (water=1) 8521 pH of undiluted product Not app 1 i cab 1 e Vapor Pressure 07 - 3 mmHg at 100 0 Viscosity 3 cSt at 37 7 C VOC Content Not determined Vapor Density lair=1l Not determined Solubility in Water (%1 1 Other None N D - NOT DETERMINED < - LESS THAN PAGE 5 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4~ ~.~ PRODUCT CODE 26120 NAME DIESEL 2 Date Issued Supersedes 03-20-96 12-08-95 10 STABILITY AND REACTIVITY This Material Reacts Violently With (If Others is checked below see comments for details) Air Water Heat Strong Oxidizers Others None of These X X Comments None Products Evolved When Subjected to Heat or Combustion Toxic levels of carbon monoxide carbon dioxide irritating aldehydes and ketones Hazardous Polymerizations DO NOT OCCUR 11 TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA) Median Lethal Dose Oral LD50 Similar product 9 00 ml/kg (rat) practically non-toxic Inhalation Not determined Dermal LD50 Similar product> 5 00 ml/kg (rabbit) practically non-toxic Irritation Index Estimation of Irritation (Species) Skin (Draize) Similar product 5 29 /8 0 (rabbit) severely irritating Eyes (Oraize) Bel ieved to be > 15 00 - 25 00 /110 (rabbit) slightly irritating Sensitization Not determined Other Middle distillates have caused skin irritation and skin cancer in laboratory animals when repeatedly appl ied and left in place between appl ications Studies to further evaluate the carcinogenic potential of middle distillates are currently underway Kidney damage has also been observed in laboratory animals exposed to middle distillates Necrosis was seen on animals a few days after dermal application of this product or a component of this product However the skin returned to a normal condition within the observation period 12 DISPOSAL CONSIDERATIONS Waste Disposal Methods This product (as presently constituted) has the RCRA classification of benzene toxicity and ignitability If discarded in its present form it would have the hazardous waste numbers 0018 and 0001 respectively Under RCRA it is the responsibil ity of the user of the product to determine at the time of disposal whether the product meets RCRA crIterIa for hazardous waste This is because product uses transformations mixtures processes etc may change the classification to non-hazardous or hazardous for reasons other than or in addition to benzene toxicity and ignitabilty Remarks None 13 TRANSPORT INFORMATION Transportation DOT Proper Shipping Name Fuel 0 i 1 Hazard Class Combustible liquid (LAND TRANSPORT ONLY-49CFR 173 120(bl(2)) Identification Number NA 1993 Packing Group III Label Required None Marine pollutant No t app 1 i cab 1 e N D - NOT DETERMINED < - LESS THAN PAGE 6 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4'ti\ t~~ , PRODUCT CODE- 26120 NAME DIESEL 2 13 TRANSPORT INFORMATION (CONT) Date Issued Supersedes. 03-20-96 12-08-95 IMDG Proper Shipping Name Not evaluated ICAO Proper Shipping Name Not evaluated TOG Proper Shipping Name Not evaluated 14 REGULATORY INFORMATION Federal Regulations SARA Title III Section 302/304 Extremely Hazardous Substances ~ Chemical Name CAS Number None Section 302/304 Extremely Hazardous Substances (CONT) ~ TPO RQ None Ran~e in % Section 311 Hazardous Categorization Acute Chronic Fire Pressure ~ ~ ~ Reactive N/A Section 313 Toxic Chemical Chemical Name None Concentration CAS Number CERCLA 102(a)/DOT Hazardous Substances ~ Chemical Name 01+ Benzene, (1-methylethyl) - 02+ Benzene CERCLA/DOT Hazardous ~RO 01+ 02+ (+ indicates DOT Hazardous Substance) CAS Number Ran~e in % 98-82-8 0 01-0 09 71-43-2 0 01-0 09 RQJs) Substances (Sequence Numbers and 5000 10 TSCA Inventory Status This product or its components are listed on or are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance Inventory Other None State Regulations California Proposition 6S The following detectable components or belong to classes of substances, to cause cancer and/or reproductive Chemical Name Benzene of this product are substances, known to the State of California toxicity CAS Number 71-43-2 States Right-to-know RegUlations Chemical Name Benzene (1-methylethyl)- Ben;;;ene 1 2 4-trimethylbenzene State Riaht-to-know CT FL,IL MA NJ PA RI MI CT FL IL MA NJ PA RI MI MA NJ,PA State list CT (Connecticut) FL (Florida) IL (Illinois) Ml (Michigan), LA (Louisiana) MA (Massachusetts) NJ (New Jersey) PA (Pennsylvania) RI (RhOde Island) International Regulations WHMIS Classification Not determined N 0 - NOT DETERMINED < - LESS THAN PAGE 7 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4'tt.. ~~~ " PRODUCT CODE 26120 NAME DIESEL 2 Date Issued supersedes 03-20-96 12-08-95 14 REGULATORY INFORMATION (CONT) Canada Inventory Status Not determined EINECS Inventory Status Not determined Australia Inventory Status Not determined Japan Inventory Status Not determined 15 ENVIRONMENTAL INFORMATION Aquatic Toxicity Not determined Mobility Not determined Persistence and Biodegradability Nbt determined Potential to Bioaccumulate Not determined Remarks None 16 OTHER INFORMATIDN THIS PRODUCT IS INTENDED FOR USE AS A MOTOR FUEL ONLY This product is not intended for use in space heaters agricultural sprays Do not use in Texaco recommends that all exposures to this product be minimized by strictly adhering to recQmmended occupational controls procedures to avoid any potential adverse health effects THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT FOR PURPOSE OF HAZARD COMMUNICATION AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM IT IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT NO EXPRESS WARRANTY OR IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION CONTAINED HEREIN DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY PROCESS USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN TO DETERMINE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT, USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY TEXACO DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS Date 03-20-96 Date printed 03-30-96 x Revised Supersedes 12-08-95 New Inquiries regarding MSDS should be directed to Texaco In::: Manager Product Safety POBox 509 Beacon N Y 12508 PLEASE SEE NEXT PAGE FOR PRODUCT LABEL N 0 - NOT DETERMINED < - LESS THAN PAGE 8 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4~ ~~~ , PRODUCT CODE 26120 NAME DIESEL 2 Date Issued Supersedes 03-20-96 12-08-95 17 PRODUCT LABEL Label Date 03-20-96 READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANOLING OR DISPOSING OF PRODUCT THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910 1200) FOR USE IN THE WORKPLACE THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS 26120 DIESEL 2 WARNING ! WARNING STATEMENT MAY CAUSE DIZZINESS AND DROWSINESS CAUSES SKIN IRRITATION MAY CAUSE EYE IRRITATION ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE COMBUSTIBLE LIQUID AND VAPOR USE ONLY AS A FUEL MAY CAUSE DELAYED SKIN DAMAGE BASED ON ANIMAL DATA CONTAINS MIDDLE DISTILLATES WHICH MAY CAUSE CANCER BASED QN ANIMAL DATA ATTENTION PRECAUTIONARY MEASURES -Use only with adequate ventilation -Keep away from heat and flame -Avoid breathing vapor mist or gas -Avoid contact with eyes skin and clothing -Keep container closed -Never siphon by mouth -Wash thoroughly after handl ing FIRST AID Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes Hold evelids apart while flushing to rinse entire surface of eye and 1 ids with water Get medical attention Skin Contact Immediately remove contaminated clothing and shoes Under a safety shower flush skin thoroughly with large amounts of running water for at least 15 minutes Do not attempt to neutral ize with chemical agents Get medical attention immediately Discard or decontaminate clothing and shoes before reuse Ingestion If person is conscious and can swallow give two glasses of water (16 oz but do not induce vomiting If vomiting occurs give fluids ?gpin Have medical personnel determine if evacuation of stomach or induction of vomiting is necessary Do not give anything by mouth to an unconscious or convulsing person Inhalation If inhaled remove to fresh air and give artificial respiration medical personnel may administer If not breathing clear person s airway If breathing is difficult qual fied oxygen Get medical attention immediately Note to Physician Aspiration of this product during induced emesis may result in severe lung injury If evacuation of stomach is necessary use method least 1 ikely to cause aspiration such as gastric lavage after endotracheal intubation Contact a Poison Center for additional treatment information FIRE In case of fire use water spray. dry chemical foam or carbon dioxide Water may cause frothing Use water spray to cool fire-exposed containers If more than 100 000 pounds of product is spilled then report spill according to SARA 304 and/or CERCLA 102(a) requirements unless product qual ifies for the petroleum exemption (CERCLA Section 101( 14)) Chemical Name CAS Number Ran<:je in % PAGE 9 N A NOT APPLICABLE > - GREATER THAN N T - NOT TESTED N D NOT DETERMINED < - LESS THAN 4... ~~~ ... PRODUCT CODE 26120 NAME DIESEL 2 Date Issued Supersedes 03-20-96 12-08-95 17 PRODUCT LABEL (CONT) Label Date 03-20-96 * A complex mixture of hydrocarbons produced by crude oil distillation Consists pre~ dominantly of hydrocarbons ranging from C-9 to C-20, and boiling in the range of 325- 675F The hydrotreated or hydrosulfurized product also contains some hydrocarbons produced by the distillation of the catalytic cracking The latter materials contain bicycl ic and tricyclic aromatic hydrocarbons 100 00 PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910 1200) * COMPONENT IS HAZARDOUS ACCORDING TO OSHA Pennsylvania Special Hazardous Substance(s) Benzene RanQe in % o 01-0 09 CAS Number 71-43-2 Health Flammabil ity HMIS 1 Reactivity 0 2 Special NFPA 1 Reactivity 0 2 Special Health F 1 ammab i 1 i ty Transportation DOT Proper Shipping Name Fuel Oi 1 Hazard Class Combustible liquid (LANO TRANSPORT ONLY-49CFR 173 120(b)(2)) Identification Number NA 1993 Packing Group III Label Required None Marine pollutant Not applicable CAUTI ON Misuse of empty containers can be hazardous Empty containers can be hazardous if used to store toxic, flammable or reactive materials Cutting or welding of empty containers might cause fire explosion or toxic fumes from residues Do not pressurize or expose to open flame or heat Keep container closed and drum ,bu_ngs in place Manufacturer's Name and Address TEXACO REFINING AND MARKETING INC POBox 7812 Universal City CA 91608 TRANSPORTATION EMERGENCY Company CHEMTREC (914) 831-3400 (800) 424-9300 HEALTH EMERGENCY Company (914) 831-3400 4~ \t._ ... Date Issued Supersedes 12-08-95 07-06-95 TEXACO MATERIAL SAFETY DATA SHEET NOTE Read and understand Material Safety Data Sheet before handling or disposing of product CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL IDENTITY Product Code and Name 02353 TEXACO ANTIFREEZE/COOLANT Chemical Name and/or Family or Description Antifreeze Manufacturer's Name and Address TEXACO LUBRICANTS COMPANY A DIVISION OF TEXACO REFINING AND MARKETING INC POBox 4427 Houston, TX 77210-4427 Telephone Numbers Transportation Emergency-Company CHEMTREC -Company (914) 831-3400 (800) 424-9300 (914) 831-3400 (914) 838-7204 (914) 838-7336 (512) 459-6543 (800) 782-7852 Health Emergency General MSDS Assistance Technical Information -Fuels -Chemical -Lubricant/ Antifreezes -Additives -Solvents (713) 235-6278 (800) 876-3738 2 COMPOSITION/INFORMATION ON INGREDIENTS THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS FOLLOWS CARCINOGENS ARE LISTED WHEN PRESENT AT 0 1 % OR GREATER, COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN PRESENT AT 1 0 % OR GREATER NON-HAZARDOUS COMPONENTS ARE LISTED AT 3 0 % OR GREATER THIS IS NOT INTENDED TO BE A COMPLETE COMPOSITIONAL DISCLOSURE REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND OTHER REGULATORY INFORMATION Product and/or Component(s) Carcinogenic According to OSHA IARC NTP OTHER NONE X Composition (Sequence Number and Chemical Name) ~ Chemical Name CAS Number Ranqe in % 107-21-1 80 00-94 99 7732-18-5 3 00-9 99 7758-11-4 1 00-2 99 01 * 1 2 ethanediol 02 Water deionized 03 * Phosphoric acid dipotassium salt PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910 1200) * COMPONENT IS HAZARDOUS ACCORDING TO OSHA Exposure Limits referenced by Sequence ~ Limit 01 50 01 39 4 Number in the Composition Section ppm CEILING-OSHA ppm CEILING-ACGIH (AEROSOL) (A4) 3 HAZARD IDENTIFICATION EMERGENCY OVERVIEW Appearance Fluorescent green liquid Odor Mi ld odor N 0 - NOT DETERMINED < - LESS THAN PAGE 1 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4~ t(L~ , PRODUCT CODE 02353 NAME TEXACO ANTIFREEZE/COOLANT Date ~ssued Supersedes 12-08-95 07-06-95 3 HAZARD IDENTIFICATION (CaNT) WARNING WARNING STATEMENT HARMFUL IF SWALLOWED MAY CAUSE DIZZINESS AND DROWSINESS MAY CAUSE EYE IRRITATION ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE ' FOR INDUSTRIAL USE ONLY CAN CAUSE KIDNEY DAMAGE IF SWALLOWED MAY CAUSE LIVER DAMAGE IF SWALLOWED BASED ON ANIMAL DATA CONTAINS ETHYLENE GLYCOL WHICH MAY CAUSE BIRTH DEFECTS BASED ON ANIMAL DATA ATTENTION HMIS NFPA Hea 1 th 2 Reactivity 0 Health 2 Reactivity 0 F 1 ammab i 1 i ty 1 Special Flqmmability 1 Special POTENTIAL HEALTH EFFECTS EYE SKIN INHALATION INGESTION Primary Route of Exposure ~ X ~ EFFECTS OF OVEREXPOSURE Acute Eyes May cause irritation experienced as mild discomfort and seen as slight excess redness of the eye Skin Brief contact may cause sl ight irritation Prolonged contact as with clothing wetted with material may cause more severe irritation and dis- comfort seen as local redness and swelling Other than the potential skin irritation effects noted above acute (short term) adverse effects are not expected from brief skin contact see other effects, below and Section 11 for information regarding potential long term effects Inhalation Vapors or mist in excess of permissible concentrations or in unusually high concentrations generated from spraying heating the material or as from exposure in poorly ventilated areas or confined spaces may cause irritation of the nose and throat headache nausea and drowsiness Prolonged or repeated overexposure may result in the absorption of potentlally harmful amounts of material Ingestion Contains ethylene glycol and/or diethylene glycol which are toxic when swallowed A lethal dose for an adult is 1-2 ml per kilogram or about 4 ounces (one-half cup) Symptoms include headache weakness confusion diz- ziness staggering slurred speech loss of coordination faintness nausea and vomiting increased heart rate decreased blood pressure difficulty breathing and seeing pulmonary edema unconsciousness convulsions collapse and coma Symptoms may be delayed Decreased urine output and kidney falure may also occur Severe poisoning may cause death Aspiration may occur during swallowing or vomiting resulting in lung damage Sensitization Properties Unknown Chronic Repeated ingestion may cause kidney damage Medical Conditions Aggravated by Exposure Repeated overexposure may aggravate existing kidney disease Because of its irritating properties repeated skin contact may aggravate an existing dermatitis (skin condition) N 0 - NOT DETERMINED < - LESS THAN PAGE 2 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4~ ~l.~ PRODUCT CODE 02353 NAME TEXACO ANTIFREEZE/COOLANT - 12-08-95 07-06-95 Date Issued Supersedes 3 HAZARD IDENTIFICATION (CONT) Other Remarks None 4 FIRST AID MEASURES Eyes Immediately flush eyes with plenty of water for at least 15 minutes Hold eyelids apart while flushing to rinse entire surface of eye and lids with water Get medical attention Skin Wash skin with plenty of soap and water for several minutes attention if skin irritation develops or persists Get medical Ingestion If person is conscious and can swallow immediately give two glasses of water (16 oz ) but do not induce vomiting If vomiting occurs give fluids again Have physician determine if condition of person will permit induction of vomiting or evacuation of stomach Do not give anything by mouth to an unconscious or convulsing person Inhalation If irritation headache, nausea or drowsiness occurs remove to fresh air Get medical attention if breathing becomes difficult or respiratory irritation persists Other Instructions Ethylene glycol (EG) and diethylene glycol (DEG) intoxication may initially produce behavioral changes drowsiness vomiting diarrhea thirst and convulsions EG and DEG are nephrotoxic End stages of poison- ing may include renal damage or failure with acidosis Supportive measures supplemented with hemodialysis if indicated may 1 imit the progression and severity of toxic effects FOR ETHYLENE GLYCOL POISONING intravenous ethanol is a recognized antidotal treatment other antidotal treatments also exist for EG poisoning FOR DIETHYLENE GLYCOL POISONING the role of intravenous ethanol in the treatment is unclear but it may be of benefit in view of structural and toxicological similarities to ethylene glycol Contact a Poison Center for further treatment information Aspiration of this product during induced emesis mav result in severe lung injury If evacuation of stomach is necessary use method least likely to cause aspiration such as gastric lavage after endotracheal intubation Contact a Poison Center for additional treatment information 5 FIRE-FIGHTING MEASURES Ignition Temperature - AIT (degrees F) Not determined Flash Point (degrees F) 244 (CC) Flammable Limits (%) Lower Not determined Upper Not determined Recommended Fire Extinguishing Agents And Special Procedures Use water spray dry chemical foam or carbon dioxide to extinguish flames Use water spray to cool fire-exposed containers Water or foam may cause frothing Unusual or Explosive Hazards None Extinguishing Media Which Must Not Be Used Not determined Special Protective Equipment for Firefighters Wear full protective clothing and positive pressure breathing apparatus Approach fire from upwind to avoid hazardous vapors and toxic decomposition products PAGE 3 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED N 0 - NOT DETERMINED < - LESS THAN A€~ ~1.t1 ". PRODUCT CODE 02353 NAME TEXACO ANTIFREEZE/COOLANT Date issued supersedes 12-08-95 07-06-95 6 ACCIDENTAL RELEASE MEASURES (Transportation Spills CHEMTREC (800)424-9300) Procedures in Case of Accidental Release, Breakage or Leakage Ventilate area Avoid breathing vapor Wear appropriate personal protective equipment including appropriate respiratory protection Contain spill if possible Wipe up or absorb on suitable material and shovel up Prevent entry into sewers and waterways Avoid contact with skin eyes or clothing If more than 5 269 pounds of product is spilled then report spill according to SARA 304 and/or CERCLA 102(a) requirements unless product qualifies for the petroleum exemption (CERCLA Section 101(14)) 7 HANDLING AND STORAGE Precautions to be Taken in Handl i ng Minimum feasible handling temperatures should be maintained Storage Periods of exposure to high temperatures should be minimized Water contamination should be avoided 8 EXPOSURE CDNTROLS/PERSONAL PROTECTION Protective Equipment (Type) Eye/Face Protection Safety glasses chemical type goggles, or face shield recommended to prevent eye contact Skin Protection Workers should wash exposed skin several times daily with soap and water Soiled work clothing should be laundered or dry-cleaned Respiratory Protection Airborne concentrations should be kept to lowest levels possible If vapor mist or dust is generated and the occupational exposure limit of the product or any component of the product is exceeded use appropriate NIOSH or MSHA approved air purifying or air supplied respirator after determining the airborne concentration of the contaminant Air supplied respirators should always be worn when airborne concentration of the contaminant or oxygen content is unknown Ventilation Adequate to meet component occupational exposure limits (see Section 2) Exposure Limit for Total Product None establ ished for product refer to Section 2 for component exposure 1 imi ts 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Fluorescent green 1 iquid Odor Mild odor Boiling Point (degrees F) 388 Melting/Freezing point (degrees F) Not app 1 i cab 1 e Specific Gravity (water=1) 1 13 pH of undiluted product 11 Vapor Pressure < 1 mmHg Viscosity < 20 cSt at 40 0 C N 0 - NOT DETERMINED < - LESS THAN PAGE 4 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4,.. ~J.~ '" PRODUCT CODE 02353 NAME TEXACO ANTIFREEZE/COOLANT 9 PHYSICAL AND CHEMICAL PROPERTIES (CONT) Date Issued Supersedes 12-08-95 07-06-95 VOC Content Not determined Vapor Density (air=1) 2 1 Solubility in Water (%) > 10 Other None 10 STABILITY AND REACTIVITY This Material Reacts Violently With (If Others is checked below see comments for details) Air Water Heat Strong Oxidizers Others None of X These Comments None Products Evolved When Subjected to Heat or Combustion Toxic levels of carbon monoxide carbon dioxide irritating aldehydes and ketones may be formed on burning Heating in air may produce irritating aldehydes acids and ketones Hazardous Polymerizations DO NOT OCCUR 11 TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA) Median Lethal Dose Oral Animal data does not reflect human toxicity see Sections 3 & 11 Inhalation Not determined Denna 1 LD50 Believed to be < 100 - 2 00 g/kg (rabbit) slightly toxic Irritation Index, Estimation of Irritation (Species) Skin (Draize) Believed to be > 50 - 3 00 /8 0 (rabbit) slightly irritating Eyes (Draize) Believed to be > 15 00 - 25 00 /110 (rabbit) slightly irritating Sensitization Not determined Other Oral administration of ethylene glycol to pregnant experimental animals has been shown to cause birth defects in the offspring These effects were not seen when ethylene glycol was administered by dermal application or by inhalation Continuous ingestion of a diet contaning 1% or 2% ethylene glycol for two years produced liver and kidney damage and bladder stones in rats 12 DISPOSAL CONSIDERATIONS Waste Disposal Methods This product has been evaluated for RCRA characteristics and does not meet the criteria of a hazardous waste if discarded in its purchased form Under RCRA, it is the responsibility of the user of the product to deter- mine at the time of disposal, whether the product meets RCRA criteria for hazardous waste This is because product uses transformations mixtures processes etc may render the resulting materials hazardous Remarks To prevent contamination of drinking water suppl ies, and poisoning of children aquatic life wildlife and farm and domestic animals, ethylene glycol products such as used antifreeze solution, regardless of quantity should never by discarded onto the ground, into surface waters or into storm sewers N D - NOT DETERMINED < - LESS THAN PAGE 5 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED Alltt.. ".l.~ , PRODUCT CODE 02353 NAME TEXACO ANTIFREEZE/COOLANT Date rssued Supersedes 12-08-95 07-06-95 13 TRANSPORT INFORMATION Transportation DOT Proper Shipping Name Not regulated This product contains a DOT Hazardous Substance or Substances, listed in , Section 14 of the MSDS If the product's shipping container holds at least 5 269 lbs, then the DOT information must be accompanied with RQ notation or an otherwise 'Not Regulated' product will be classified as Environmentally Hazardous (sol id/l iquid) NOS Class 9 unless the product qualifies for the petroleum exemption (49 CFR 1718) IMDG Proper Shipping Name Not evaluated ICAO Proper Shipping Name Not evaluated TDG Proper Shipping Name Not evaluated 14 REGULATORY INFORMATION Federal Regulations SARA Tit 1 e II I Section 302/304 Extremely Hazardous Substances ~_ Chemical Name CAS Number None Section 302/304 Extremely Hazardous Substances (CONT) ~ TPQ RO None Range in % Section 311 Hazardous Categorization Acute Chronic Fire Pressure X X Reactive N/A Section 313 Toxic Chemical Chemical Name 1 2 ethanediol CAS Number Concentration 107-21-1 80 00-94 99 CERCLA 102(a)/DOT Hazardous Substances ~ Chemical Name 01+ 1 2 ethanediol 02+ Disodium hydrogen phosphate 03+ Sodium hydroxide CERCLA/DOT HaZardous Substances (Sequence ~RO 01+ 02+ 03+ (+ indicates DOT Hazardous Substance) CAS Number 107-21-1 7558-79-4 1310-73-2 Numbers and RQ's) Range in % 80 00-94 99 o 10-0 99 o 00115 5000 5000 1000 TSCA Inventory Status This product, or its components are 1 isted on or are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance Inventory Other None State Regulations California Proposition 65 The following detectable components or belong to classes of substances to cause cancer and/or reproductive Chemical Name None of this product are substances known to the State of California toxicity CAS Number States Right-to-know Regulations Chemical Name State Right-to-know PAGE 6 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED N D - NOT DETERMINED < - LESS THAN Llis. ~Lf' PRODUCT CODE 02353 NAME TEXACO ANTIFREEZE/COOLANT 14 REGULATORY INFORMATION (CONT) Date Issued Supersedes 12-08-95 07-06-95 1 2 ethanediol Disodium hydrogen phosphate FL IL MA NJ PA,RI CT IL MA NJ PA State list CT (Connecticut), FL (Florida), IL (Illinois) MI (Michigan), LA (Louisiana), MA (Massachusetts), NJ (New Jersey), PA (Pennsylvania), RI (Rhode Island) ------------------------------------------------------------------------------- , International Regulations WHMIS Classification Class D, Div 1, Subdiv B Class D, Div 2 Subdiv A Toxic Teratogenic Canada Inventory Status Not determined EINECS Inventory Status Not determined Australia Inventory Status Not determined Japan Inventory Status Not determined 15 ENVIRONMENTAL INFORMATION Aquatic Toxicity Not determined Mobility Not determined Persistence and Biodegradability This product is estimated to have a moderate rate of biodegradation, greater than or equal to 30 % degradation over a test period of 28 days or 1 ess Potential to Bioaccumulate This product is estimated to have a low potential to bioconcentrate Remarks None 16 OTHER INFORMATION Acute or chronic oral consumption of products containing ethylene glycol can produce significant adverse health effects including death in humans and animals Keep out of reach of children and pets Such products should not be used in potable (drinking) water systems or other systems where con- tamination of potable water supplies is possible (e g recreational ve- hicles winterizing potable water systems) Texaco recommends that all exposures to this product be minimized by strictly adhering to recommended occupational controls procedures to avoid any potential adverse health effects THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT FOR PURPOSE OF HAZARD COMMUNICATION AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM IT IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT NO EXPRESS WARRANTY OR IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION CONTAINED HEREIN DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN < TO DETERMINE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY TEXACO DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH PAGE 7 N A - NOT APPLICABLE - GREATER THAN N 0 - NOT DETERMINED - LESS THAN N T - NOT TESTED > 4... ~~ PRODUCT CODE 02353 NAME TEXACO ANTIFREEZE/COOLANT 16 OTHER INFORMATION (CaNT) Date lssued 12-08-95 Supersedes 07-06-95 MATTERS Date 12-08-95 Date printed 02-05-96 ~ Revised Supersedes 07-06-95 New InqUiries regarding MSDS should be directed to Texaco Inc Manager Product Safety POBox 509 Beacon, N Y 12508 PLEASE SEE NEXT PAGE FOR PRODUCT LABEL N 0 - NOT DETERMINED < - LESS THAN PAGE 8 N A - NOT APPLICABLE > - GREATER THA~ N T - NOT TESTED """ 4~ ~~f , .. .f;. ." PRODUCT CODE 02353 NAME TEXACO ANTIFREEZE/COOLANT Date Issued Supersedes 12-08-95 07-06-95 17 PRODUCT LABEL Label Date 12-08-95 READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910 1200) FOR USE IN THE WORKPLACE THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS 02353 TEXACO ANTIFREEZE/COOLANT WARNING STATEMENT WARNING ! HARMFUL IF SWALLOWED MAY CAUSE DIZZINESS AND DROWSINESS MAY CAUSE EYE IRRITATION ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE FOR INDUSTRIAL USE ONLY CAN CAUSE KIDNEY DAMAGE IF SWALLOWED MAY CAUSE LIVER DAMAGE IF SWALLOWED BASED ON ANIMAL DATA ATTENTION CONTAINS ETHYLENE GLYCOL WHICH MAY CAUSE BIRTH DEFECTS BASED ON ANIMAL DATA PRECAUTIONARY MEASURES -Use only with adequate ventilation -Avoid breathing vapor mist or gas -Avoid contact with eyes skin and clothing -Keep container closed -Wash thoroughly after handling FIRST AID Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes Hold eyelids apart while flushing to rinse entire surface of eye and 1 ids with water Get medical attention Skin Contact Wash skin with plenty of soap and water for several minutes Get medical attention if skin irritation develops or persists Ingestion If person is conscious and can swallow immediately give two glasses of water (16 oz ) but do not induce vomiting If vomiting occurs give fluids again Have physician determine if condition of person will permit induction of vomiting or evacuation of stomach Do not give anything by mouth to an unconscious or convulsing person Inhalation If irritation headache nausea or drowsiness occurs remove to fresh air Get medical attention if breathing becomes difficult or respiratory irritation persists Note to Physician Ethylene glycol (EG) and diethylene glycol (DEG) intoxication may initially produce behavioral changes drowsiness vomiting diarrhea thirst and convulsions EG and DEG are nephrotoxic End stages of poison- ing may include renal damage or failure with acidosis Supportive measures supplemented with hemodialysis if indicated may limit the progression and severity of toxic effects FOR ETHYLENE GLYCOL POISONING intravenous ethanol is a recognized antidotal treatment other antidotal treatments also exist for EG poisoning FOR DIETHYLENE GLYCOL POISONING the role of intravenous ethanol in the treatment is unclear but it may be of benefit in view of structural and toxicological similarities to ethylene glycol Contact a Poison Center for further treatment information Aspiration of this product during induced emesis may result in severe lung injury If evacuation of stomach is necessary, use method least 1 ikely to cause aspiration such as gastric lavage after endotracheal intubation Contact a Poison Center for additional treatment information FIRE In case of fire use water spray dry chemical foam or carbon dioxide Water may cause frothing Use water spray to cool fire-exposed containers If more than 5 269 pounds of product is spilled, then report spill according to SARA 304 and/or CERCLA 102(a) requirements, unless product qual ifies for the petroleum exemption (CERCLA Section 101(14)) Chemical Name CAS Number Range in % N D - NOT DETERMINED < - LESS THAN PAGE 9 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED 4~ ~1.~ ". PRODUCT CODE 02353 NAME TEXACO ANTIFREEZE/COOLANT 17 PRODUCT LABEL (CaNT) Date Issued Supersedes 12-08-95 07-06-95 Label Date 12-08-95 * 1 2 ethanediol Water deionized Phosphoric acid dipotassium salt 107-21-1 80 00-94 99 7732-18-5 3 00-9 99 7758-11-4 1 00-2 99 PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910 1200) * COMPONENT IS HAZARDOUS ACCORDING TO OSHA Pennsylvania Special Hazardous Substance(s) None CAS Number Ranqe in % Hea 1 th F 1 ammab i 1 i ty HMIS 2 Reactivity 0 1 Special Health Flammability NFPA 2 Reactivity 0 1 Special Transportation DOT Proper Shipping Name Not regulated This product contains a DOT Hazardous Substance or Substances listed in Section 14 of the MSDS If the product's Shipping container holds at least 5 269 lbs then the DOT information must be accompanied with RQ notation or an otherwise 'Not Regulated' product will be classified as Environmentally Hazardous (sol id/liquid) NOS Class 9 unless the product qualifies for the petroleum exemption (49 CFR 171 8) CAUTION Misuse of empty containers can be hazardous Empty containers can be hazardous if used to store toxic flammable or reactive materials Cutting or welding of empty containers might cause fire explosion or toxic fumes from residues Do not pressurize or expose to open flame or heat Keep container closed and drum bungs in place Manufacturer's Name and Address TEXACO LUBRICANTS COMPANY A DIVISION OF TEXACO REFINING AND MARKETING INC POBox 4427 Houston TX 77210-4427 TRANSPORTATION EMERGENCY Company CHEMTREC (914) 831-3400 (800) 424-9300 HEALTH EMERGENCY Company (914) 831-3400 A~ ~..t~ .,. "I'. Date Issued 01-03-96 Supersedes' 12-08-95 TEXACO MATERIAL SAFETY DATA SHEET NOTE Read and understand Material Safety Data Sheet before handling or disposing of product CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL IDENTITY Product Code and Name 79959 METHYL-T-BUTYL ETHER, MTBE Chemical Name and/or Family or Description Fuel additive - oxygenate Manufacturer's Name and Address TEXACO CHEMICAL INC POBox 27724 Houston, TX 77227-7724 Telephone Numbers Transportation Emergency-Company CHEMTREC -Company (409) 727-0831 (800) 424-9300 (914) 831-3400 (914) 838-7204 (914) 838-7336 (512) 459-6543 (800) 782-7852 Health Emergency General MSDS Assistance Technical Information -Fuels -Chemical -Lubricant/ Antifreezes -Additives -Solvents (713) 235-6278 (800) 876-3738 2 COMPOSITION/INFORMATION ON INGREDIENTS THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS FOLLOWS CARCINOGENS ARE LISTED WHEN PRESENT AT 0 1 % OR GREATER COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN PRESENT AT 1 0 % OR GREATER NON-HAZARDOUS COMPONENTS ARE LISTED AT 3 0 % OR GREATER THIS IS NOT INTENDED TO BE A COMPLETE COMPOSITIONAL DISCLOSURE REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND OTHER REGULATORY INFORMATION Product and/or Component(s) Carcinogenic According to OSHA IARC NTP OTHER NONE X Composition (Sequence Number and Chemical Name)~ ~ Chemical Name CAS Number Ranqe in % 1634-04-4 95 00-99 99 67-64-1 1 00-2 99 75-65-0 1 00-2 99 01 * Propane 2-methoxy-2-methyl- 02 '" Acetone 03 * Tert-butyl alcohol PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910 1200) * COMPONENT IS HAZARDOUS ACCORDING TO OSHA Exposure Limits referenced by Sequence Number in the Composition Section ~ Limit 01 40 ppm TWA-ACGIH (A3) 01 40 ppm TWA-TEXACO 02 750 ppm TWA-OSHA 02 1000 ppm STEL-OSHA 02 750 ppm TWA-ACGIH 02 1000 ppm STEL-ACGIH 03 100 ppm TWA-OSHA 03 150 ppm STEL-OSHA 03 100 ppm TWA-ACGIH-(A4) 3 HAZARD IDENTIFICATION EMERGENCY OVERVIEW Appearance Colorless liquid Odor Petroleum odor N 0 - NOT DETERMINED < - LESS THAN PAGE N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED f' 't~. ~~ ~~~, PRODUCT CODE 79959 NAME METHYL-T-BUTYL ETHER, MTBE 3 HAZARD IDENTIFICATION (CONT) Dat~ Issued Supersedes 01-03-96 12-08-95 DANGER WARNING STATEMENT EXTREMELY FLAMMABLE LIQUID AND VAPOR VAPOR MAY CAUSE FLASH FIRE MAY CAUSE DIZZINESS AND DROWSINESS MAY CAUSE EYE IRRITATION ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE HMIS NFPA Hea lth 1 Reactivity 0 Hea 1 th 1 Reactivity 0 Flammability 3 Special Flammability 3 Special POTENTIAL HEALTH EFFECTS EYE SKIN INHALATION INGESTION Primary Route of Exposure ~ ~ ~ EFFECTS OF OVEREXPOSURE Acute Eyes May cause irritation experienced as mild discomfort and seen as slight excess redness of the eye Skin Brief contact may cause sl ight irritation Prolonged contact as with clothing wetted with material may cause more severe irritation and dis- comfort seen as local redness and swelling Other than the potential skin irritation effects noted above, acute (short term) adverse effects are not expected from brief skin contact see other effects below and Section 11 for information regarding potential long term effects Inhalation Vapors or mist in excess of permissible concentrations or in unusually high concentrations generated from spraying heating the material or as from exposure in poorly ventilated areas or confined spaces may cause irritation of the nose and throat, headache, nausea and drowsiness Inhalation may cause dizziness drowsiness euphoria loss of coordination disorientation headache nausea and vomiting In poorly ventilated areas or confined spaces unconsciousness and asphyxiation may result Ingestion May cause abdominal discomfort nausea and diarrhea Aspiration may occur during swallowing or vomiting resulting in lung damage Sensitization Properties Unknown Chronic No adverse effects have been documented in humans as a result of chronic exposure Section 11 may contain appl icable animal data Medical Conditions Aggravated by Exposure. Because of its irritating properties repeated skin contact may aggravate an existing dermatitis (skin condition) Other Remarks None 4 FIRST AID MEASURES Eyes Immediately flush eyes with plenty of water for at least 15 minutes Hold eyelids apart while flushing to rinse entire surface of eye and lids with water Get medical attention Skin Wash skin with plenty of soap and water for several minutes attention if skin irritation develops or persists Get medical PAGE 2 - NOT APPLICABLE - GREATER THAN - NOT TESTED N 0 < - NOT DETERMINED - LESS THAN N A > N T 4'!CC' \ii." . ~ ~ ~~~ PRODUCT CODE 79959 NAME METHYL-T-BUTYL ETHER, MTBE 4 FIRST AID MEASURES (CONT) Date Issued Supersedes 01-03-96 12-08-95 Ingestion If person is conscious and can swallow, give two glasses of water (16 oz but do not induce vomiting If vomiting occurs, give fluids again Have medical personnel determine if evacuation of stomach or induction of vomiting is necessary Do not give anything by mouth to an unconscious or convulsing person Inhalation If inhaled, remove to fresh air and give artificial respiration medical personnel may administer If not breathing, clear person's airway If breathing is difficult, qualified oxygen Get medical attention immediately Other Instructions Aspiration of this product during induced emesis may result in severe lung injury If evacuation of stomach is necessary, use method least likely to cause aspiration. such as gastric lavage a-f"ter endotracheal intubation Contact a Poison Center for additional treatment information Remove and dry-clean or launder clothing soaked or sOiled with this material before reuse Dry cleaning of contaminated clothing may be more effective than normal laundering Inform individuals responsible for cleaning of potential hazards associated with handling contaminated clothing 5 FIRE-FIGHTING MEASURES Ignition Temperature - AIT (degrees F) 815 Flash Point (degrees F) -43 6 (TCC) flammable Limits (%) Lower 9 Upper 9 5 Recommended Fire Extinguishing Agents And Special Procedures Water may be ineffective on flames but should be used to cool fire-exposed containers and provide protection for persons atempting to stop the leak Use water spray dry chemical alcohol resistant foam or carbon dioxide to extinguish fire Unusual or Explosive Hazards Danger! Extremely flammable materials may release vapors 'that travel long distances ignite and flash back Containers may explode in a fire Do not expose to heat sparks flame static or other sources of ignition When handling use non-sparking tool ground and bond all containers Explosive air-vapor mixtures may form Special Protective Equipment for Firefighters Wear full protective clothing and positive pressure breathing apparatus 6 ACCIDENTAL RELEASE MEASURES (Transportation Spills CHEMTREC (800)424-9300) Procedures in Case of Accidental Release, Breakage or Leakage El iminate all ignition sources including internal combustion engines and power tools Use vapor stabilization foam to blanket spill Ventilate area Keep people away Stay upwind and warn of possible downwind explosion haz- ard Avoid breathing vapor Avoid contact with skin eyes or clothing Pressure demand air supplied respirators should always be worn when the airborne concentration of the contaminant or oxygen is unknown Otherwise wear respiratory protection and other personal protective equipment as appropriate for the potential exposure hazard Contain spill if possible Remove with inert absorbent Prevent entry into sewers and waterways If more than 1 030 pounds of product is spilled, then report spill according to SARA 304 and/or CERCLA 102(a) requirements, unless product qualifies for the petroleum exemption (CERCLA Section 101(14)) PAGE 3 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED N 0 - NOT DETERMINED < - LESS THAN Lk ~~~ PRODUCT CODE 79959 NAME METHYL-T-BUTYL ETHER, MTBE 7 HANDLING AND STORAGE Date Issued Supersedes 01-03-96 12-08-95 Precautions to be Taken in Handling Use spark-proof tools Material may be at elevated temperatures and/or pressures Exercise care when opening bleeders and sampling ports storage Ground and bond shipping container Keep away from heat, sparks, flame transfer 1 ine and receiving container and other sources of ignition 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Protective Equipment (Type) Eye/Face Protection Safety glasses chemical type goggles or face shield recommended to prevent eye contact Skin Protection Workers should wash exposed skin several "times daily with soap and water Soiled work clothing should be laundered or dry-cleaned Respiratory Protection Airborne concentrations should be kept to lowest levels possible If vapor mist or dust is generated and the occupational exposure limit of the product or any component of the product is exceeded, use appropriate NIOSH or MSHA approved air purifying or air supplied respirator after determining the airborne concentration of the contaminant Air suppl ied respirators should always be worn when airborne concentration of the contaminant or oxygen content is unknown Ventilation Use explosion-proof equipment to maintain adequate ventilation to meet occupational exposure limits if applicable (see below) prevent accumulation of explosive air-gas mixtures and avoid significant oxygen displacement Oxygen levels should be at least 19 5% in confined spaces or other work areas (OSHA value) Exposure Limit for Total Product None established for product refer to Section 2 for component exposure limits 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Colorless 1 iquid Odor Petroleum odor Boiling Point (degrees F) 131 Melting/Freezing point (degrees F) -164 Specific Gravity (water=1) 74 pH of undiluted product Not appl icable Vapor Pressure 200 mmHg at 68 0 Viscosity 5 cSt at 20 0 C VOC Content Not determined Vapor Density (air=1) 3 1 PAGE 4 - NOT APPLICABLE - GREATER THAN N T - NOT TESTED N D < N A > - NOT DETERMINED - LESS THAN ~~ ~~~ .. Date Issued Supersedes. 01-03-96 12-08-95 PRODUCT CODE 79959 NAME METHYL-T-BUTYL ETHER, MTBE 9 PHYSICAL AND CHEMICAL PROPERTIES (CONT) Solubility in Water (%) 5 Other None 10 STABILITY AND REACTIVITY This Material Reacts Violently With (If Others is checked below, see comments for details) Air Water Heat Strong Oxidizers Others None of These ~ ~ Comments None Products Evolved When Subjected to Heat or Combustion Toxic levels of carbon monoxide carbon dioxide, irritating aldehydes and ketones Hazardous Polymerizations DO NOT OCCUR 11 TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA) Median Lethal Dose Oral LD50 Similar product 3 80 g/kg (rat) slightly toxic Inhalation 4 hr LC50 Similar product 23500 00 ppm (gas vapor) (rat) practically non-toxic Dermal LD50 Similar product 10 20 g/kg (rabbit) practically non-toxic Irritation Index, Estimation of Irritation (Species) Skin (Draize) Bel ieved to be > 50 - 3 00 /8 0 (rabbit) sl ightly irritating Eyes (Draize) Similar 'product 20 80 /110 (rabbit) sl ightly irritating Sensitization Not determined Other In male mice prolonged and repeated exposure to high levels of MTBE vapor produced a higher than expected mortal ity due to urinary tract obstruction believed caused by physical non-neoplastic blockage of the urethral canal In female mice data indicate increased incidence~of hepatocellular adenomas (benign liver tumors) Prolonged and repeated exposure to high levels of MTBE (up to 8000 ppm for over 15 months) resulted in excess mortality (82 %) in male rats Prel iminary evaluation showed a chronic progressive nephrosis (kidney damage) as the possible cause of death Associated with the increased severity of nephropathy was an increase in the number of renal tubular cell adenomas (benign kidney tumors) and carcinomas (malignant kidney tumors) There was also a difference in the number of testicular interstitial cell adenomas (benign testicular tumors) MTBE has been shown to cause embryo/fetal toxicity and birth defects in mice but only at maternally toxic doses No developmental effects were seen in rabbits at the same exposure levels Although the significance of these findings to humans is unclear workers should minimize exposure to MTBE vapor Long-term exposure of rats and mice to high levels of t-butyl alcohol in drinking water resulted in an increased incidence of kidney tumors in male rats This tumor response may be associated with a mechanism distinct to rodents Male mice experienced a marginal increase in thyroid gland tumors, however there was no dose response In female rats there was an increased incidence of thyroid gland tumors at the highest dose level Because the significance of these tumor findings to humans is unclear at this time workers should minimize exposure to t-butyl alcohol Additional or repeat studies are planned or underway to better define the toxic potential of this product, or to verify the results obtained from previous animal studies N 0 - NOT DETERMINED < - LESS THAN PAGE 5 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED tJ;;:,.. I........ ~~~ PRODUCT CODE 79959 NAME METHYL-T-BUTYL ETHER, MTBE 12 DISPOSAL CONSIDERATIONS Dat~ Issued Supersedes' 01-03-96 12-08.,.95> Waste Disposal Methods This product (as presently constituted) has the RCRA characteristics of ignitability and, if discarded in its present form, would have the haz- ardous waste number of 0001 Under RCRA it is the responsibility of the user of the product to determine at the time of disposal, whether the product meets RCRA criteria for hazardous waste This is because product uses, transformations mixtures, processes, etc may change the Classifi- cation to non-hazardous, or hazardous for reasons other than, or in addition to ignitability Remarks Do not allow to enter drains or sewers Can cause explosion 13 TRANSPORT INFORMATION Transportation DOT Proper Shipping Name Methyl-tert-butylether Hazard Class 3 Identification Number UN 2398 Packing Group II Label Required Flammable liquid This product contains a DOT Hazardous Substance or Substances listed in Section 14 of the MSDS If the product's shipping container holdS at least 1,030lbs then the DOT information must be accompanied with RQ notation or an otherwise 'Not Regulated' product will be classified as Environmentally Hazardous (solid/liquid) NOS Class 9, unless the product qualifies for the petroleum exemption (49 CFR 171 8) IMDG Proper Shippin9 Name Not evaluated ICAO Proper Shipping Name Not evaluated TDG Proper Shipping Name Not evaluated 14 REGULATORY INFORMATION Federal Regulations SARA Title III Section 302/304 Extremely Hazardous Substances ~ Chemical Name CAS Number None Section 302/304 Extremely Hazardous Substances (CONT) ~ TPQ RQ None Ran~e in % Section 311 Hazardous Categorization Acute Chronic Fire Pressure X X - - Reactive N/A Section 313 Toxic Chemical Chemical Name Propane, 2-methoxy-2-methyl- Tert-butyl alcohol CAS Number Concentration 1634-04-4 95 00-99 99 75-65-0 1 00-2 99 CERCLA 102(a)/DOT Hazardous Substances ~ Chemical Name 01+ Propane, 2-methoxy-2-methyl- 02+ Acetone (+ indicates DOT Hazardous Substance) CAS Number Range in % 1634-04-4 95 00-99 99 67-64-1 1 00-2 99 N D - NOT DETERMINED < - LESS THAN PAGE 6 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED k: i.' . ~~ -~~-- ~ ,...-\::;;:~!" ~? :~'1}~ PRODUCT CODE. <79959 NAME METHYL-T-BUTYL ETHER,MTBE 14 REGULATORY INFORMATION (CONT) .l. Date Issued. 01-03-96 Supersedes: 12-08-95 CERCLA/DOT Hazardous Substances (Sequence Numbers and RQ's) ~RQ 01+ 1000 02+ 5000 TSCA Inventory Status This product, or its components are listed on or are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance Inventory Other None State Regulations California Proposition 65 The following detectable components or belong to classes of substances, to cause cancer and/or reproductive Chemical Name None of this product are substances, known to the State of California toxicity CAS Number States Right-to-know Regulations Chemical Name Acetone Propane 2-methoxy-2-methyl- Tert-butyl alcohol State Riqht-to-know CT FL IL MA NJ PA,RI MA NJ PA FL IL MA,NJ PA,RI ------------------------------------------------------------------------------- State list CT (Connecticut), FL (Florida) IL (Illinois) MI (Michigan) LA (Louisiana), MA (Massachusetts) NJ (New Jersey), PA (Pennsylvania) RI (Rhode Island) ------------------------------------------------------------------------------- International Regulations Export Notification (TSCA-12b) This product may be subject to export notification under TSCA section 12(b) contains Propane 2-methoxy-2-methyl- Acetone WHMIS Classification Not determined Canada Inventory Status This product or its components Canadian Domestic Substance List are 1 isted on or are exempt from the (DSL) EINECS Inventory Status This product or its components are 1 isted on or are exempt from the European Inventory of Existing Chemical Substances (EINECS) or the European List of Notified Chemical Substances (ELINCS) Australia Inventory Status This product or its components Austral ian Inventory of Chemical are 1 isted on or are exempt from the Substances (AICS) ~apan Inventory Status Not determined 15 ENVIRONMENTAL INFORMATION Aquatic Toxicity Not determined Mobility Not determined Persistence and Biodegradability Not determined <; Potential to Bioaccumulate Not determined N 0 - NOT DETERMINED < - LESS THAN PAGE 7 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED ., \. L~ \tL~ PRODUCT CODE 79959 NAME METHYL-T-BUTYL ETHER, MTBE 15 ENVIRONMENTAL INFORMATION (CONT) Date Issued 01-03-96 Supersedes 12-08-95 Remarks None 16 OTHER INFORMATION None THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT FOR PURPOSE OF HAZARD COMMUNICATION AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM IT IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT NO EXPRESS WARRANTY OR IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION CONTAINED HEREIN DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS YOU ARE URGEO TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY PROCESS USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN TO DETERMINE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT USER SHOULD CONSULT HIS LEGAL AOVISOR OR THE APPROPRIATE GOVERNMENT AGENCY TEXACO DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS Since the last mailing for this customer code, the following sections have been revised 2 4 6 13 14 16 17 Date 01-03-96 Date printed 02-05-96 Revised Supersedes 12-08-95 New X Inquiries regarding MSDS should be directed to Texaco Chemical Inc Coordinator Product Safety POBox 27724 Houston TX 77227-7724 PLEASE SEE NEXT PAGE FOR PRODUCT LABEL N 0 - NOT DETERMINED < - LESS THAN PAGE 8 N A - NOT APPLICABLE > - GREATER THAN N T - NOT TESTED LL ~L~ PRODUCT CODE 79959 NAME' METHYL-T-BUTYL ETHER, MTBE 17 PRODUCT LABEL Date Issued Supersedes 01-03-96 12-08-95 Label Date 12-08-95 READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910 1200) FOR USE IN THE WORKPLACE THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS 79959 METHYL-T-BUTYL ETHER. MTBE WARNING STATEMENT DANGER ! EXTREMELY FLAMMABLE LIQUID AND VAPOR VAPOR MAY CAUSE FLASH FIRE MAY CAUSE DIZZINESS AND OROWSINESS MAY CAUSE EYE IRRITATION ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE PRECAUTIONARY MEASURES -Keep away from heat, sparks or flame -Use only with adequate ventilation -Avoid breathing vapor mist or gas -Avoid contact with eyes -Keep container closed -Wash thoroughly after handling FI RST AID Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes Hold eyelids apart while flushing to rinse entire surface of eye and lids with water Get medical attention Skin Contact Wash skin with plenty of soap and water for several minutes attention if skin irritation develops or persists Ingestion If person is conscious and can swallow give two glasses of water (16 oz but do not induce vomiting If vomiting occurs give fluids again Have medical personnel determine if evacuation of stomach or induction of vomiting is necessary Do not give anything by mouth to an unconscious or convulsing person Inhalation If inhaled remove to fresh air and give artificial respiration medical personnel may administer Get medical If not breathing clear person's airway If breathing is difficult qualified oxygen Get medical attention immediately Note to Physi~ipn Aspiration of this product during induced emesis may res~lt in severe lung injury If evacuation of stomach is necessary use method least 1 ikely to cause aspiration such as gastric lavage after endotracheal intubation Contact a Poison Center for additional treatment information FIRE In case of fire carbon dioxide containers cool use water spray dry chemical alcohol resistant foam or Water may be ineffective on flames Use water spray to keep and protect personnel attempting to stop the leak If more than 1030 pounds of product is spilled then report spill according to SARA 304 and/or CERCLA 102(a) requirements, unless product qualifies for the petroleum exemption (CERCLA Section 101(14)) Chemical Name CAS Number Range in % 1634-04-4 95 00-99 99 67-64-1 1 00-2 99 75-65-0 1 00-2 99 * * Propane 2-methoxy-2-methyl- Acetone Tert-butyl alcohol PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910 1200) * COMPONENT IS HAZARDOUS ACCORDING TO OSHA Pennsylvania Special Hazardous Substance(s) None CAS Number Range in % Health F 1 ammab i 1 i ty HMIS 1 Reactivity 3 Special NFPA 1 Reactivity 0 3 SpeCial o .Hea 1 th Flammability PAGE 9 - NOT APPLICABLE - GREATER THAN - NOT TESTED N T N 0 < N A > - NOT DETERMINED - LESS THAN A.~....,.~ ~. ~~~ PRODUCT CODE 79959 NAME: METHYL-T-BUTYL ETHER, MTBE 17 PRODUCT LABEL (CONT) Date Issued Supersedes 01-03-96 12-08-95 Label Date 12-08-95 Transportation DOT Proper Shipping Name Methyl-tert-butylether Hazard Class 3 Identification Number UN 2398 Packing Group II Label Required Flammable liquid This product contains a DOT Hazardous Substance or Substances listed in Section 14 of the MSDS If the product's shipping container holds at least 1.030 lbs then the DOT information must be accompanied with RQ notation, or, an otherwise 'Not Regulated' product will be classified as Environmentally Hazardous {solid/liquid) NOS, Class 9, unless the product qualifies for the petroleum exemption (49 CFR 1718) CAUTION Misuse of empty containers can be hazardous Empty containers can be hazardous if used to store toxic flammable or reactive materials Cutting or welding of empty containers might cause fire explosion or toxic fumes from residues Do not pressurize or expose to open flame or heat Keep container closed and drum bungs in place Manufacturer's Name and Address TEXACO CHEMICAL INC POBox 27724 Houston, TX 77227-7724 TRANSPORTATION EMERGENCY Company CHEMTREC (409) 727 -0831 (800) 424-9300 HEALTH EMERGENCY Company (914) 831-3400 it"' ~;' ~~ ~~~ :;' 1~\ ) ". ~ \~ \ N \ t ! ~ \; )~ \' ~ '\ ~ "- ....r' ~ ~ ~ 'j ~, ~ \. ZO-d u o~_u"u5",1 u ~o "ll'j' II Urt..ll., "' _ .~. UU(J .,. IUUD.. ;.t UtJO~ 11 DS~ ~ . ntJO~fl [l i ~, .L ~ I u o . :.. - I I ~ I . . ' \ WI j ~ 6 I ~). ~~ I I I I I , i0 I I I \ ---;'''0 CO'CD-lHI "".... W"U.. "("O:l'I~"~ l'(l..."I''''6''''~.l) OI-^PW 96- d8E::ZO ti .!; ~ 0 .!; '" is '" ~ :; . c 8 d "- , Z -"....~ ) 0 / p::: S.T.FoP. srnniAcass_~ I ! E-< -IJMNTCNANCE EASDIENT .;.. " U) __ ___01; / ~ 'i' I P:: !,I, ~ rhl Q "I :1\1 ,I" :' I' , II / I; :/ I,' .f' ~__~_~ I I, ----;--i' f' J! " r I ; ~I ! f i I. ,( I I. 11 Ii Ii II II II I , Ii f ' I' I . ~ ~ I' "<:( e '<( I V) 1.0 (:) 1.0 Ii . ~ (:) ~~::t ~~ II Cl~~ ~~I ~ C,.) -..J Cl (:) :"( ~ ~~ i ~ 10 j ~~ h: ~ ~ t;j~ I I "AI'" CHECKED OJH we iSCAlE AT[ ,. _ 20' 1~MAR-9 RAWlNG NO. 96013.2 SHEET Cl SECTION 3D, TOWNSHIP 17 NORTH, RANGE 2 EAST, W.M., THURSTON COUNTY LEGEND NOTE -ss- -UGT- ----'JI<-- -UGP- -DHP- APPROXIMATE LOCATIONS OF EXlsnNG UTlUTlES HAVE BEEN OBTAINED fRo... AVAILABLE RECORDS AND ARE SHO~ FOR CONVENIENCE. THE CONTRACTOR SHAlL BE RESPONSIBLE FOR VERIFleA nON Of loeA liONS SHOWN AND FOR D1SCO~'f Of POSSIBLE ADDITIONAl unUTlES NOT SHO..".". so AS TO AVOID DAMAGE OR DISTURBANCE. THE CONTRACTOR SHAlL CONTACT THE Ul1UTlES UNDERGROUND LOCATION SERVICE (1-800-424-5555) PRIOR TO CONSTRUCTION. THE OIllNER OR HIS REPRESENTATIVE SHALL BE IUMEDlATaY CONTACTED IF A UTlUTY CONFUCT EXISlS. o i EXISTING SANITARY SEWER EXISTING UNDER GROUND mEPHONE EXlS11NG WATER UNE EXISTING UNDER GROUND POWER EXISTING O\f:R HEAD POVIER EXISTING STClRM DRAINAGE PIPE CURB AND GUTTER PROPERTY UNE EXISTING CATCH BASIN EXISTING p~ VAULT EXISTING TElEPHONE VAULT EXISTING TELEPHONE MANHOlE EXISTING WATER VAlVE EXISTING .lJNCTlON BOX EXISTING GAS METER EXISTING p~ POL( EXISTING UGHT Pa.E QUARTER SECllON CORNER SECTION CORNER EXISTING CONIFER mE[ " '" ~ SUBMITTAL SET NOT APPROVED FOR CONSTRUCTION UNTIL APPROVED BY THE CITY OF YELM )l ~ X * c=J EXISTING CONCRETE __ STORM PIPE., 8"'. MINIMUM . TYPE 1 CATCH BASIN . TYPE 2 CATQ-I BASIN, 48-' MINIMUM FlNISHED SURFACE DRAINAGE DiRECTION ~, ,~ ~ SOIL LOG LOCATION o 20' 40' SCALE. " = 20' EXISTING CONTOUR -S43- FlNlSH CONTOUR ~<l! ill- ;/ _ ;08.5<':.'_ ~~ A V E. 507) E. SIANDARD NOTES "Ll I.I,o,TER1ALS AND WOR""'ANS/-lIP IN OT'!' Of ,"l.lol RICHT-~-W"'Y SHALL BE IN .o.CCORO,o.NCE WITH THE REQUIREI,IHlTS OF THE LATEST STATE Of W"SHINGTON ()(PAR~[NT or TllANSPORTA,TlON STANDARD ~onCAnONS fOR n-JE ROAD AND BPIDG( CONSTRlJCTlON AND PIERCE COUNTY PVBUC ROAD STANO,o,ROS. IT I'oILL BE THE CONTRACTO.(S RESP{lNSl81UTY TO CONr",CT ALL UTILITY COlolPANI[S TO COOROINATt CONSTRUCTION. ALL UnllTY RElOC,o,nQN WORK SHAll BE AT THE: [XP[NS[ Of THE CONTRACTOR AND loIusr BE IN "CCQRO,o,NCf. WITH ntE STANO.o.ROS Of' THE ClN. . BURIED UTILITIES ARE 9iO_ IN rnElR APPFlQXII.IAT[ lOCATION THE CONTRACTOR SHALL HA,VE UTIUTIES YERlnED ON THE GROUND PRIOR TO ANY CONSTRUCTION ONSlTE EROSION CONTROl I.l[ASURES SH"lL BE ThE RESPONSl81UT'l' Of THE CONTRACTOR "'NY PROBLEMS OCClJRRlNG BEfORE fINAL ACCCPTANCE 81' THE ENGINEER SH"'ll BE CQRRECITO BY THE CONTR"CTQR THE CONm",CrQq SH"'LL Nonn' THE ,o,?PUc.o.Nrs [NGINEER IN Tt1E [VENT or DlSCO\lt:RY OF POOR SOILS. STANDING GROUND WATER OR DISCREPANCIES FROM PlANS IN EX1STIflG CONDITlONS EXCAVATION STANDARDS ~ SlOPES SHALL NOT BE STEEPER THAN 2 HORIZONTAL TO 1 \ltRTlCAL, OR AS RECOJ.IMENDEO BY A SOILS EN~NEER ThE CATCH POINT OF niE TOP Of niE SlOPE SHAlL BE SET B...Cl< FRO>.I TH( SlIT BOUNDARY LI"IE IN "'CCOROANCE Mni niE FOLLOMNG TABLE. UNLESS A RElIIINNG WALL IS DESIGNED SY rnE ENGINEER AND CONSTRUCTED FOR THE PRo..€cr CJLLll!:EItl U"IOER 5 FrET 5 - 20 rEET O'-1:R 20 FEET FILL STANOARDS ~ SloPES SHALL NOT BE SITEPER niAN 1-1/2 HORIZONTAL TO 1 '-1:RTICAL, OR liS RECOI.IMENDED BY A SOILS ENGINEER. flU SlITS MUST BE APPROVED 8Y ThE ENGI"I(ER AS SUITABLE LOCATIONS FOR THE PRCPOSEO FlLL PRrPIIR,o,nON Of" 1,ROIJNf1 niE GROUND SURFACE FOR FILLS OVER FIVE FEET IN HEIGHT SHALL BE PREPARfD BY REMOVING \lEGE:T,o,TIOO. NONCOI.IPL'l1NG FlLL. TOPSOIL. AND ornER UNSUH,o,SLE .....TER1...LS; SC....R1F'l1NG TO PROVIDE... SOND llllrn THE NEW FlLL; AND. _ERE EXISTING SlOPES ...RE STEEPER TliAN 5 HORIZONTAL TO 1 VERTlC"'L. By BENCHING INTO CQ!.lPEITNT ~...-rERI"'L "'S DETER\AINEO BY THE ENGlNfER TliE BENCH UNDER niE lOE Of ... FILL ON A SLOPE STEEPER 11-IAN 5- HORIZONT"'- TO 1 VERnc...L SH"'LL BE ...l LEAST 10 FEET 'MOE. OR "'S RECOM~ENDED BY A SOILS ENGINEER <;Fm...CK FROt.t PR'OPFRTY liNT!'; niE TOE OR CA TCH POINT or fiLL SlOPES SH,o,U BE SET B...CK FRN THE SlTE BOONO...RY UN[ IN "'CCOROANCE I'llTH THE FOlLO'oIlNG T"'BlL. UNLESS A Rn"'I~NG WALL IS DESIGNED BY THE ENGINEER IINO CONSTRUCTED FOl'l' THE PRD.JECT. ~ c;flA...CKr1I<;TANCF UNDER 5- FEEl 2 FEET 5 - 40 FEET HEIGl-IT/2 D\iER 40 FEET 20 FEET ON-SiTe EROSION CONTROL MEA,SURES SHALL BE THE RESPONSIBILITY OF ThE CONTR...CTOR. "'~Y PR08LE~S OCCURRING BEFORE FlN"'L ACCEP,...NC( OF THE STOR\I sYSn~ BY rHE ENGINEER SHALL BE CORRfCTED BY THE CONm...CTOR. IN CASE EROSION OR SEOIUENT...nOl\l OCCURS TO "'OJ"'CENT PRoPERTY O....,..ERS. ALL CONSTRUCTION WORK 'MTHIN THE OEVELOPUENT THAT ~Ll AGGR"'VATE THE SlTU...nON IN THE FUTURE. ~UST a...SE IINO THE OVINER/CQNTRACTQR I'llLL IU\AEOIATELY COl.!~(Io.CE RESTOR...TION METHOOS RESrORATION ...cnvtrY ~LL CONTINUE UNTIL SUCH nUE AS niE AFFECTED PROPERTY OWNER IS s...Tlsm:o "'LL EROSION AND SEOl~ENTAnON CONTROl. OE\IICES SHOI'IN ON nilS DR"'VIING SHALL El( INST"'U.EO PRlQR TO OR AS THE FIRST ST"'G( Of' SITE PREP...R...TION SHOULD THE rrt,lPOR...RY EROSION "'NO SEDI"'ENTATlON CONTRQ \AE"'SURES "'S SHOVlN ON THESE PL"""S NOT PROVE ADEQUATE TO CONlRQ EROSION ...NO SEOI\AENTAnON, THE APPlICANT/CONTR"'CTOR SHAlL INSTAU AOOITIQN"'L F"'CllITIES "'S NECESSARY TO PROITCT ...OJ"'CENT PRQP<:RTIES. SENSITIVE: ARE"'S. N"'TUR"'L W"'TER CCURSES. ANO/OR STORl.I OR...,N"'GE: SrsTEl.!S IN ...NY AR'[... WHIOl HAS BEEN STRIPPED OF VEGE:T...nON AND llll'l[RE NO FUfHHER WORK IS ANTIOPHED FOR A PERIOO OF JO o...rs OR "'{)RE. ,o,Ll OIST\JRBEO ...RE...S "'UST BE IMMEOI...TELY STABILIZED Y\1lH \AULCHING. GRASS PLANTING, OR OTHER APPROVED EROSION CONTRa.. TR[;,o,'rMENT APPLICABLE TO THE TI\AE or Y[AR IN QUESTION. GR...SS SEEDING ALONE 'MLL BE "'CCEPTABLf ONLY DURING niE loIONTHS OF o\,PRlL THROUGH SEPTEl.!BER. INCLUSIVE. SEEDING MAY PROCEED. HOWl::vtR. WHENE"rR IT IS N Tl-lE INTrREST OF TliE APPUC"'NT/CONTRACTOR. BUTI.lUST BE AUG\AENTED I'lllli t,lULCHINC. NETllNG. OR OTHER TRE"'T!.IENT. . THE ENGINEER 'MLL BE RESPONSlBLf FOR FIElD LOC'" TlNG THE CLE...RING L1\AITS ,wD ESTABLISHING niOSE BWNOAR'IES I'llTH BRIGHT COLORED FL...GGlNG THE CQf<lTR"'CTOR SHAU cu:,o,R TO niE UloIllS AS ESTABLISHED ON nilS PLAN ...NO FL...GGlNG IN THE FIELD. THE OTY Sl-tALL BE RESPONSIBLE FOR THE INSPECTION "'NO ACCEPT"'NCE Of' AlL CLE...RING "'1'10 GR"'ClNG WOR"; AND EROSION AND SEOI\AENTATIQN CONTRQ FAClUTIES. THE CONTR"'CTOR SH...U NOTIFY THE CITY FORTY-EIGHT HOURS IN ADV"'NCE or EACH REQUIRED INSPECTION I"ISPECTION NO 1 - INST...u...nON OF EROSlO"l CONTROl F"'ClUnES/PRIQR TO CLEARING INSPECTION NO. 2 - CQI,lPLfT1QN or ClE"'RlNG. INSPECTION NO J - UPON CQt,lPLETION Of' EXC"'VATION, FlLUNG, "'NO E"'RTHWORK. INSPECTION NO 4 - Cc::JMPU:TION or PROJECT. INSP(CTION NO.5 - WORK IN OTY R1CHT-~-WAY. . ALl WORK ASSOO...-rrO WITH ST...BttJZ!NG THE OlS"IlJRBEO AREAS SHAll BE IN "'CCORDANCE 'oIITH Sf:C'TlQN &-01 OF THE 1988 STANQ"'Rl) SPEOFIC"'TIONS FCR ROAD BRIDGE. "'NO UUHIClPAL CONSTRUCTION. OR 'THE LATEST VERSI<W 'THEREOF tlNLESS APPROVEO OTHERWISE BY THE OrY. . THE NECESS"'RY r"'C1UTIES SHALl BE U"'INTAINED ON SITE TO PREVENT DEBRIS. DUST, AND WD FRo... "'CCl.!WUl...nNG ON TH( COUNTY RlCHT OF WAY. <;n AM:K OI<;T""'U'F 2FUT HE1Gl-lT/2 10 FEET JOINTS IN f1LTER F,o,BIllC IoIATERlAl SHALL BE SPlICED "'T POSTS. USE ST...Pl..ES OR WIRE RINGS OR 2" )( 2" BY 14 G...UGE 'MRf OR rOUIVI!.ENT TO AnACH FABRIC TO POSTS / EQUIVALENT. IF STAWARD SlREHGTH i F"'BRICVSEO 1 I. .n ~ II II -- i~_________ N U BURY BOTTOM OF FlLTER MATERI"'~ - IN .....NlIolV\A :- :AYX... TRENClf '" .....Y BE INCREASf:O TO fllF 2" BY 4" \Ij()()() POSTS 'MR( BACKING IS USEO STEEl.. FENCE POST. REBAR OR E()JlVAlENT SECTION 30, TOWNSHIP 17 NORTH, RANGE 2 EAST, W.M., THURSTON COUNTY DRAINAGE AND GRADING NOTES ...u DR...IN"'GE STRUCTURES. SUCH "'S C...TCH B"'SlNS "'ND \A"'NHOlES. NOT LOC"'TED 'MTHIN A TRAVELED ROAOW"'Y OR PATHW,o,y. SHALL ,""'VE SOUD LQCI(ING LIDS PER WSOOT STANO...RDS. . ...LL DRAINAGE STRUCTURES. SUCH ...S C...TCH BASINS "'ND IoI...NHOLES. LOC"'TEO WITHIN A TR"'VELED RO"'DW"'Y OR' PATHWAY. SHALL HAVE FR"'\AE ... CR"'TES PER WSDOT ST"'ND...RDS. . All STORU DRAlN...GE PIPES TO H...V[ ... UINI\AUU 2. OF COVER AND "'LL PIPE LfNGf11$ (IF PROVIDED) "'RE SC"'LED HQRlZONJ"'L DlST...NCES FRQu CATCH B"'SlN CENTER TO CENTER . SEE SlIT PlAN. AND OTHER BUILDlNG PERMIT PLAN SHEETS (BY OTHERS) fOR SITE D1U[NSlONS "'NO OTHER I\APROVE\AENTjDEl.IOUTIQN DETAILS . RESTORE EXISTING TRAFFlC SIGNS "'S OIRECTUI BY eHY . "'LL STORU PIPES SHALL BE "'OS N12 OR "'PPfW'.rO EQUAl UNLESS OTHER'MSE NOTED . THE CONTRACTOR SH"'U BE R'ESf'ONSlBLE fOR PRO\llOlNC "'OEOUA TE SAFEGUARDS, SAfETY DEVICES. PROTECTIve: EQU1P\AENT. FL...CCERS. ...100 ...NY OThER NEEOEO ACTIONS TO PROTECT THE LIFE. HE"'L TH. A"IO SAFETY OF THE PUBlIC. ...HO TO PROTECT PROPERTY IN CONNECTION 'MTH ThE PERFQR\AANCE or WQR"; COve:REO BY THE CCNTR"'CTOR ,-- ~ - J" PLAN \1EW -,-.- SIDE \1EW END WlEW DEBRIS RACK 2" BY.. WOOD POSTS STEEL ITHCE POST, RQlAR OR EQUlVAJ..(NT SILT FENCE NOTES 1.SE[...OJ...CENTOETAlL 2. THE CEOTEXnLE USED MUST l.IEET THE FOllO'MHG sPECIFlc...nONS.: ADS (...S1\I 0-47~1) JO-.l00 SIEVE SIZE FOR SILT F1l.U W...TER P(fl1.l1T'nVlTY ("'Sn. 0-.....91) ~1~C~p'E\AI~ZE FOR OTH(R FABRICS GRAB TENSILE STRENGni (AS1\I 0-46J2) :gg t: = ~~~~~=~nJ..,~FA8RIC GRAB l'[NSIL[ ELOHG...nDH (ASN 0-46.l2) 30X I,IAX. VLlR...VlOL.ET Fl(SISTAHCE ("'SN 0-43$5) 70X 1oIlN. A copy CI THE \IAtfUFACTIJRERS' FABRIC SPEClFlCA'TIClHS WST BE ",vAJl..A8L[ ONSlTE .}. STANDARD STRENGTH FABRIC REWIRES 'MR[ BACKING TO ~ THE STRENGTH CI' THE FDfCE. 'MRE BACKING OR CLOSER POST SPACII'IG W"'Y BE REQUIRED fOR EXTR'" SlRENGTH FABRIC " FIELD PERf'OI,INrtC[ WARRANTS ... SlR()N(;[R f'ENCE. .. WHERE THE FENCE IS ""STAlLED. lHE Sl.Cf'E 9lAU. lIE NO S1UPER THAN 2H:IV. " . ~ SILT FENCLDETAl!. "'. 5. 12" MIN QUARRY SPALLS B1OFlLlRAnON OiECK DAt.! DETAIL NOTE; PROVIDE 2 CHECK DAMS ALONG THE BIOSWAlE ALIGNMENT SPACE 30' MINIMUM TOPSOIL AND SEED ALL EXCAVATED AND FILLED SLOPES 0.33' [_O:::l CRooNO 6~ MIN TOPSOIL OVER 12" COMPACTED TOPSOil 2.' Tt ~20.~ 12" EXISTING SOIL (MIN.) TO BE ~t.llXED 'MTH ON-SITE SILTS OR BENTONITE TO ACHIEVE PERK RATE SLOWER THAN 9 MINUTES/HOUR BIOFlLTRATION SWALE SECTION NTS PLAN VIEW Frome and Grote Marked ~DRAlN. w/ Locking Bolts Invert & Elev. Per Plans o Restrictor Plate For on POllution Control Only ~46"lf SECIION A-A ~!!?,' ~Y,~E 2 SPILL CONTAINMENT CATCH_ BASIN NOTES. 1. THE BOTTOM OF THE INFllTRAnON TRENCH'" PERFOR"TED DRAINPIPE SHALL BE LEVEL. 2. THE TRENCH SHALL FOlLOW GROUND CONTOURS. 3. A t.lINIMUt.l Of' 100 LF SHALL BE INSTALLED. 4 CONTOUR LINES AND ELEVA nONS ARE BASED UPON THE PROVIDED DATUM AND FIELD SURVEY. NOTIFY THE ENGINEER Of ANY DEVIATION FROM THE SURVEY INFORMATION. S N/A 6. N/A 7 ALL TRENCHES SHALL BE A t.lINIMUM 7' FROM ANY STRUCTURE, PROP[RT'r' LINE, OR NGPE. 8 THE INfiLTRATION TRENCH IS DESIGNED TO INFILTRAI"E SURFACE DRAINAGE THAT IS FREE OF SEDIMENTS AND POLLUTANTS 9. BOTTOM OF TRENCH SHALL NOT EXCEED 84" OR BE LESS THAN 36M fROM EXISTING GROUND SURFACE. PLACE A MINIMUM Of OS fiLL OVER GRAVEL LAYER. 10. ALL INfiLTRATION TRENCH PIPE SHAH BE ADS OR PVC SEWER PIPE(ASru 3034) 11. FILTER FABRIC SHALL BE MIRAFI 140 OR EQU"'l NON-WOVEN GEOTEXTILE 12. EACH TRENCH SHALL HAVE ONE OBSERVATION PORT THAT EXTENDS TO THE BOTTOM Of THE TRENCH, LOCATED AT A POINT APPROXIMATELY HAlf-WAY ALONG THE TRENCH LENGTH. 13. INFILTRATION SYSTEt.lS MUST NOT BE USED BY SEPTIC SYSTEMS. 14 GROUND WATER TABLE MUST BE AT LEAST 1 FOOT BELOW THE TRENCH BOTTOM. 15. A MINIMUM 10 FOOT WIDE SPACING IS REQUIRED BETWEEN INFILTRATION TRENCHES. 16. CLEANOUTS SHALL BE PROViDED ON ONE END Of EACH LINE 'MilCH ODES NOT START WITH CB. 17 fOUNDATION DRAIN SHALL DISCHARGE TO SEPARATE DR'l".'t[LL UNLESS fiRST CB SUt.lP GRATE ELEVATION IS 6" BELOW THE LO'NEST FOUNDATION LEVEL. OBSERVATION WELL WITH METAL CAP &; lOCK FINISH GRADE COMPACT BACKFILL j I I EXISTING GRADE W\ WRAP TRENCH ENTIRELY 'MTH .... FILTER FABRIC LAP JOIN TS 12" MIN 12- PERFORATED PIPE 6- PVC PIPE , (PERFORATED)-- l.m'in I TRENCH BOTTO,", BELOW EXISTING GRADE 72- MIN_. 84- MAX. WAs'HEO ROCK 3/4" TO 1-1/2" SECTION A-A NO SCALE A TYPE 2 CB WITH SOUD ROUND LOCKING LID BIO SWALE OBSERVATION WELL FINISH GRA ~1;6kNG ,~ - .-\.! 12" PERFORATED ADS fiNE MESH SCREEN '00. L A (SEE PLAN) INFILTRATION TRENCH PROFILE NO SCALE PROVIDE EXP...NSlON JOINT AT CONCRETE SlAB 1.5" WAX.. OS ""N. FlBERWESH ......-REINFORCING I .s" CONCRETE SWALE NO SCALE SUBMITTAL SET NOT APPROVED FOR CONSTRUCTION UNTIL APPROVED BY THE CITY OF YELM ~ ti .!; S " G .!; '" < is ~ '" :S "3 ~ ; ft ~ ~ 0 :> en Z . 0215 ~ ~ j:i E-< il :5 rn ::i a. 2 . < en Ii ~ ei " w z z Q i ~ [I ~ ~ lJ) "- ::::! C) ~ . It) <: I..u ~Cl~ Cl tI)~~ ~ ~Cl::~ ~lJ) ~ i a:<{~ ~ I'i <...>t:i Cl W :q:"t ~ ~~~ i C)i:;j ~ 1--.:- ~ lJ) f I, RA"" CHECKED I 0... lDl ;CALE ATE SHEET C2 OF 4 / ~~Ar;.:;.%&PARATOR )0\" If IN = 342.4-4 Ie O/IT = 342..J4., SEE SCWFR (}f1AJL SHeer CONNECT f"ROjJ CAR WASH PCR p~ BY OTHE~ ,,~ /~ .r.~, WATCR STlJB----------~- IE 11ft J44.5 CAR WASH FF = 345.5 // BUILDINb",,- '~ FF = 3'r16.5:f ~ \ / /' // / =? ='="='u *1 1\ I 'l" ji 1'= I I I I I' " I' " \_ .,.5 \ \ r / I I I I I L--__------J45-- I I I I I I I I I I I / / / \ \_~ / \ \ \ /' ,^,,,, p,p(S it t~ fJ:J5') Ie r" = .J.I3.69 INSTALL ALONG PROJCCT1ON or CENTCRUNE OF FUeL ISLAND 112LF ... DI S--D.'" ';',.1'-\(, \ 00 ~ eo\..\.."'ROS 2 \. \ " \ __\c 8. . ~i.f~NWCNT ~ DCTAlL. SHEET C2 INSTALl. ALONG PROJEa1ON OF 1VCL PUJJP ISLAND lGE or <I STING 3PHAlT ~ ~ ~ floR\~i:, '~ flIJ,/) f\\.J..(R OJ) \Uh>4J \1)1 : I / , I , : I I / : il 1(/ , 1_, ~- II : : I: :1! , , , / , / , ,1 , , , /' , o "'N / !; li~ / ~ ,,~ I : 8~ / .s; ~I 0 '" - ~ ,:j , '" ~ 0 ~ "5'" (f) ;1 ~h u :. ~ o ~ or , :> Z ~ '" " o 5 ~ p::_W . z E-<~~ rJ) rl a. i1 . ~ P::~ ~:d , , I , , , , , , , , , , , , , jI II! I : I ' I I ,ll_J I f"'J ~' I'" 11-) I_L -':f ~:: 'j I I I I o I I I I I I I / / ;' / ~ 'l LEGEND - SCWE1l PlK WT1H CLCANOUT see SCWCR DCTAlL SHEeT h~ I o /0' 20' SCALE. /" = /0' SUBMITTAL SET NOT APPROVED FOR CONSTRUCTION UNTIL APPROVED BY THE CITY OF YELM I ~ ~ "- C) . II) <: ~l::lC) u) C3 t; . Cl:: <: ::J :t ~ <n <: a~~ :::5 t)<n Cl. ~~ ~ =-" C) ~ :.:: ~ ci!j L.J .....->: <n I~: ~: I i l RAWN CHECKED OJH D.Ji CALl: ATE ,. .. 10' 16-MAR-9 RAWlNG NO 9601J.3 SHEET C3 SEWER CONSTRUCT/ON NOTES 1 ALL APPROVALS AND PERMITS REOU1RED BY THE CITY OF YELM SHALL BE OBTAINED BY THE CONT.':ACTOR PRIOR TO THE START OF CONSTRUCTION 2 A PRECON$TRUCTION MEETING SHALL BE HELD WITH THE CITY OF YEL\,! PRIOR TO THE START OF CONSTRUCTION 3 THE EXISTlriG SEPTIC TANK SHALL BE PROPERLY ABANDON,IN ACCORDANCE WITH THURSTON COUNTY AND CITY OF YELM STANDARDS. THE SEPTIC TANK SHALL EITHER BE REMOVED OR IT SHALL BE PUMPED. ITS TOP AND BOTTOM CRUSHED AND THEN IT SHALL BE FILLED WITH DIRT 4 ALL \....ORKMANSHIP AND MATERIALS SHALL BE IN ACCORDANCE WITH CITY OF YELM STANDARDS AND THE MOST CURRENT COPY OF THE STATE OF WASHINGTON STANDARD SPECIFICA lIONS FOR ROAD, BRIDGE AND MUNICIPAL CONSTRUCTION (WSDOTIAPWA) 5 All CmJCRETE TANKS SHALL BE M,"NUFACTURED AND HYDROSTATICALLY TESTED AFTER PLACEMENT IN ACCORDANCE WITH THE CITY OF YELM DEVELOPMENT GUIDELINES, SECTION Teoso, CONCRETE TANKS ~ TijE CO~'TRACTOR SHALL BE FULL' RESPONSIBLE FOR THE . LOCATION AND PROTECTION OF AL~ EXISTING UTlllTlES. THE CONTRACTOR SHALL VERIFY ALL U-:-IUTY LOCATIONS PRIOR TO CONSTRUCTION BY CALLING THE U-lDERGROUND lOCATE LINE AT 1.800-424-5555 A MINIMUM OF 48 -lOURS PRIOR TO ANY EXOVATIQN 7 IF CONSTRUCTION IS TO TAKE PLACE IN THE COUNTY RIGHT-OF WAY THE CONTRACTOR SHALL NOTIFY THE COUNTY AND OBTAIN ALL THE REQUIRED APPROVALS AND PERMITS 8 THE CITY OF YELM SHALL BE NOTiFIED A MINIMUM OF 48 HOURS IN ADVANCE OF A TAP CONNECTION TO AN EXISTING MAIN A CITY REPRESENTATIVE SHAll BE PRESENT AT THE TIME OF THE TAP 9 SIDE SEWER SERVICES SHALL BE PVC, ASTM D 3034 SDR 35 WITH FLEXIBLE GASKET ED OR SOLVENT WELD JOINTS. SIDE SEWER CONNECTIONS SHALL BE MADE BY A TAP TO AN EXISTING MA!N OR A W'fE BRANCH FROM A NEW MAIN CONNECTED ABOVE THE SPRINGllNE OF THE PIPE 10, ALL PLASTIC PIPE AND SERVICES SHALL BE INSTALLED WITH CONTINUOUS TRACER TAPE INSTALLED 11" TO 18' UNDER THE PROPOSED FINISHED SUBGRADE. THE MARKER SHALL BE PLAST C NON. BIODEGRADABLE. METAL CORE OR BACKING MARKED SEWER WHICH CAN BE DETECTED BY A STANDARD METAL DETECTOR IN ADDITION, STEP SYSTEMS, FORCE MAINS, AND CURVILINEAR SEWERS SHALL BE INSTALLED WITH 14 GAUGE COATED COPPER WIRE WRAPPED AROUND ALL PLASTIC PIPE, BROUGHT UP AND TIED OFF AT VALVE BODY ONA CURVILINEAR seWER, THE WIRE SHALL BE BROUGHT UP BARED AND WRAPPED THREE TIMES AROUND THE MANHOLE RING TAPE SrlALL BE TERRA TAPE "D"OR APPROVED EQUAL THE TAPE AND WIRE SHALL B~ FURNISHED BY THE CONTRACTOR 11. ALL BURIED POWER FOR STEP SYSTEMS SHALL BE INSTALLED WITH CONTINUOUS TRACER TAPE I:'-ISTALLED 17 ABOVE THE BURIED POWER. THE MARKER SHALL BE PLASTIC NON- BIODEGRADABLE, METAL CORE BACKING MARKED "POWER" TAPE SHALL BE FURNISHED BY CONTRACTOR 12 EROStON CONTROL MEASURES SH,IILL BE TAKEN BYTHE CONTRACTOR DURING CONSTRUCTION TO PREVENT lNFIL TRA TlON OF EXISTING AND PROPOSED STORM DRAINAGE FACILITIES AND ROADWAYS 13. PROVIDE TRAFFIC CONTROL PlANeS)]N ACCORDANCE WITH THE MANUAL ON UNIFORM TRAFFIC CONTROL DEVICES (MUTCD)AS REQUIRED. 14. IT SHALL BE THE RESPONSIBilITY OF THE CONTRACTOR TO HAVE A COPY OF THESE APPROVED PLANS ON CONSTRUCTION SITE AT All TIMES. 15. ANY CHANGES TO THE DESIGN SHALL FIRST BE REV]EWED AND APPROVED BY THE PROJECT ENGINEER AND THE CITY OF YELM 16, THE PANEL LOCATION SHALL BE DETERMINED BY THE CITY OR THE OWNER AS APPROVED BY THE CITY OF YELM 17 IN THE EVENT THAT THE DEPARTMENT OF LABOR AND INDUSTRIES OR THE CITY SHOULD REQUIRE A SEPARATE "ON. OFF" SWITCH CONTROLLING POWER TO THE PUMP CONTROL PANEL, SAID SWITCH MUST BE LOCKABLE OR HAVE A LOCKING COVER TO HOLD AN OL YMPUS TYPE BP125, 30MM PADLOCK. 18. INSPECTIONS FOR ONSITE STEP INS-:-ALLATiONS ARE REDUIRED A 24 HOUR NOTICE TO THE SEWER [,EPARTMENT IS REQUIRED PRIOR TO THE INSPECTION. ITEMS tJEEDING INSPECTION ARE A) TANK INSTALLATION. IT" BEDDING AND LOCATION B) TANK INFIL TRA TION. EXFll TRA TION TEST C) S.S. PRESSURE TEST 0) SERVICE LINE PRESSURE TEST E) FINAL INSPECTION 19 ALL LUMBER (PLYWOOD, ETC.) USED TO MOUNT EITHER PUMP CONTROL PANEL OR POWER METER MUST BE PRESSURE TREATED ",,o,nV[ ""'" Fl8ERGl"'SS UO ....TH ST,'.)I'<USS STEEL BOlTS ,o.NQ ~EOPR[NE G,o,SI([T SECTION 30, TOWNSHIP 17 NORTH, RANGE 2 EAST, W.M., THURSTON COUNTY 5' 101m (rrP.) r;~::,~'. '" U"' l~lSl.QP[TD~('rrp) P\lCRlSER, ORE"'CO SYSTEIoIS. I~C. OR EQU.o.L -2 P...RT EPO~l I~ 11j2;H~~V[O:~~W T"'~K ~ (FORUS[....TH~O"l-TRJo.FTICBE...RI...GT.o.HKS) RISER A~O UO SHAU BE 24 C"'l"'u $luP\.O puuP v"'ULT ''''STAlLATlONS RISER AND UO 9-I...u B'E 30" 00; "'ll DUPl[~ .....0 TR1PU~ puuP v,o,ULT I...STAlLATIONS. PUUP "'SS<:UIh l OIJPl-EK ClRE",CD UOOEl 10 OS! O~ HHF PUUPS. SEE Sn:PsYSn:UDESlCNREPQRT FI"'ISH=::-T <>IT lOR~~~N~l::~ PUMP FLOA T DETAIL DG7-1~ ~D SCALE ~BO:".t -I ~. 2/2 Hosecormecllon /' wll~ threads I _"/2Steamercannecllon with NST Ihread, !: 5" SIon: odopter Style $-37 w/SC cop 18"~2-4" I fi Clan 50 ductll. Iron pipe cut 10 length fi gate vol..... rL X MJ S.. note below ~Vorles ".KtrK1fi concrete block Hydront shoe Bockflll to top of drain ring housing bolts with -r washed rock as shawn 6' 6' sheet of 11 mil, plastic or con- struction fabric, coYerlng -r ....oshed rock ,,",otes 1. Hydrants sholl be located In accordonce with Section 6,060, In addition, 0 minimum three foot radIus unobstructed ....orklng oreo shall be provided around all hydrants, 2. Hydrant sholl b. Woterous Pacer, Onner lrol !: H Reliant style 929, "'ueller Centurion, or Clow F-2500. 3. Cote ...olves sholl be resUlenl wedge NRS wIth O-ring seals. Valve ends ,hall be lrolechanlcol lolnl by ANSI flange,. Vol...e, sholl conlorm to AWWA 509-80. VolYes sholl be Mueller M&:H. Kennedy, Clo.... R/W or Wolerovs Serl., 500, VAULT RISER ;~, ,~I liQ1L. INSTAll T"''''KSASPER DETAil OR lolANUr"'CTURER'S RECOUlol[~OAnON _Cl-lEV[R IS IoIORE STRINGOH. "";,~'\:..- STEP TANK/PUMP TANK OC7-11, ~O SCALE:. UTIuTYV,.o,UtT 612-5.A, 2.000 G...Uo... 1.500 GAL "2000 GAL. 3000 GAl 60" 88" n 43" 5~'- ~" SO 78 /; 400 GAl 960 GAl 600 GAL UOOG..o.l 2,400G.o.L 2,400G"'l 0-' ft v:T V=2 1 T...NK SH"'U BE ... unun V"UlT 612-GA (2000 G.o.L.) SEPTIC T","'l(. YllTH UOOIfl[Q UIOWAU 8""(.E OPE~I~GS. I~STAU POWER m"'~SfER S....lCH DHEn: 8...rFlE FOR ... JOOO G"'llON T"'~K UTlUlEO "'S A TRlPU~ PUUP V"'UlT INLET E~W.EER WlU REVIEw TOlER"''''CES IN DCESS Of IE = 34416'__ OllolE"'SIONS SHOWN --- eEDOI~G lolATERlAl fOR R1QOPlPE (SECTION 9-03.15 w.>OOT 1994 STA"'O"'RO SPECIfiCATIONS) CONCRETE TANK BEDDING OCT-H, ~O SCAlE TABLE FOR FEWER WIRE RUN _ See volv. bOll and / valve ,tem defcll- 6~12 rGround Plastic born., betw..n thrust block and tee Concrwt. Ihrust block eosl-In-ploc. ogo]nsl flttlng only ~~1 HYDRANT OFFSET FIRE HYDRANT DETAIL ~ SUBMITTAL SET NOT APPROVED FOR CONSTRUCTION UNTIL APPROVED BY THE CITY OF YELM ,,2 AflIG COPPER ,,0 Awe CoPPER 18 "''/IfG COPPER 3SO FEET (sa SPECIfiCATIONS FOI'f AOOlTlOl<lAl INFOFNATION) ~g,~,C"'~S BotDl8PT lETTl:RING P...QlOCl<; "",TH COo.lUON KEY ~~~EO BY THE CH'" RESTCiRA TIC'N TABLE Z-:CEU~ir;::D ~ -~ snEClIl"'CKflU <XW>ACT TO Ull ....C.P..._NT O">V!QU'o'[l1!l"'S[ )' -. CI'lADlII ....c. "...wtGoYUI."CIlI/SH( SUIlfAC(l'OPCOJIl:'l!: snEeT 8AOCrlU CQPACTto":s n"C,17-fl2 TO STEP TA~l( TR!PILX PUMP CONTROL PANEL OC7-&, NO SCAU :::"'~)I~:t~~ I =::1':: N~~~~ ~= IIA1M:aAOO:f'U ~AClTOl!ISll FNSH CIU.D[ 9<AU. II( SWlXlTH"CO<SSTDlT .11+ EICISTHCQl.OOE ~~ 2"_DJSTIHG CI'lADE"SWOOllO .....11'01[ BAO<YU COIllPAC1T08511 CSlIC-CINSHUI~.o.a:IIASt:~ CST\: CRUSHEDSl.Jlf.o.a:TOPCOU"5l: PIPE TRENCH DETAIL OGT-J. ~D SC,o,l[ ENml OR CRA'oU. LOOCIHG C1LAHOUT CO'YElt Do""""""""'" NO.~-l~ SERVICE BO~ - CMtSON INO!JSTRIES 1oI0000l NO 14198 WITH BOln:O >lINGEO CO'<Ul OR EQU"'l COvt:R lolARl(IHG TO RE"'O "SEWER" (USE I~ ~ON- TRAmc ..R(AS) 14 GA. ''''SUl...TEO COPPER TONI"'G \OIRE 2" P\IC SWP CLEANOUT DETAIL NOT TO SCALE SEWER SERVICE CONNECTION D~rAJL OG7-2. ~O SCALE 1 24.~ ACCESS HOlE 3 PLA.C[S , is PRECAST DIVIDER 6" TH1CK-- ~SLOT { f1..Mi...YlEW BOTH SIDES I _~ FRAMES '" C~~~S NOT S~~____~ ~I DIM A I 24"iJ LOCKING FlAME'" OVER TOP [L - 34600 / AIR'" GAS TICH / 3 PLACES __ ADJUST TO GRADE - 'M TH RISERS , is GALLON CAPACITY UV MODEll DIM A DIM "8" DIY "C" DIM .0- DIM "E- GROUT ALL AROUND- BOlH SIDES 2/3 L~~__~_L__![5 lENGTH _ ~ STRUCTURAl NOlFS: 1. CONCRETE. 28 DAY COMPRESSIVE STRENGTH t'c""4500 psi 2 REBAR; ASTh! A-615 GRADE 60 J l.4ESH: ASTM 1.-185 GRADE 65 4. DESIGN: ACI-)18 BUILDING CODE ASnA C-857 ~MINIMUM STRUCTURAL DESIGN LOADING FOR UNDERGROUND PRECAST CONCRETE UTILITY STRUCTURES~ lOADS. H-20 TRUCK WHEEL wi 30~ IMPACT PER AASHTO CONTRACTOR TO SUPPLY & INSTALL <lolL PIPING & SAMPLING TEES AS SHO'M>f 2,000 612-GA 12' - 8"' 6' - 8- 8' - 0- 4' - 7- J' - 10" GREASE TRAP 9Y UTllln v"'UlT. ~O SCAlf ~OX{'Ik~ ,=.. ~> OUnLT liI()R--- OL ". "- ~-,. I ~~ ~-~.~ NET....~~/ PROWl[ lJ1'IUlY VALLT ~CPS OR Af'f>RO',fi) EQU~ ~;:~ ~~~AREA 12S G.P.... _ WADAAI FlOW RAlE PROWl( IIlSERS AS NECES$o\RY. SEE PLAN FOR D.EVATlONS OIL---JYATER SEPARATOR DETAIL BY unun V...Ut.T, NO SCAlE ti "' ~ e . "' '" ,:j '" ~ ~ ~ ~ li . >- (.) ; ~ ci '" c.? ~ " Z ~ V> 0;; [5 (}:;~~ E-t ~ :'3 "' "- (f)? ~ ~ . ~ W (}:;.w , ~ . " Q ~ Q I !\!; (I) :::! ~ ""( <: ~ '~L.j~ VI (.:) Q:: :::) I...J <: ~ :::'::;: :<{ "<((I) ~ a~~ ~ (.J--J :q:~ Q:: ~ ~ t...i ~<O--J ~ f-:~~ ~ Hi ,I, ';0'1[[1 C4 3. ALL REINFORCED CASi-IN-PLACE CONCREl'E SHALL BE ft' RISER SEC'ION ClASS 4000 4 PRECASi BASES SHALL BE F'URNISHED wnH CUTOUiS OR KNOCKOUTS. KNOCKOUTS SHALL HAVE A WALL iHICKNESS , ,~ BAR HOOP - OF 7: MIN. AlL PIPE SHALL BE INSTAlLED IN FACiORY PROVIDED KNOCKOU'TS. UNUSED KNOCKOUTS NEED NO'T BE GROUTED IF WALL IS LEFT IN'TACT 5. KNOCKOUT OR CUTOUT HOLE SIZE IS EOUAL TO PIPE OUTER DIAI.\. PLUS CATCH BASIN WAlL 'THICKNESS. 6. ROUND KNOCKOUTS MAY BE ON AlL 4 SIDES. wnH MAX. DIAM. or 2rJ KNOCKOUTS MAY BE EITHER ROUND OR . D" sHAPE. \2' 7 THE w.:I.. DEPTH rROM THE FINISHED GRADE TO 'THE \ 2" RISER S(C110N PIPE INVERT IS 5'-rJ 'I 8. THE 'TAPER ON THE SIDES OF THE PRECAST BASE SEC'TION 2'3 BAR HOOPS- AND RISER SECTION SHAlL NO'T EXCEED 117: 1FT "-V' '--v 9 CATCH BASIN rFWolE AND GRATE SHALL BE IN ACCORDANCE WITH STANDARD SPEC1FlCA'TIONS AND \,\EEl' 'THE STRENGTH REQUIREMENiS or rEDERAL~SEEClFlCA110N RR-r-62ID. MATlNG-SiJRFACES-SHALL8E FINISHED 10 ASSURE NON-ROCKING m wnH ANY COVER posmON. 10 FFWoIE AND GRATE MAY BE INSTALLED WITH \-"LANGE DOWN OR CAST INTO RISER. 11 FOR CA1CH BASINS IN PARKING LOTS REFER 'TO WSD01/APWA ":::':~~ A\(t~ll~w:~ \ SIANDARD DWG. B1-b. -~ ,- , j, \l.. ) 12. EDGE OF' RISER OR BRICK SHAlL NOT BE MORE lHAN z: FROM .,\ PR(CA$1 SASl: SECTION VERTiCAl EDGE OF CA'TCH BASIN WAlL. (h1VSVRE\.lEN'T IS 1HE 10f' or lHE eASE) (i) KI>IG COUNTY pU8LIC WORKS KING COUNTY. WASHING10N rR>>olE ANO GRI;1l: SEE SEC. 7.if.> IINO Al'PuCABLE owes. CATCK BASINS SHALL BE CONS1RUCTED IN ACCORDANCE WITH ASTM C478 (MSH'TO M 199) & ca90 UNLESS OTKERWlSE SHOWN ON PLANS OR NOTED IN 'THE WSDOT/APWA SIANDARD SPECIFICATIONS. 2. AS AN ACCEP11>8LE AllERNAlfVE 'TO REBAR. WELDED WIRE F'ABRIC HAVING A MIN. AREA OF' 0 12 SQUARE INCHES PER FOO'T MAY BE USED. WELDED WIRE FABRIC SHALL COMPLY 10 AST\,\ A497 (AASHTO M 221). WIRE FABRIC SHALL NO'T aE PLACED IN KNOCKOUiS. NOlES. P BAR [)oD\ WAY F: '''' \ ","," \ '" ~ CATCH BASIN TYPE 1 DWG. 2-003 NO. 78 , J ~ J , \l , " , a " I 1 ffiAloIE & CRATE OR COVER. SEE SEC. 7 .O~. N ToP SLA8 }WlDHOLOS 2 2rJ 24" 48" ,s..".&:r ,71' .OR 96" " " ... :I: c; G:i :I: X "" 2 \,' ~ 4IS DWl.- 6" !).I' DWl. - fl 6If DIAIl.- fl 7'1' DWl.- 8" 96" Dw.l.-' 2' '0\ . .1 i N 4 . FOR SEP,lJlATE CAST -IN- pLACE ONLY REINFORCING STEEL (rOR SEPARATE BASES ONLY) O,2~ SO IN./f! IN t,.o.CH DIRECTION rOR 46'" Dw.!. 0.,9 SO IN./f! IN U.CH DIRECTION rOR !).I' Dw.!. 0.25 SO. IN./f! IN EACH DIRECTION fOR 6If DW-l. O.~5 SO. IN./f! IN U.CH DIRECTION rOR 77 DIAM. O.~9 W. IN./f! IN EACH DIRECTION rOR 96" DIAM. PRECASi B>.SE JOHn ~ KINO COUNTY PUBUC YKYi"KS KING COUNTY. WASHINGTON CATCH ADJUSTMENT SECT10N (LMLlNG ElRIO(S OR GRAPE RINGS OPTiONAl). S1EPs2 OR WlDER. ORIENT WITH INLET SO SitPS WILL CLEAR PlPES. sEE OWC. NO 2-0<)6. PRE CAST ElASE & ""ECow. RlSER. , -(1 fOR 415' !).I" & fIf DW'. 2'-C!' fOR 7Z' & 96" DIAW. GRAVEL fl,loCKnu. rOR fOUNDATiONS 6" lAIN. COIAP"CTED DEPTH rOR PREOS'l ElASE ONLY NOTES. CATCH BASINS SHALL BE CONSTRUCTED IN ACCORDANCE WITH ASTloA C478 (AASHTO t.l199) AND ASTM C890 UNLESS OTHERWISE SHOWN ON PLANS OR NOTED IN THE WSOOT/APWA STANDARD SPECltlCATIONS. 2. HANDHOLDS IN ADJUSTMENT SECTION SHALL HAVE :r MIN. CLEARANCE. STEPS IN CATCH BASIN SHALL HAVE fj MIN. CLEARANCE. SEE DWO. NO 2-006, CATCH BASIN DETAILS. HANDHOLDS SHALL BE PLACED IN ALTERNATING GRADE RINGS OR LEVELING BRICK COURSE WITH A MIN. OF ONE HANDHOLD BETWEEN THE lAST STEP AND TOP OF THE MANHOLE. :, ALL REINFORCED CAST _IN-PLACE CONCRETE SHALL BE ClASS 4000. ALL PRECAST CONCRETE SHALL BE ClASS 4000. 4 PRECAST BASES SHALL BE FURNISHED wITH CUTOUTS OR KNOCKOUTS. KNOCKOUTS SHALL HAVE WALL THICKNESS OF 'L MIN. UNUSED KNOCKOUTS NEED NOT BE GROUTED IF WALL IS LEn INTACT PIPES SHALL BE INSTALLED ONLY IN r ACTORY KNOCKOVTS UNLESS OTHERWISE APPROVED BY THE ENGINEER. 5 KNOCKOUT OR CVTOUT HOLE SIZE SHALL EQUAl PIPE OUTER DIAM. PLUS CATCH BASIN WALL THICKNESS. MAX. HOLE SIZE SHALL BE -:,f)' FOR 48" CATCH BASIN, 42" rOR 54" C.B., 46" FOR 5et' C.B.. 50" FOR 72" C.B., 84" FOR gf)' C.B. MIN. DISTANCE BETWEEN HOLES SHALL BE f{ FOR 48" 54", AND 5et' C B,. 12" FOR n" AND gf)' C.B. 5. CATCH BASIN FRAMES AND GRATES OR COVERS SHALL BE IN ACCORDANCE WITH SEC. 7.05 AND ~EET THE STRENGTH REQUIREMENTS OF FEDERAL SPECIFICATION RR-r-621 D. MATING SURFACES SHALL BE FINISHED TO ASSURE NON-ROCKING F'IT WITH ANY COVER POSITION, 7 ALL BASE REINFORCING STEEL SHALL HAVE A MIN. YIELD STRENGTH OF 60,000 PSI AND BE PLACED IN THE UPPER HALF OF THE BASE WITH 1" MIN. CLEARANCE. 8. MIN. SOIL BEARING VALUE SHALL EOUAL 3,300 POUNDS PER SQuARE FOOT FOR DETAILS SHOWlNG LADDER, STEPS. HANDRAILS AND TOP SLABS, " ~6. SEE THE WSOOT/APWA STANDARD SPECIFICATIONS SEe 7-05,3 FOR JOINT REQUIREMENTS. 9 10 RElNrORClNC STEEL (roR pREOS'l BASE & IHTECRAl. R&R ONLY) o \ ~ SQ. IN./f! IN UCH DiRECTION rOR 48" ()WoI. 0.' 9 SQ. IN./M IN UCH DiRECTION rOR ~4' ()WoI. 0.25 SO. IN-If! IN t,.o.CH DIRECT10N rOR 6tJ DIAM. 0.24 SQ. IN-If! IN UCH (llRECT10N rOR 71' DWo!. 0.29 SQ. tN./M IN EACH DiRECi10N rOR 96" ()WoI. BASIN TYPE [ C"TE 1- RCV1SIOH ~ 2 48" , 54" 6 0" , 7 2" , & 9 6" DWG. 2-005 NO, 80 ... I I I I II II I ! ~ I I i , e I n LJ 96 013.200 fl LJ n u n U c r LJ TEXACO 706 YELM AVE E DRAINAGE & EROSION CONTROL REPORT c c c n I ' , I U Prepared for fl LJ Texaco Refirung and Marketmg Inc POBox 2969 Kirkland, W A 98083 n LJ [ I' ~ C C o PREPARED BY D.R. STRONG Consulting Engineers Inc. 10604 N.E. 38TH PLACE, SUITE 101 . KIRKLAND WA 98033 . (206) 827-3063 March 19, 1996 n U D ~ 1996 D. R. STRONG Consulting Engineers, Inc. o c n u o [J PROJECT ENGINEER'S CERTIFICATION n U I hereby certIfy that trus Drainage and ErosIOn Control Plan for Texaco at 706 Yelm Avenue E., Yelm, WA, has been prepared by me or under my supervisIOn and meets minimum stan- dards for the City of Yelm, unless noted otherwIse, and normal standards of engmeenng prac- tice. I understand that the CIty of Yelm does not and will not assume lIabilIty for the suffi- ciency, sUItabilIty, or performance of the dramage facilItIes desIgned by D R. STRONG Consulting Engineers, Inc o n I ' LJ c n I I U n I I U D I' LJ c [l LJ r' LJ n U o D c o o TEXACO AT 706 YELM AVE E DRAINAGE & EROSION CONTROL REPORT c n lJ T ABLE OF CONTENTS fl LJ n U SECTION 1 - PROPOSED PROJECT DESCRIPTION 1 SECTION 2 - EXISTING CONDITIONS 3 SECTION 3 - INFILTRATION RATES/SOILS REPORT 3 SECTION 4 - WELLS AND SEPTIC SYSTEMS 3 SECTION S - FUEL TANKS 4 SECTION 6 - SUB-BASIN DESCRIPTION 4 SECTION 7 - ANALYSIS OF THE IOO-YEARFLOOD 4 SECTION 8 - AESTHETIC CONSIDERATIONS FOR FACILITIES 4 SECTION 9 - FACILITY SIZING AND DOWNSTREAM ANALYSIS 4 SECTION 10 - CAR WASH OIL/W ATER SEPARATOR SIZING- S fI U fI LJ n i I U n LJ n U I' ~ APPENDIXES n I U A Soil Log and Soil Infiltration Data n LJ B On-SIte and Adjacent Well Logs c Stormwater Storage, Treatment, and Infiltration Systems CalculatIons fl LJ D n U D D R. STRONG Consultmg'Engmeers DRS Job # 96 013 March 1996 Yelm Texaco Drainage & Erosion Control Report Page i